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公开(公告)号:HU0300215A2
公开(公告)日:2003-07-28
申请号:HU0300215
申请日:2001-02-28
Applicant: BASF AG
Inventor: CLOSS FRIEDRICH , GOETZ ROLAND , HENKELMANN JOCHEM , KNEUPER HEINZ-JOSEF , STAMM ARMIN
Abstract: Production of chloroalkanoyl chlorides (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. Production of chloroalkanoyl chlorides of formula (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone of formula (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. [Image] R1>, R2>H or R; R : halo, nitro, cyano or an organic group containing carbon; Y : optionally R-substituted 1-10 C alkylene, which may have a (thio)ether, tertiary amino or keto group in the chain; and R groups on Y, R1> and/or R2>can be linked to form a non-aromatic system.
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公开(公告)号:DE59905678D1
公开(公告)日:2003-06-26
申请号:DE59905678
申请日:1999-10-29
Applicant: BASF AG
Inventor: STAMM ARMIN , HENKELMANN JOCHEM
Abstract: The invention relates to a process for the preparation of acid chlorides by reaction of carboxylic acids, carboxylic anhydrides, cyclic carboxylic esters or sulfonic acids with phosgene in the presence of a catalytic amount of a compound from the group consisting of N,N,N',N'-tetrasubstituted amidinium halides (I), N,N,N'-trisubstituted amidinium hydrohalides (II) and N,N,N'-trisubstituted amidines (III).
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公开(公告)号:HU222026B1
公开(公告)日:2003-03-28
申请号:HU0003768
申请日:1998-08-28
Applicant: BASF AG
Inventor: HENKELMANN JOCHEM , STAMM ARMIN , WEBER THEODOR , WEYER HANS-JUERGEN
IPC: B01J31/02 , C07B61/00 , C07C329/02
Abstract: PCT No. PCT/EP98/05525 Sec. 371 Date Feb. 17, 2000 Sec. 102(e) Date Feb. 17, 2000 PCT Filed Aug. 28, 1998 PCT Pub. No. WO99/11611 PCT Pub. Date Mar. 11, 1999A catalyst used for preparing thiochloroformates by reacting thiols with phosgene is a cyclic urea or cyclic thiourea which may be in the form of a salt obtainable by reaction with a hydrohalic acid or phosgene.
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公开(公告)号:BR0108422A
公开(公告)日:2003-03-25
申请号:BR0108422
申请日:2001-02-16
Applicant: BASF AG
Inventor: HENKELMANN JOCHEN , MAAS HEIKO , SCHULZ GERHARD , STAMM ARMIN , RINK HEINZ-PETER , JUNG WERNER-ALFONS , SCHWAB PETER
IPC: C07C263/10 , C07C265/14 , C08G18/62 , C08G18/72 , C08G18/73 , C09D175/04 , C09J175/04
Abstract: A description is given of polyisocyanates of the formula I in which R and R' are identical or different and are alkyl groups having 1-4 carbon atoms and n is on average from 1.5 to 5 and also of a process for preparing these polyisocyanates in which a polyamine of the formula II in which R, R', and n are as defined above, is reacted with phosgene. The new polyisocyanates are suitable for producing crosslinked polyurethanes from reaction mixtures with low solvent content and for producing coating compositions or adhesives. Also described are the coating compositions and adhesives, and their use.
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公开(公告)号:CZ20022975A3
公开(公告)日:2003-02-12
申请号:CZ20022975
申请日:2001-02-28
Applicant: BASF AG
Inventor: STAMM ARMIN , GOTZ ROLAND , HENKELMANN JOCHEM , CLOSS FRIEDRICH , KNEUPER HEINZ-JOSEF
Abstract: Production of chloroalkanoyl chlorides (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. Production of chloroalkanoyl chlorides of formula (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone of formula (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. [Image] R1>, R2>H or R; R : halo, nitro, cyano or an organic group containing carbon; Y : optionally R-substituted 1-10 C alkylene, which may have a (thio)ether, tertiary amino or keto group in the chain; and R groups on Y, R1> and/or R2>can be linked to form a non-aromatic system.
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公开(公告)号:ES2174494T3
公开(公告)日:2002-11-01
申请号:ES98948890
申请日:1998-08-28
Applicant: BASF AG
Inventor: WEYER HANS-JURGEN , STAMM ARMIN , WEBER THEODOR , HENKELMANN JOCHEM
IPC: B01J31/02 , C07B61/00 , C07C329/02
Abstract: PCT No. PCT/EP98/05525 Sec. 371 Date Feb. 17, 2000 Sec. 102(e) Date Feb. 17, 2000 PCT Filed Aug. 28, 1998 PCT Pub. No. WO99/11611 PCT Pub. Date Mar. 11, 1999A catalyst used for preparing thiochloroformates by reacting thiols with phosgene is a cyclic urea or cyclic thiourea which may be in the form of a salt obtainable by reaction with a hydrohalic acid or phosgene.
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公开(公告)号:CA2444800A1
公开(公告)日:2002-10-31
申请号:CA2444800
申请日:2002-04-17
Applicant: BASF AG
Inventor: RITTINGER STEFAN , KNEUPER HEINZ-JOSEF , STAMM ARMIN , WEBER THEODOR , HEILIG MANFRED , DRANSFELD PETER , SCHILDBERG HANS-PETER
Abstract: The invention relates to a method for the intrinsically safe handling of 3- chlorpropyne in the presence of a diluent, which has a boiling point under normal pressure in the range of -50 ~C (223 K) to 200 ~C (473 K). According to the method, the concentration of 3-chloropropyne in the liquid phase and in the gaseous phase is maintained below the concentrations at which deflagrati on occurs, by means of the type and quantity of the diluent, the temperature an d the total pressure of the system. The invention also relates to the use of 3 - chloropropyne produced, stored or transported in this manner for the synthes is of dyes, pharmaceutical and agricultural active ingredients, electroplating auxiliary agents, disinfection agents, steroids and growth hormones.
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公开(公告)号:BR0016216A
公开(公告)日:2002-09-10
申请号:BR0016216
申请日:2000-11-27
Applicant: BASF AG
Inventor: GOETZ ROLAND , GOETZ NORBERT , KEIL MICHAEL , WOLF BERND , STEINMETZ ADRIAN , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: A process for preparing o-chloromethylbenzoyl chlorides of the formula I,in which R to R can be identical or different and are hydrogen, C1-C4-alkyl, halogen or trifluoromethyl, by reacting benzo-fused lactones of the formula II,in which R to R are as defined above, with thionyl chloride, which comprises carrying out the reaction in the presence of catalytic amounts of boric acid, boric anhydride, borate, boronic acid or boronic acid esters and catalytic amounts of a quaternary ammonium salt is described.
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公开(公告)号:BR0016244A
公开(公告)日:2002-08-27
申请号:BR0016244
申请日:2000-11-27
Applicant: BASF AG
Inventor: STAMM ARMIN , GOETZ ROLAND , GOETZ NORBERT , HENKELMANN JOCHEM , KEIL MICHAEL , WOLF BERND , STEINMETZ ADRIAN
Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R 1 to R 4 can be the same or different and represent hydrogen C 1 -C 4 alkyl, halogen or trifluoromethyl, by reaction benzo condensed lactones of formula (II), in which R 1 to R 4 have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.
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公开(公告)号:DE59803565D1
公开(公告)日:2002-05-02
申请号:DE59803565
申请日:1998-11-21
Applicant: BASF AG
Inventor: WEYER HANS-JUERGEN , STAMM ARMIN , WEBER THEODOR , HENKELMANN JOCHEM
Abstract: The present invention provides process for the preparation of chlorocarbonyl chlorides of the formula IwhereR1 is for example hydrogen or C1- to C20-alkyl andY is for example a saturated or mono- or polyolefinically unsaturated C2-C8-alkylene chain,by reacting lactones with a chlorinating agent in the presence of a urea compound.
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