公开(公告)号：CA1333737C

公开(公告)日：1994-12-27

申请号：CA600720

申请日：1989-05-25

Applicant: BASF AG

Inventor： SEELMANN-EGGEBERT HANS-PETER ,  BOECKH DIETER ,  HARTMANN HEINRICH ,  TRIESELT WOLFGANG ,  BAUR RICHARD

IPC: C07C233/38 ,  C08F2/10 ,  C08F20/10 ,  C08F220/04 ,  C08F222/10 ,  C11D3/37

Abstract: Water-soluble polymers having K values of from 5 to 100 (determined on the Na salt of the polymers according to H. Fikentscher in aqueous solution at 25.degree.C, a pH of 7 and a concentration of 1% by weight of the Na salt of the polymer) are prepared by polymerizing a monomer mixture of (a) monoethylenically unsaturated C3-C5-monocarboxylic acids and (b) more than 20-100 mol % of monomers which have two or more ethylenically unsaturated double bonds linked via one or more ester or amide functions and which contain one or more -CO-OX groups, where X is one hydrogen equivalent, one alkali metal equivalent or one alkaline earth metal equivalent or an ammonium group, in aqueous solution in the presence of a polymerization initiator, and the polymers are used in amounts of from 0.5 to 25% by weight in detergents and cleaners.

公开(公告)号：CA2143745A1

公开(公告)日：1994-05-11

申请号：CA2143745

申请日：1993-10-29

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  SCHORNICK GUNNAR ,  BAUR RICHARD ,  SCHWENDEMANN VOLKER ,  HARTMANN HEINRICH

IPC: C08G65/34 ,  C08G81/00 ,  C08G81/02 ,  C08J3/24 ,  C09K23/52 ,  C11D3/37 ,  C08G2/26

Abstract: There are described block copolyacetals obtainable by cationically initiated polyaddition of (A) polyacetals containing acetaldehyde acetal units and having at least 2 OH groups in the molecule and (B) polyacetals containing acetaldehyde acetal units and having at least 2 vinyl ether groups in the molecule. in a molar ratio of (A):(B) of from 2:1 to 1:2, processes for preparing the block copolyacetals by cationically initiated polyaddition of (A) and (B), and the use of the block polyacetals as additament to reduced-phosphate and phosphate-free detergents and cleaners and as low-foam surfactants in dishwashing compositions.

公开(公告)号：CA2140752A1

公开(公告)日：1994-03-03

申请号：CA2140752

申请日：1993-08-16

Applicant: BASF AG

Inventor： FUNHOFF ANGELIKA ,  MC KEE GRAHAM E ,  BAUR RICHARD ,  KUD ALEXANDER ,  SCHWENDEMANN VOLKER ,  HARTMANN HEINRICH

IPC: C08G2/12 ,  C08G2/18 ,  C08G2/28 ,  C08G2/30 ,  C08G4/00 ,  C08G12/18 ,  C09K23/00 ,  C09K23/52 ,  C11D3/37 ,  C08G6/00 ,  C08G2/00

Abstract: A process for preparing polyacetals by copolymerization of glyoxylic esters with other copolymerizable monomers in the presence of anionic or cationic polymerization initiators, with or without the introduction of stable end groups and with or without hydrolysis of the copolymerized units of glyoxylic ester present in the copolymer comprises using as monomers cyclic formals derived from diols, homopolymers of formaldehyde, trioxepane or mixtures thereof, although up to 50 % by weight of this group of monomers may be replaced by other customary copolymerizable monomers, and the poly(acetal-carboxylate)s thus obtainable are useful as additives in reduced-phosphate and phosphate-free detergents and cleaners, as water treatment agents and as dispersants for finely divided substances.

公开(公告)号：DE59002861D1

公开(公告)日：1993-10-28

申请号：DE59002861

申请日：1990-05-10

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  HARTMANN HEINRICH ,  GOUSETIS CHARALAMPOS ,  GOECKEL ULRICH ,  RULAND ALFRED

IPC: C02F1/00 ,  C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C02F5/12 ,  C02F5/14 ,  C08F20/02 ,  C08F26/06 ,  C08F220/04 ,  C08F220/06 ,  C08F222/02 ,  C08F226/06

Abstract: PCT No. PCT/EP90/00752 Sec. 371 Date Nov. 1, 1991 Sec. 102(e) Date Nov. 1, 1991 PCT Filed May 10, 1990 PCT Pub. No. WO90/14314 PCT Pub. Date Nov. 29, 1990.Water-soluble copolymers which contain, polymerized in, as characteristic monomers (a) 99 to 50% by weight of monoethylenically unsaturated carboxylic acids with 3 to 8 carbon atoms or their salts and (b) 1 to 50% by weight of N-vinylimidazole or substituted N-vinylimidazoles, their salts or products of quaternization and which have K values of from 10 to 50 are used for water treatment to reduce deposits of scale and sludge in water-conveying systems.

公开(公告)号：DE59001550D1

公开(公告)日：1993-07-01

申请号：DE59001550

申请日：1990-03-14

Applicant: BASF AG

Inventor： MOENCH DIETMAR ,  HARTMANN HEINRICH ,  FREUDENBERG ENRIQUE ,  STANGE ANDREAS

IPC: D21H17/34 ,  D21H17/45 ,  D21H21/06 ,  D21H21/10

Abstract: PCT No. PCT/EP90/00406 Sec. 371 Date Dec. 4, 1990 Sec. 102(e) Date Dec. 4, 1990 PCT Filed Mar. 14, 1990 PCT Pub. No. WO90/11404 PCT Pub. Date Oct. 4, 1990.Paper, board and cardboard are produced by draining a paper stock in the presence of a nonhydrolyzed copolymer which contains, as polymerized units, (a) from 99 to 1 mol % of N-vinylformamide and (b) from 1 to 99 mol % of one or more water-soluble basic monomers of the formula (I) or (II) where R1 is H, CH3 or C2H5, R2, R3 and R4 are each H, CH3, C2H5 or (-CH2-CH2-O-)nH, R5 and R6 are each C1-C10-alkyl, A is C1-C6-alkylene, n is from 1 to 6 and Y(-) is an anion, in an amount of from 0.01 to 3.5% by weight, based on dry paper stock.

公开(公告)号：AT89879T

公开(公告)日：1993-06-15

申请号：AT90904264

申请日：1990-03-14

Applicant: BASF AG

Inventor： MOENCH DIETMAR ,  HARTMANN HEINRICH ,  FREUDENBERG ENRIQUE ,  STANGE ANDREAS

IPC: D21H17/45 ,  D21H21/10

公开(公告)号：FI923753A

公开(公告)日：1993-02-22

申请号：FI923753

申请日：1992-08-20

Applicant: BASF AG

Inventor： MOENCH DIETMAR ,  HARTMANN HEINRICH ,  WEKEL HANS-ULRICH

IPC: C08F2/32 ,  C08L101/00 ,  C09K8/36 ,  C09K23/42

Abstract: Water-in-oil emulsions of water-soluble or water-swellable polymers, in which the oil phase of the emulsion consists of not less than 50% by weight of an oil of vegetable or animal origin, contain, as water-in-oil emulsifiers, compounds which are obtainable by (A) reacting a C10-C22-fatty alcohol with epichlorohydrin in a molar ratio of from 1:0.5 to 1:1.5 to give a glycidyl ether, (B) reacting the glycidyl ether with (1) a saturated C2-C6-alcohol containing from 2 to 6 OH groups or (2) the monoether thereof with a C10-C22-fatty alcohol, in a molar ratio of glycidyl ether to (1) or (2) of from 1:0.5 to 1:6, in the presence of an acid or base and (C) alkoxylating the reaction product from (B) with one or more C2-C4-alkylene oxides in a molar ratio of from 1:1 to 1:6, if necessary, from 5 to 95% by weight of the stated water-in-oil emulsifier being replaced with other water-in-oil emulsifiers.

公开(公告)号：AU628712B2

公开(公告)日：1992-09-17

申请号：AU7017291

申请日：1991-02-01

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  HARTMANN HEINRICH ,  KUD ALEXANDER ,  BAUR RICHARD ,  FELDMANN JOHN ,  RAUBENHEIMER HANS-JUERGEN

IPC: C08F251/00 ,  C11D3/22 ,  C11D3/37

Abstract: Graft copolymers obtainable by free radical-initiated copolymerization of (A) a monomer mixture comprising (a) a monoethylenically unsaturated C4- to C8-dicarboxylic acid, or an anhydride, alkali metal salt or ammonium salt thereof, (b) a monoethylenically unsaturated C3- to C10-carboxylic acid, or an alkali metal salt or ammonium salt thereof, (c) if desired another monoethylenically unsaturated monomer which can be copolymerized with monomer (a) and (b), and (d) a monomer containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of (B) a monosaccharide, oligosaccharide, polysaccharide, oxidatively, hydrolytically or enzymatically degraded polysaccharide, oxidized, hydrolytically or enzymatically degraded polysaccharide, or chemically modified monosaccharide, oligosaccharide or polysaccharide, in the weight ratio (A):(B) of (95 to 20):(5 to 80), a process for the preparation of the graft copolymers, and detergents and cleaners containing the graft copolymers in amounts of from 0.1 to 20% by weight, are described.

公开(公告)号：NO914443L

公开(公告)日：1992-05-15

申请号：NO914443

申请日：1991-11-13

Applicant: BASF AG

Inventor： KONRAD GERD ,  WENDEROTH BERND ,  BARTHOLD KLAUS ,  SCHWARTZ ERICH ,  RAUBENHEIMER HANS-JUERGEN ,  HARTMANN HEINRICH

IPC: C10L1/14 ,  C10L1/18 ,  C10L1/195 ,  C10L1/196 ,  C10L1/197 ,  C10L1/22 ,  C10L1/236

公开(公告)号：FI915128A

公开(公告)日：1992-05-15

申请号：FI915128

申请日：1991-10-30

Applicant: BASF AG

Inventor： KONRAD GERD ,  WENDEROTH BERND ,  BARTHOLD KLAUS ,  SCHWARTZ ERICH ,  RAUBENHEIMER HANS-JUERGEN ,  HARTMANN HEINRICH

IPC: C10L1/14 ,  C10L1/18 ,  C10L1/22 ,  C10L1/236 ,  C10L

Abstract: Petroleum distillates with improved properties contain minor amts. of a conventional ethylene-based flow improver (I) and a copolymer (II) comprising 10-95 mol.% of one or more 1-26C alkyl (meth)acrylates and 5-90 mol.% of one or more ethylenically unsatd. dicarboxylic acids or anhydrides, post-reacted with one or more primary or sec. amines to form the corresp. monoamide or amide/ammonium salt. (I):(II) wt. ratio is 40-95:60-5. - Pref. (I) is a copolymer of ethylene with vinyl acetate, vinyl propionate or ethylhexyl acrylate. (II) is a copolymer of 40-95% lauryl acrylate or 8-18C alkyl acrylate and 5-60% maleic anhydride, post-reacted with di(hydrogenated tallow) amine (DHTA), behenylamine or n-octadecylamine. (II) is opt. grafted onto (I). The distillates contain 50-5,000 ppm (I)+(II).