公开(公告)号：DE4135265A1

公开(公告)日：1993-04-29

申请号：DE4135265

申请日：1991-10-25

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  ZIERKE THOMAS DR ,  BRATZ MATTHIAS DR ,  MISSLITZ ULF DR ,  MEYER NORBERT DR ,  LANDES ANDREAS DR ,  RADEMACHER WILHELM DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: A01N37/42 ,  A01N37/48 ,  A01N37/50 ,  A01N39/00 ,  C07C67/313 ,  C07C69/757 ,  C07C249/02 ,  C07C249/08 ,  C07C251/18 ,  C07C251/42 ,  C07C251/52 ,  C07C251/54 ,  C07C255/56 ,  C07C255/61 ,  C07C255/62 ,  C07C317/28 ,  C07D295/18 ,  C07D521/00

Abstract: Cyclohexenone derivates have the formula (I), in which R stands for alkyl, alkenyl, alkinyl, cycloalkyl, aloxyalkyl, alkylthioalkyl, possibly substituted phenyl, possibly substituted benzyl, possibly substituted 5-/6-membered heteroaryl; W stands for 0, =N-OR or =N-R ; R stands for possibly substituted alkyl, alkenyl or alkinyl residue, possibly substituted 3- to 6-membered alkyl chain or 4- to 6-membered alkenyl or alkinyl chain, a chain link in each of the chains being substituted by -0-, -S-, -S0-, -S02- or -N(R )-; R stands for H, alkyl, alkenyl, alkinyl, alkylcarbonyl, benzoyl; R stands for H, alkyl hydroxyakyl, alkoxyalkyl or alkylthioalkyl, possibly substituted phenyl, possibly substituted benzyl; X, Y stand for -OR or -NR R ; R stands for H, alkyl, akenyl, alkinyl, alkoxyalkyl, alkylthioalkyl; R stands for H, alkyl, alkenyl, alkinyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl and R stands for H, alkyl, alkenyl, alkinyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl, alkylcarbonyl, possibly substituted benzoyl or R -R form together with the shared N atom a 5-/6-membered heterocycle that may contain -O-, -S- or -N(R )- as ring element; R stands for H, alkyl, alkenyl, alkinyl, alkylcarbonyl, benzoyl. Also disclosed are the agriculturally useful salts and esters of C1-C10-carboxylic acids and anorganic acids of the compounds having the formula (I). These cyclohexenone derivates (I) are useful as herbicides and plant growth regulators.

公开(公告)号：DE4128441A1

公开(公告)日：1993-03-04

申请号：DE4128441

申请日：1991-08-28

Applicant: BASF AG

Inventor： HAMPRECHT GERHARD DR ,  MAYER HORST DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  GERBER MATTHIAS DR ,  KARDORFF UWE DR

IPC: A01N47/36 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D521/00

Abstract: Substituted sulphonyl ureas have the general formula (I), in which n and m equal 0 or 1 and the substituents have the following meaning: R is hydrogen, alkyl, alkenyl or alkinyl; R is halogen or trifluoromethyl, when m equals 0 or, when m equals 1, R is alkyl, alkenyl or alkinyl, and when X stands for O or S and m equals 1, trifluoromethyl or chlorodifluoromethyl; X is O, S or N-R , whereas R is hydrogen or alkyl; R is hydrogen, halogen, alkyl, halogenalkyl, alkoxy or halogenalkoxy; A is NO2, NH2, OH, CN, SCN, S(O)oR , SO2NR R , ER , whereas E stands for O, S or NR , the groups (a), (b) possibly substituted C1-C4-alkyl or C2-C4-alkenyl; R is a possibly substituted alkyl group, a possibly substituted cycloalkyl group, an alkenyl group or an alkinyl group; R is hydrogen, an alkoxy group, an alkyl group, or represents together with R a C4-C6-alkylene chain, wherein a methylene group may be substituted by an oxygen atom or a C1-C4-alkylimino group; R is a possibly substituted alkyl, alkenyl or alkinyl group, a cycloalkyl group and may also represent, when E = NR , methyl sulphone, trifluoromethyl sulphone, ethylsulphone, possibly halogen-substituted acetyl, dimethylcarbamoyl, dimethylsulphamoyl; o equals 0, 1 or 2; p, q equal 0 and/or 1 (when p = 0, q = 0); R is hydrogen or halogen; R is hydrogen, methyl, ethyl; R is alkyl, halogenalkyl, alkoxyalkyl, alkenyl, cycloalkyl, halogenalkenyl or, when p = 1 and q = 0, it may also be alkylamino or dialkylamino. Also disclosed are their environmentally compatible salts, a process and intermediates for producing the compounds having the formula (I) and their use as herbicides.

公开(公告)号：DE4126937A1

公开(公告)日：1993-02-11

申请号：DE4126937

申请日：1991-08-10

Applicant: BASF AG

Inventor： VOGELBACHER UWE JOSEF DR ,  RHEINHEIMER JOACHIM DR ,  SAUPE THOMAS DR ,  MEYER NORBERT DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: A01N43/54 ,  A01N43/66 ,  C07C39/11 ,  C07D239/52 ,  C07D239/60 ,  C07D251/22 ,  C07D251/30 ,  C07D251/34 ,  C07D403/12 ,  C07D403/14 ,  C07D405/12 ,  C07D409/12 ,  C07F9/6509 ,  C07F9/6521

Abstract: Salicyl (thio)ether derivatives of the formula I in which X represents oxygen or sulphur and Z represents carbon or nitrogen and the radicals R to R and A are as defined in the description, as well as processes and intermediates for the preparation of the compounds I.

公开(公告)号：DE4123469A1

公开(公告)日：1993-01-21

申请号：DE4123469

申请日：1991-07-16

Applicant: BASF AG

Inventor： LANDES ANDREAS DR ,  WALTER HELMUT DR ,  HAMPRECHT GERHARD DR

IPC: A01N25/32 ,  A01N43/50 ,  A01N43/52 ,  A01N43/56 ,  A01N43/90

Abstract: Herbicidal compsns. contain an N-dichloroacetyl-diazacycloalkane safener of formula (I) and one or more herbicides of formula (II)-(V). In the formulae, A = 1-4C alkylene with each CH2 gp. opt. substd.; B =a bond or 2-4C alkylene with each CH2 gp. opt. substd.; R1 =H, Me or Et; R2 and R3 = H or Me when B = bond, or R2+R3 = a bond when B = alkylene; Ar = 2-methoxycarbonyl-4-methylphenyl, 2-methoxycarbonyl-5-methylphenyl, etc.; Z = N or CH; X = O or S; W = 2-R4CO-3-R5-phenyl or CH(R10)COR0); R4 = H; pyrrolyl, pyrazolyl, imidazolyl or triazolyl opt. substd., etc. R5 = H; halogen; opt. halogenated 1-4C alkyl or alkoxy; CHO; 2-9C alkoxycarbonyl; opt. halogenated 3-6C alkenyl, alkynyl, etc. R9 = H, 1-10C alkoxy, 1-4C haloalkoxy, 3-6C alkenyloxy, 3-6C alkynyloxy, etc. R10 = 1-10C alkyl opt. substd. or 3-12C cycloalkyl opt. substd.; R11 - H 1-10C alkyl, 3-6C alkenyl, 3-6C ''''nyl, alkali(ne earth) metal, NH4, mono-, di- or tri(1-4C alkyl) ammonium, etc.; R16 = H or Me; R17 = F, Cl, Me, OMe, OCHF2, NHMe or NMe2; R18 = Me, CF3, OMe, OCHF2, OCF3, OCF2Cl, OEt or OCH2CF3; U = 2-R19-phenyl (opt. ring-monosubstd. by halogen or Me), 2-methoxycarbonylbenzyl, 3-dimethylcarbamoyl-2-pyridyl, etc.; R19 = Cl, 2-chloroethoxy, 2-methoxyethoxy, COOMe or COOEt. ADVANTAGE - (I) reduce the phytotoxicity of (II)-(V) to crops, esp. barley, wheat, maize, sorghum and rice.

公开(公告)号：DE4042194A1

公开(公告)日：1992-07-02

申请号：DE4042194

申请日：1990-12-29

Applicant: BASF AG

Inventor： SCHAEFER BERND DR ,  RUEB LOTHAR DR ,  SCHAEFER PETER DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

IPC: A01N37/32 ,  A01N37/46 ,  A01N43/36 ,  A01N43/38 ,  A01N43/56 ,  A01N43/90 ,  C07D207/44 ,  C07D207/452 ,  C07D209/48 ,  C07D231/56 ,  C07D513/04

Abstract: Styrene derivatives I (R = H; R = halogen; R = H, halogen, C1-C4-alkyl; R = CN, C1-C6-alkylcarbonyl; A = a heterocyclic radical A1 to A5 where R and R are H, CH3 or C2H5, n is 0 or 1 and X is oxygen or sulphur), with the proviso that R is an alkylcarboxyl group if R represents H and simultaneously A represents A2 where n = 0; and their agriculturally useful salts, the preparation of the styrene derivatives I and herbicidal agents containing them.

公开(公告)号：DE4039734A1

公开(公告)日：1992-06-17

申请号：DE4039734

申请日：1990-12-13

Applicant: BASF AG

Inventor： HAGEN HELMUT DR ,  NILZ GERHARD DR ,  WALTER HELMUT DR ,  LANDES ANDREAS DR

IPC: A01N25/32 ,  A01N35/06 ,  A01N39/02 ,  A01N43/10 ,  C07D333/26 ,  C07D333/38 ,  C07D333/62 ,  C07D333/68 ,  C07D333/70 ,  C07D409/04 ,  C07D409/12 ,  C07D417/12

Abstract: Herbicidal agents contain as antagonistic compound at least one substituted 2-aminothiophene having formula (I), in which R , R stand for H, CN, alkyl, halogen alkyl, if necessary substituted phenyl, CO-R or R + R stand for a C3-C6 alkylene chain, upon which a benzene ring, if necessary substituted, may be annulated, a C2-C3 alkylene chain broken by -O- or -N(R )-, which may also carry 1-4 alkenyl residues or a group CO-N(R )-CO; R stands for CN, if necessary substituted -C(NH2)=N-C6H5, -C(NH3 Hal )=N-C6H5, CX-R ; Hal stands for halogen; R stands for H, alkyl, alkenyl, if necessary substituted phenyl, if necessary substituted triazin, -PX(OR )2, -CX-R , -SO2R , -SO2-NHR , -CX-N(R )-CY-R , -CX-N(R )-SO2-R or R =R stand for CO-O-CO; R stands for H, alkyl, -CX-R , -SO2-R ; X, Y stand for O, S; R stands for H, phenyl, alkyl; R stands for H, alkyl, if necessary substituted phenyl; R stands for alkyl, halogen alkyl, alkenyl, halogen alkenyl, if necessary substituted cycloalkyl or cycloalkenyl, NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted phenyl or phenylamino; R stands for alkyl, if necessary substituted phenyl; R stands for NH2, alkylamino, dialkylamino, if necessary substituted pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl; R + R stand for =CR R or -CO-W-CO-; R stands for H, NH2, alkylamino, cycloalkylamino; R stands for NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted thienylamino, pyrrolidinyl, piperidinyl, morpholinyl, if necessary substituted phenyl or pyridyl; W stands for an ethylene or ethenylene bridge, if necessary substituted, or for an aromatic or heteroaromatic 5/6 membered cycloalkylene or cycloalkenylene bridge, if necessary substituted. Also disclosed are a basic salt of compound (I), in which R stands for hydroxycarbonyl, hydroxythiocarbonyl, or an acid salt of compound (I) which contains a basic hydrogen atom, and at least one herbicidal active substance from (A) the group of 4-aryloxy- and 4-heteroaryloxy-phenoxyacetic acid derivates or from (B) the group of cyclohexan-1,3-dione derivates.

公开(公告)号：DE4037636A1

公开(公告)日：1992-06-04

申请号：DE4037636

申请日：1990-11-27

Applicant: BASF AG

Inventor： KAST JUERGEN DR ,  MEYER NORBERT DR ,  MISSLITZ ULF DR ,  HARREUS ALBRECHT DR ,  RANG HARALD DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR

IPC: A01N35/10 ,  A01N43/14 ,  A01N49/00 ,  C07C239/20 ,  C07C251/42 ,  C07C251/52 ,  C07C317/28 ,  C07C323/47 ,  C07D213/30 ,  C07D261/08 ,  C07D307/12 ,  C07D309/06 ,  C07D309/22 ,  C07D309/28 ,  C07D317/26 ,  C07D333/22 ,  C07D339/06 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12

Abstract: 1-Oxo-3-hydroxy-2-cyclohexenyl ketoxime ethers of formula (I) are new. In (I) Q is H, 2-7 alkanoyl, benzoyl, alkali(ne earth) metal, opt. substd. ammonium, phosphonium, sulphonium, sulphoxonium or transition metal; W is CC or CH=CH; R1 is (a) alkoxyalkyl or alkylthioalkyl, (b) cycloalkyl, cycloalkenyl or 6-membered heterocyclyl contg. 1-2 nonadjacent O and/or S atoms, opt. substd. by 1-3 of OH, halogen, alkyl, haloalkyl, alkoxy or alkylthio, (c) 5-membered satd. heterocyclyl contg. 1-2 O and/or S atoms, opt. substd. by 1-3 of alkyl, haloalkyl, alkoxy or alkylthio, (d) 5-membered heteroaryl contg. 1-2 N atoms and/or an O or S atom, opt. substd. by 1-3 of CN, halogen, alkyl, haloalkyl, alkenyl, haloalkenyl, alkoxy, alkylthio, alkenyloxy or alkoxyalkyl, (e) phenyl or pyridyl opt. substd. by 1-3 of NO2, CN, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl, alkenyloxy, alkynyloxy or NR8R9, or (f) R7X-substd. alkyl, where X is O, S, SO, or SO2 and R7 is alkyl, or phenyl or 5- or 6- membered heteroaryl opt. substd. as in (e); R8 is H, alkyl, alkenyl or alkynyl; R9 is H, alkyl, alkenyl, alkynyl, alkanoyl, or benzoyl opt. substd. by 1-3 of NO2, CN, halogen, alkyl, haloalkyl, alkoxy or alkylthio; R2 is alkyl; R3 is H or alkyl; R4 is H, halogen or alkyl; R5 is H or alkyl; or R3+R4, R3+R5 or R4+R5 are each alkylene or alkenylene; R6 is (a) H, alkyl, haloalkyl, phenylhaloalkyl, alkenyl, alkoxyalkyl or alkylthioalkyl, (b) cycloalkyl or cycloalkenyl, opt. substd. by 1-3 of OH, alkyl, haloalkyl, alkoxy, alkoxyalkyl or alkylthioalkyl or (c) phenyl or pyridyl opt. substd. by 1-3 of NO2, CN, OH, halogen, alkyl, haloalkyl, alkoxy, alkylthio, alkoxyalkyl or alkylthioalkyl. (B) Intermediates of formula (IIa) and (IIIa) are also new.

公开(公告)号：DE4035479A1

公开(公告)日：1992-05-14

申请号：DE4035479

申请日：1990-11-08

Applicant: BASF AG

Inventor： HAGEN HELMUT DR ,  RAATZ PETER DR ,  WALTER HELMUT DR ,  LANDES ANDREAS DR

IPC: A01N43/54 ,  A01N25/32 ,  C07D471/04

Abstract: Pyrido[2,3-d]pyrimidin-2,4(1H,3H)-diones are disclosed, having formulas (Ia) and (Ib), in which R and R stand for H, substituted or unsubstituted alkyl, cycloalkyl; R stands for H, substituted or unsubstituted alkyl; R stands for H, alkyl, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, cyano or aminocarbonyl; or R and R represent together alkylene, alkenylene or 1,2-phenylene; R stands for H, alkyl, cyano, C(O)R ; R stands for alkyl, possibly substituted aralkenyl, aryl or hetaryl, CH2R , alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, OH, SH, alkoxy, alkylthio, NH2, alkylamino, NHCXR , NHSO2R ; R and R represent together substituted alkylene, alkenylene or 1,2-phenylene, which may also contain carbonyl or thiocarbonyl groups; R stands for H, alkyl, OH, SH, alkoxy, alkylthio, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl, NH2 alkylamino, dialkylamino, possibly substituted aryl or arylamino; R stands for halogen, OH, SH, alkoxy, alkylthio, alkoxycarbonyl, (alkylthio)carbonyl, alkoxy(thiocarbonyl), (alkylthio)thiocarbonyl or the formula (a); R stands for alkyl, halogen alkyl, NR R or OR ; R stands for alkyl, substituted or unsubstituted aryl; R stands for halogen, OH, SH, alkoxy, alkylthio, alkyl, nitro or amino; X stands for oxygen or sulphur. Also disclosed are the salts of compounds (Ia) and (Ib) that can be used in agriculture and that contain nitrogen or hydroxy substituants, as well as herbicides that contain 2-[4-(hetero)-aryloxy]-phenoxyacetic acid or propionic acid derivates and/or cyclohexenone derivates as active herbicidal substances and substituted pyrido[2,3-d[pyrimidin-2,4(1H, 3H)-diones, as well as the salts of (Ia) or (Ib) as antidotes when acid end groups or basic nitrogen atoms are present.

公开(公告)号：DE4030929A1

公开(公告)日：1992-04-02

申请号：DE4030929

申请日：1990-09-29

Applicant: BASF AG

Inventor： RHEINHEIMER JOACHIM DR ,  EICKEN KARL DR ,  VOGELBACHER UWE JOSEF DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

IPC: A01N43/54 ,  A01N43/66 ,  C07C251/48 ,  C07C251/52 ,  C07D239/52 ,  C07D239/60 ,  C07D251/30

Abstract: Benzaldoxime ether derivatives of the formula I (R denotes succiniminoxy; unsubstituted or substituted hetaryl; OR in which R denotes substituted or unsubstituted cycloalkyl, alkyl, alkenyl, alkynyl, phenyl or an oxime group; OR in which R denotes hydrogen, alkali metal or alkaline earth metal cation, ammonium or organic ammonium; R and R denote C1-C4-alkyl, C1-C2-haloalkyl, C1-C4-alkoxy, C1-C2-haloalkoxy, C1-C4-alkylamino, di(C1-C4-alkyl)amino and/or C1-C4-alkylthio; R denotes C1-C8-alkyl, C3-C6-alkenyl, C3-C6-haloalkenyl, unsubstituted or substituted benzyl; X denotes oxygen, sulphur; Z denotes nitrogen, methine group) and also the preparation of these substances, intermediates therefor, and the use of the compounds I as herbicides and bioregulators.

公开(公告)号：DE4029753A1

公开(公告)日：1992-03-26

申请号：DE4029753

申请日：1990-09-20

Applicant: BASF AG

Inventor： HEISTRACHER ELISABETH DR ,  FISCHER KLAUS DR ,  MAYER HORST DR ,  SAUPE THOMAS DR ,  HAMPRECHT GERHARD DR ,  DITRICH KLAUS DR ,  KUEKENHOEHNER THOMAS DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR

IPC: A01N43/10 ,  A01N43/36 ,  A01N43/50 ,  A01N43/56 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  C07D207/34 ,  C07D207/416 ,  C07D231/14 ,  C07D231/16 ,  C07D231/54 ,  A01N43/08 ,  C07D231/56 ,  C07D233/90 ,  C07D261/18 ,  C07D263/34 ,  C07D271/04 ,  C07D271/06 ,  C07D271/08 ,  C07D271/10 ,  C07D277/20 ,  C07D277/32 ,  C07D277/34 ,  C07D277/56 ,  C07D285/06 ,  C07D307/68 ,  C07D307/71 ,  C07D333/38 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12

Abstract: Sulphonamides of the formula I in which the substituents have the following meanings: A is an optionally substituted aromatic or heteroaromatic radical; W is oxygen or sulphur; B is an optionally substituted furyl, thienyl, pyrrolyl, oxazolyl, isothiazolyl, imidazolyl, pyrazolyl, thiadiazolyl, oxadiazolyl or triazolyl radical, and their environmentally compatible salts; their preparation, and their use as herbicides.