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公开(公告)号:AU2003258544A1
公开(公告)日:2004-03-29
申请号:AU2003258544
申请日:2003-07-30
Applicant: BASF AG
Inventor: SIRCH TILMAN , WARTINI ALEXANDER , DERNBACH MATTHIAS , MELDER JOHANN-PETER
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公开(公告)号:AU2003250113A1
公开(公告)日:2004-02-23
申请号:AU2003250113
申请日:2003-07-18
Applicant: BASF AG
Inventor: DERNBACH MATTHIAS , WARTINI ALEXANDER , SIRCH TILMAN , MELDER JOHANN-PETER
IPC: C07C29/10 , C07C29/141 , C07C29/88 , C07C45/75
Abstract: The invention relates to a method for increasing yield in the production of polyvalent alcohols, especially trimethylolpropane, obtained by condensing formaldehyde with a higher aldehyde. According to the inventive method, acid treatment is carried out on a mixture (high-boiling fraction) that is obtained by reprocessing, contains derivatives of said alcohols and has a higher boiling point than the respective alcohol, and the polyvalent alcohol is recovered from the acid-treated high-boiling fraction. The inventive method is characterised in that the water content of the high-boiling fraction amounts to between 20 and 90 wt. % in relation to the entire mixture of the high-boiling fraction and water.
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53.
公开(公告)号:AU2002217031A1
公开(公告)日:2003-06-10
申请号:AU2002217031
申请日:2001-11-15
Applicant: BASF AG
Inventor: WARTINI ALEXANDER , SIRCH TILMAN , DERNBACH MATTHIAS , MELDER JOHANN-PETER
Abstract: The invention relates to a method for removing acetals containing formaldehyde from polyvalent alcohols, especially trimethylolpropane. The inventive method is characterised in that the polyvalent alcohol is liberated of low-boiling constituents after it has been produced by distillation, is then subjected to tempering and is repurified, preferably by means of distillation.
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公开(公告)号:AT228924T
公开(公告)日:2002-12-15
申请号:AT98947430
申请日:1998-08-13
Applicant: BASF AG
Inventor: BERBNER HEINZ , ETLING HANS , GUENTHER ERHARD , SIRCH TILMAN , ZETTLER HANS DIETER
IPC: B29C48/38 , B29C47/00 , B29C48/76 , B29C67/24 , C08G8/00 , C08G12/12 , C08G12/32 , C08G14/00 , B29C47/50 , B29C47/76
Abstract: The invention relates to a continuous process for preparing aminoplastics and/or phenolics, in which a precondensate solution is prepared in a first extruder (14), the precondensate solution is continuously fed, with addition of additives, to a second extruder (20) with partial filling in the feed section (E) and devolatilization section (G), devolatilized in the second extruder (20) and then formed to give a molding composition or an end product. The process is particularly suitable for preparing melamine resins, in particular melamine-formaldehyde resins, as well as for preparing urea-formaldehyde resins.
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公开(公告)号:MY137827A
公开(公告)日:2009-03-31
申请号:MYPI20054914
申请日:2005-10-19
Applicant: BASF AG
Inventor: SIRCH TILMAN , TEBBEN GERD-DIETER DR , HECK LUDWIG E , DIEFENBACHER ARMIN DR , KRAUSE ALFRED DR , BORGEL FRANZ
Abstract: 1 7 PREPARATION OF 1,6-HEXANEDIOL ABSTRACT 5 THE PRESENT INVENTION PROVIDES A PROCESS FOR PREPARING 1,6-HEXANEDIOL FROM A CARBOXYLIC ACID MIXTURE WHICH COMPRISES ADIPIC ACID, 6-HVBROXYCAPROIC ACID AND SMALL AMOUNTS OF 11,4-CYCLOHEXANCCLIOLS AND IS OBTAINED AS A BY-PRODUCT IN THE OXIDATION OF CYCLOHEXANE TO CVCLOHEXANONELCYCLOHEXANOL WITH OXYGEN OR OXVGCN-CONTAININO CASES AND BY %,ALEI EXTRACTION OL THE REACTION MIXTURE, BY ESIERILICATION OF ZHE ACIDS AND 10 HYDROGENATION, IN WHICH A) THE MONO- AND DICARBOXYLIC ACIDS PRESENT IN THE AQUEOUS DICARBOXYLIC ACID MIXTURE ARE REACTED WITH A LOW MOLECULAR WEIGHT ALCOHOL TO GIVE THE CORRESPONDING C@RBOXYLIC ESTERS, 1 5 B) THE RESULTING ESTERIFICATION MIXTURE IS FREED OF EXCESS ALCOHOL AND LOW BOILERS IN A FIRST DISTILLATION STAGE, C) A SEPARATION OF THE BOTTOM PRODUCT IS CARRIED OUT IN A SECOND DISTILLATION STAGE INTO 20 AN ESTER FRACTION SUBSTANTIALLY FREE OF 1,4-CYCLOHEXANECLIOLS AND A FRACTION COMPRISING AT LEAST THE MAJORITY OF THE 1,4-CYCLOHEXANEDIOLS, D) THE ESTER FRACTION SUBSTANTIALLY FREE OF 1,4-CYCLOHEXANEDIOLS IS CATAL ICALLY YT HYDROGENATED AND 25 E) 1,6-HEXANEDIAL IS OBTAINED IN A PURIFYING DISTILLATION STAGE FROM THE HYDROGENATION EFFLUENT WHILE REMOVING AN ALCOHOL-LOW BOILER MIXTURE IN A MANNER KNOWN PER SE, WHEREIN ALCOHOL IS REMOVED BY A MEMBRANE SYSTEM FROM THE MIXTURES, OBTAINED AFTER THE ESTERIFICATION IN STAGE B) AND/OR AFTER THE HYDROGENATION IN STAGE E), OF 30 ALCOHOLS AND LOW BOILERS AND RECYCLED INTO THE ESTERIFICATION. Z)OAM4 I Q /I O/O@-
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公开(公告)号:AT376987T
公开(公告)日:2007-11-15
申请号:AT05759413
申请日:2005-07-07
Applicant: BASF AG
Inventor: HAUNERT ANDREA , PINKOS ROLF , KRUG THOMAS , SIRCH TILMAN , KOCH MICHAEL , TEBBEN GERD-DIETER
IPC: C07C29/145 , C07C29/149 , C07C31/20
Abstract: The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
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公开(公告)号:MY128842A
公开(公告)日:2007-02-28
申请号:MYPI20024454
申请日:2002-11-27
Applicant: BASF AG
Inventor: SIRCH TILMAN , KAIBEL GERD DR , WARTINI ALEXANDER DR , DERNBACH MATTHIAS DR
IPC: C07C29/38 , C07C29/80 , C07B61/00 , C07C29/141 , C07C31/22
Abstract: TRIMETHYLOLPROPANE IS ISOLATED FROM A REACTION MIXTURE WHICH HAS BEEN OBTAINED BY REACTION OF N-BUTYRALDEHYDE WITH FORMALDEHDE IN THE PRESENCE OF A BASE AND, IF APPROPRIATE, HYDROGENATION OF THE RESULTING MIXTURE BY DISTILLING THE MIXTURE BY MEANS OF A DIVIDING WALL COLUMN OR A DISTILLATION COLUMN WITH A PRECOLUMN OR A DISTILLATION COLUMN WITH AN AFTER-COLUMN. THE PROCESS HAS LOW CAPITAL COSTS AND A LOW ENERGY CONSUMPTION AND GIVES REDUCED FORMATION OF HIGH-BOILING BY-PRODUCTS.
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公开(公告)号:DE50208083D1
公开(公告)日:2006-10-19
申请号:DE50208083
申请日:2002-10-18
Applicant: BASF AG
Inventor: KOCH MICHAEL , WARTINI ALEXANDER , SIRCH TILMAN , DERNBACH MATTHIAS
Abstract: A method for removing trialkyl ammonium formate from a methylol alkanes obtained by condensation of formaldehyde with a higher aldehyde. The invention is characterized in that trialkyl ammonium formate is decomposed at a high temperature using catalysts containing at least one metal from groups 8-12 of the classification of elements in the presence of gas containing hydrogen. The method makes it possible to separate trialkyl ammonium formate according to the organic Cannizzaro method and according to the hydrogenation method.
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公开(公告)号:DE102004021985A1
公开(公告)日:2005-11-24
申请号:DE102004021985
申请日:2004-05-04
Applicant: BASF AG
Inventor: KASHANI-SHIRAZI NAWID , SIEGERT MARKUS , SIRCH TILMAN , KAIBEL BJOERN
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公开(公告)号:DE10334489A1
公开(公告)日:2005-02-24
申请号:DE10334489
申请日:2003-07-29
Applicant: BASF AG
Inventor: KOCH MICHAEL , WARTINI ALEXANDER , MAAS STEFFEN , SIRCH TILMAN , DERNBACH MATTHIAS
IPC: B01J21/06 , B01J23/46 , B01J35/00 , B01J35/10 , B01J37/06 , B01J37/14 , B01J37/18 , C07C29/88 , C07C29/74
Abstract: Removal of trialkylammonium formates (TAAF) from methylolalkanes obtained by condensation of formaldehyde with higher aldehydes involves decomposing the TAAF at elevated temperature on a titanium dioxide- supported ruthenium-containing catalyst in presence of a hydrogen-containing gas. An independent claim is also included for such a catalyst in which commercially-available titanium dioxide is treated before or after shaping to form the support with 0.1-30 wt.% of an acid in which the TiO 2 is difficultly soluble.
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