METHOD FOR PRODUCING CHLOROCARBOXYLIC ACID CHLORIDES

    公开(公告)号:HU0300215A2

    公开(公告)日:2003-07-28

    申请号:HU0300215

    申请日:2001-02-28

    Applicant: BASF AG

    Abstract: Production of chloroalkanoyl chlorides (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. Production of chloroalkanoyl chlorides of formula (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone of formula (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. [Image] R1>, R2>H or R; R : halo, nitro, cyano or an organic group containing carbon; Y : optionally R-substituted 1-10 C alkylene, which may have a (thio)ether, tertiary amino or keto group in the chain; and R groups on Y, R1> and/or R2>can be linked to form a non-aromatic system.

    62.
    发明专利
    未知

    公开(公告)号:DE59905678D1

    公开(公告)日:2003-06-26

    申请号:DE59905678

    申请日:1999-10-29

    Applicant: BASF AG

    Abstract: The invention relates to a process for the preparation of acid chlorides by reaction of carboxylic acids, carboxylic anhydrides, cyclic carboxylic esters or sulfonic acids with phosgene in the presence of a catalytic amount of a compound from the group consisting of N,N,N',N'-tetrasubstituted amidinium halides (I), N,N,N'-trisubstituted amidinium hydrohalides (II) and N,N,N'-trisubstituted amidines (III).

    Process for preparing chlorocarboxylic acids

    公开(公告)号:CZ20022975A3

    公开(公告)日:2003-02-12

    申请号:CZ20022975

    申请日:2001-02-28

    Applicant: BASF AG

    Abstract: Production of chloroalkanoyl chlorides (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. Production of chloroalkanoyl chlorides of formula (I) with a (substituted) 1-10 carbon (hetero)alkylene chain, by reacting a lactone of formula (II) with a chlorinating agent in the presence of a chlorination catalyst, is carried out in the presence of a boron compound. [Image] R1>, R2>H or R; R : halo, nitro, cyano or an organic group containing carbon; Y : optionally R-substituted 1-10 C alkylene, which may have a (thio)ether, tertiary amino or keto group in the chain; and R groups on Y, R1> and/or R2>can be linked to form a non-aromatic system.

    66.
    发明专利
    未知

    公开(公告)号:ES2174494T3

    公开(公告)日:2002-11-01

    申请号:ES98948890

    申请日:1998-08-28

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP98/05525 Sec. 371 Date Feb. 17, 2000 Sec. 102(e) Date Feb. 17, 2000 PCT Filed Aug. 28, 1998 PCT Pub. No. WO99/11611 PCT Pub. Date Mar. 11, 1999A catalyst used for preparing thiochloroformates by reacting thiols with phosgene is a cyclic urea or cyclic thiourea which may be in the form of a salt obtainable by reaction with a hydrohalic acid or phosgene.

    METHOD FOR THE INTRINSICALLY SAFE HANDLING OF 3-CHLORPROPYNE

    公开(公告)号:CA2444800A1

    公开(公告)日:2002-10-31

    申请号:CA2444800

    申请日:2002-04-17

    Applicant: BASF AG

    Abstract: The invention relates to a method for the intrinsically safe handling of 3- chlorpropyne in the presence of a diluent, which has a boiling point under normal pressure in the range of -50 ~C (223 K) to 200 ~C (473 K). According to the method, the concentration of 3-chloropropyne in the liquid phase and in the gaseous phase is maintained below the concentrations at which deflagrati on occurs, by means of the type and quantity of the diluent, the temperature an d the total pressure of the system. The invention also relates to the use of 3 - chloropropyne produced, stored or transported in this manner for the synthes is of dyes, pharmaceutical and agricultural active ingredients, electroplating auxiliary agents, disinfection agents, steroids and growth hormones.

    68.
    发明专利
    未知

    公开(公告)号:BR0016216A

    公开(公告)日:2002-09-10

    申请号:BR0016216

    申请日:2000-11-27

    Applicant: BASF AG

    Abstract: A process for preparing o-chloromethylbenzoyl chlorides of the formula I,in which R to R can be identical or different and are hydrogen, C1-C4-alkyl, halogen or trifluoromethyl, by reacting benzo-fused lactones of the formula II,in which R to R are as defined above, with thionyl chloride, which comprises carrying out the reaction in the presence of catalytic amounts of boric acid, boric anhydride, borate, boronic acid or boronic acid esters and catalytic amounts of a quaternary ammonium salt is described.

    69.
    发明专利
    未知

    公开(公告)号:BR0016244A

    公开(公告)日:2002-08-27

    申请号:BR0016244

    申请日:2000-11-27

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R 1 to R 4 can be the same or different and represent hydrogen C 1 -C 4 alkyl, halogen or trifluoromethyl, by reaction benzo condensed lactones of formula (II), in which R 1 to R 4 have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.

    70.
    发明专利
    未知

    公开(公告)号:DE59803565D1

    公开(公告)日:2002-05-02

    申请号:DE59803565

    申请日:1998-11-21

    Applicant: BASF AG

    Abstract: The present invention provides process for the preparation of chlorocarbonyl chlorides of the formula IwhereR1 is for example hydrogen or C1- to C20-alkyl andY is for example a saturated or mono- or polyolefinically unsaturated C2-C8-alkylene chain,by reacting lactones with a chlorinating agent in the presence of a urea compound.

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