Compact solid laundry detergent formulation with low inorganic builder content

    公开(公告)号:DE19732688A1

    公开(公告)日:1999-02-04

    申请号:DE19732688

    申请日:1997-07-30

    Applicant: BASF AG

    Abstract: Solid laundry detergent formulation contains (A) 1-30 wt.% inorganic builder based on carbonate, (B) 0-12 wt.% inorganic builder based on crystalline or amorphous aluminosilicates and/or silicates, (C) 0-5 wt.% inorganic builder based on phosphate, (D) 1-40 wt.% glycine-N,N-diacetic acid derivative(s) of formula MOOC-CH(R)-N(CH2COOM)2 (I) as organic builder, (E) 0-40 wt.% anionic surfactant and (F) 0.5-50 wt.% non-ionic surfactant; in which R = (a) 1-30C alkyl or 2-30C alkenyl (which may have up to 5 hydroxyl, sulfate, sulfonate, formyl, 1-4C alkoxy, phenoxy or 1-4C alkoxycarbonyl substituents and up to 5 non-adjacent oxygen (O) and/or nitrogen (N) atoms in the chain), (b) alkoxylate of the formula -(CH2)k-O-(A O)m-(A O)n-Y, (c) phenyl-(1-20 C)-alkyl, (d) 5-6-membered (un)saturated (benzo)-heterocyclyl with up to 3 hetero-atoms selected from N, O and sulfur (S) in the ring; or (e) -A-CH(COOM)-N(CH2COOM)2; A , A = 2-4C 1,2-alkylene; Y = hydrogen (H), 1-12 C alkyl, phenyl, 1- 4 C alkoxycarbonyl or sulfo; k = 1, 2 or 3; m, n = 0-50; m+n \- 2; A = 1-12 C alkylene or a chemical bond; M = H, alkali(ne earth) metal or optionally substituted ammonium.

    Use of new or known amino-, hydroxy-substituted fatty acid or derivative

    公开(公告)号:DE19620613A1

    公开(公告)日:1997-11-27

    申请号:DE19620613

    申请日:1996-05-22

    Applicant: BASF AG

    Abstract: The following compounds are new. A1-CO-OR4 (Ia); A4-CO-NR12R13 (XV); G-CO-NR16R17 (XXI); A3-CO-R8 (VIIIa); and alkoxylated fatty acid derivatives (VII) obtained by reacting a fatty acid derivative of formula A2-CO-R5 (VIII) with 3-15 equivalents alkylene oxide (XXX) per equivalent of group (ix) in (VIII). (XXX) is ethylene oxide, propylene oxide or butylene oxide. Also claimed are 1) use of fatty acids derivatives of formula A1-CO-R1 (I) as surfactants in compositions for cleaning fat-soiled non-textile materials; 2) epoxidised fatty acid amides of formula B3-CO-NR121R13 (XVII) as intermediates for surfactants; 3) mixtures of fatty acids derivatives of formula A41-CO-NR16R17 (XVIII) and E-CO-NR16R17 (XIX) in weight ratio 99:1-1:99; and 4) washing and cleaning compositions containing (VII), (VIIIa) or (XXI), and other additives. A1 = 8-24C unbranched aliphatic group containing one or more groups of formula -CH(NR2R3)-CH(OH)- (ii); A2 = 8-24C unbranched aliphatic group containing one or more groups of formula -CH(NR6R7)-CH(OH)- (ix); A3 = 8-24C unbranched aliphatic group containing one or more groups of formula -CH(NR9R10)-CH(OH)- (ix); A4 = 8-24C unbranched aliphatic group containing one or more groups of formula -CH(NR14R15)-CH(OH)- (xvi); B3 = 8-24C unbranched aliphatic group carrying one or more epoxy groups; A41 = 8-24C unbranched aliphatic group containing one or more groups of formula -CH(NR121R141)-CH(OH)- (ii); E = 8-24C unbranched aliphatic group containing one or more groups of formula -CH(OR18)-CH(OH)- (xx); G = 8-24C unbranched aliphatic group containing one or more groups of formula -CH(OR19)-CH(OH)- (xxi); R1 = N(R2)R3, OH or its alkali or ammonium salt, 1-4C alkoxy, or a residue of a mono-, di- or tri-glyceride, (where the two latter residues may be from natural fatty acids or the same or different A1 residues); R2 = 2-40C hydrophilic group; R3 = H, 1-4C alkyl or R2; R4 = H or alkali or ammonium cation; R5 = N(R6)R7, OH or its alkali or ammonium salt, 1-4C alkoxy, or a residue of a mono-, di- or tri-glyceride, (where the two latter residues may be from natural fatty acids or the same or different A2 residues); R6, R7 = H, 1-6C alkyl, or 1-14 C alkyl (substituted by OH, NH2 and/or CONH2 and/or interrupted by non-adjacent O, NH or N(1-4C)alkyl, and/or COOH or SO3H, or their alkali- or ammonium-salts); R8 = N(R6)R7, OH or its alkali or ammonium salt, 1-4C alkoxy, or a residue of a mono-, di- or tri-glyceride, (where the two latter residues may be from natural fatty acids or the same or different A3 residues); R9 = 1-6C alkyl (optionally substituted by OH, NH2 and/or CONH2 and/or interrupted by non-adjacent NH, and substituted by one SO3H or at least one COOH, or their alkali- or ammonium-salts); R10 = H, or a group as for R9; R12 = hydroxy- and/or amino- substituted 2-40C hydrophilic group; R13 = H, 1-4C alkyl or as for R12; R14 = 1-14C alkyl carrying COOH and/or SO3H groups as free acids and/or as alkali or ammonium salts, and optionally interrupted by non-adjacent O, NH and/or N-(1-4C)alkyl groups; R15 = H, 1-6C alkyl or as for R14; R121, R17 = as for R12 or R14; R141, R17 = H, 1-6C alkyl or as for R12; R18 = 1-4C alkyl; R19 = H or 1-4C alkyl.

    57.
    发明专利
    未知

    公开(公告)号:BRPI0610719A2

    公开(公告)日:2012-10-30

    申请号:BRPI0610719

    申请日:2006-04-13

    Applicant: BASF AG

    Abstract: Mixture (Q) comprises at least two plant protective active agent comprising at least a fungicidal active agent of conazole group (1), at least one plant protection active agent (2), exhibiting solubility in water of 20g/l at 20[deg]C and optionally a copolymer obtained form an ethylenic unsaturated monomer (M) of at least monoethylenic unsaturated monomer (M1) with at least one sulfonic acid group and at least neutral group, and monoethylenic unsaturated monomer (M2). The ratio of (1) and (2) is 1:10-10:1. An independent claim is included for a copolymer comprising a polymer formed from monoethylenic unsaturated monomers (M), at least a monoethylenic unsaturated monomer (M1) with at least one sulfonic acid and at least 1 neutral group and monoethylenic unsaturated monomers (M2a) and (M2b), exhibiting a solubility of less than 50 g/l at 20[deg]C. ACTIVITY : Fungicide. In a test for determining pathogenic fungicidal activity, results showed that a 1:3 mixture (32 ppm) of epoxiconazole and pyraclostrobin reduced the development of the fungus to 2%. MECHANISM OF ACTION : None given.

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