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    MIXTURE OF AT LEAST TWO ALKOXYLATED ALCOHOLS AND ITS USE AS ANTIFOAM TENSIDE ADDITIVE IN CLEANING PRODUCTS FOR MECHANICAL WASHING PROCESSES
    71.
    发明专利
    MIXTURE OF AT LEAST TWO ALKOXYLATED ALCOHOLS AND ITS USE AS ANTIFOAM TENSIDE ADDITIVE IN CLEANING PRODUCTS FOR MECHANICAL WASHING PROCESSES 未知

    公开(公告)号：CA2104468A1

    公开(公告)日：1992-08-23

    申请号：CA2104468

    申请日：1992-02-11

    Applicant: BASF AG

    Inventor： STOECKIGT DIETER ,  BAUR RICHARD ,  TRAPP HORST ,  PERNER JOHANNES

    IPC: C11D1/722 ,  C11D1/825 ,  C11D3/00 ,  C11D17/00 ,  C07C43/04 ,  C07C41/03

    Abstract: Preparation of mixture of alkoxylated alcohols and use thereof as a foam-suppressing surfactant additament in cleaning compositions for mechanized cleaning processes. Preparation of a mixture of alkoxylated alcohols I R-O-(C2H4O)x-(C3H6O)y-H (I) where x is an average degree of ethoxylation of from 1 to 12 and y is an average degree of propoxylation of from 1 to 15, comprises mixing at least two mixtures of alcohols of the general formula R-O-H where one alcohol mixture carries straightchain or branched C8-C18-alkyl groups as the radical R and one other alcohol mixture carries straight-chain or branched C10-C20-alkyl groups as the radical R, subject to the proviso that the two radicals R differ by at least 0.5 in the average number of carbon atoms, and the two alcohol mixtures are present in a weight ratio of from 10:90 to 90:10, with one another and reacting this mixture first with the corresponding amount of ethylene oxide and then with the corresponding amount of propylene oxide. This mixture is useful as a foam-suppressing surfactant additament in cleaning compositions for mechanized cleaning processes.

    USE OF HETEROCYCLIC COMPOUNDS AS BLEACH ACTIVATORS OR OPTICAL LIGHTENERS IN WASHING AND CLEANING AGENTS
    72.
    发明专利
    USE OF HETEROCYCLIC COMPOUNDS AS BLEACH ACTIVATORS OR OPTICAL LIGHTENERS IN WASHING AND CLEANING AGENTS 未知

    公开(公告)号：AU6739490A

    公开(公告)日：1991-06-26

    申请号：AU6739490

    申请日：1990-11-13

    Applicant: BASF AG

    Inventor： DUNG BERNHARD ,  TRIESELT WOLFGANG ,  HAHN ERWIN ,  PERNER JOHANNES ,  OFTRING ALFRED

    IPC: C11D3/28 ,  C07D265/22 ,  C11D3/39 ,  C11D3/42

    Abstract: PCT No. PCT/EP90/01897 Sec. 371 Date Mar. 3, 1992 Sec. 102(e) Date Mar. 3, 1992 PCT Filed Nov. 13, 1990 PCT Pub. No. WO91/08279 PCT Pub. Date Jun. 13, 1991.Heterocyclic compounds which are useful as bleach activators or optical brighteners in washing and cleaning agents have the formula (* CHEMICAL STRUCTURE *) I where the variables have the following meanings: X is O, S or the group N-R3, where R3 is hydrogen, C1-C25-alkyll C1-C25-acyl or an aryl group of up to 12 carbon atoms, Y is CH or N, R1 for X=S or N-R3 is hydrogen, a C1-C25-alkyl or C2-C25-alkenyl group or a phenyl radical which may be additionally substituted by one or two C1-C4-alkyl, C1-C4-alkoxy, hydroxyl, carboxyl, sulfo, amino, C1-C4-acylamino, nitro or cyano groups or chlorine or bromine atoms, which substituents, if there are two of them, may be identical or different, R1 for X=O is phenyl, o-, m- or p-tolyl, p-chlorophenyl, m-nitrophenyl, m-methoxyphenyl or m-methylsulfonylphenyl, R2 for X=S or N-R3 is hydrogen, a C1-C4-alkyl, C1-C4-alkoxy, hydroxyl, carboxyl, sulfo, amino or C1-C4-acylamino group or a chlorine or bromine atom, and R2 for X=O is hydrogen.

    LIQUID DETERGENT WITH COPOLYMER ADDITIVE
    74.
    发明专利
    LIQUID DETERGENT WITH COPOLYMER ADDITIVE 未知

    公开(公告)号：AU4450589A

    公开(公告)日：1990-05-17

    申请号：AU4450589

    申请日：1989-11-09

    Applicant: BASF AG

    Inventor： PERNER JOHANNES ,  DIESSEL PAUL ,  HARTMANN HEINRICH ,  DENZINGER WALTER ,  OFTRING ALFRED ,  SCHOENLEBEN WILLIBALD

    IPC: C11D3/32 ,  C11D3/37 ,  C08L33/26 ,  C08L33/02 ,  C08L35/00 ,  C08L35/02 ,  C08L33/04 ,  C08L23/02 ,  C08L25/04 ,  C08L25/16 ,  C08L29/10 ,  C08L31/02

    Abstract: The use of copolymers which contain as essential copolymerised units (a) 50 to 99 mol% of units of monoethylenically unsaturated (a) C3- to C8-monocarboxylic acids, monoethylenically unsaturated C4- to C8-dicarboxylic acids, hemiesters of monoethylenically unsaturated C4- to C8-dicarboxylic acids, esters of monoethylenically unsaturated C3- to C8-carboxylic acids, C2- to C30-olefins, styrene, C1- to C3-alkylstyrenes, C1- to C28-alkyl vinyl ethers, vinyl esters of saturated C1- to C8- carboxylic acids or mixtures of units of these monomers and (b) 50 to 1 mol% of units of amides of monoethylenically unsaturated C3- to C8-carboxylic acids with amide groups of the structure … … in which R = C8- to C28- alkyl, … … R , R = H, CH3, C2H5 R = C1- to C28-alkyl, n = 2 to 100 and R = H, R have K values of 8 to 200, or of salts of these copolymers, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and aqueous liquid detergent compositions which contain these copolymers.

    PREPARATION OF THE TRISODIUM SALT OF ISOSERINE-N, N-DIACETIC ACID
    75.
    发明专利
    PREPARATION OF THE TRISODIUM SALT OF ISOSERINE-N, N-DIACETIC ACID 未知

    公开(公告)号：AU4095589A

    公开(公告)日：1990-03-08

    申请号：AU4095589

    申请日：1989-09-01

    Applicant: BASF AG

    Inventor： WIDDER RUDI ,  GOUSETIS CHARALAMPOS ,  PERNER JOHANNES ,  WOLF HELMUT ,  BOCHNITSCHEK WERNER ,  OFTRING ALFRED

    IPC: C07C227/12 ,  C07C229/22 ,  C07C99/00 ,  C07C101/30

    Abstract: Preparation of the trisodium salt of isoserine-N,N-diacetic acid (I) by reaction of acrylonitrile with aqueous hydrogen peroxide to give glycidamide (II) and further reaction of II with the disodium salt of iminodiacetic acid (III) to give I, by carrying out the process continuously and, in it, successively a) reacting together acrylonitrile and aqueous hydrogen peroxide at pH 7-8 and 30-60 DEG C, b) removing unreacted acrylonitrile by distillation, c) passing the reaction mixture over a solid hydrogen peroxide-decomposing catalyst, d) reacting the aqueous solution of II, obtained in this way, with III at pH 7-9 and 40-90 DEG C, e) reacting the resulting solution with a basic sodium compound at pH 9-14 and 60-95 DEG C, f) removing the ammonia which is produced by distillation and g) if desired, working up the aqueous solution of I, obtained in this way, in a manner known per se to give solid I.

    78.
    发明专利
    未知

    公开(公告)号：DE50006188D1

    公开(公告)日：2004-05-27

    申请号：DE50006188

    申请日：2000-11-21

    Applicant: BASF AG

    Inventor： KRONER MATTHIAS ,  BUECHNER KARL-HEINZ ,  PERNER JOHANNES

    IPC: C04B24/26 ,  C04B24/32 ,  C08F2/06 ,  C08F8/44 ,  C08F220/28 ,  C08F290/06 ,  C08F290/14 ,  C08G65/332 ,  C08L71/02

    Abstract: The invention relates to a process for the preparation of water-soluble polymers containing polyalkylene glycol ether side chains and having molecular weights of from 15,000 to 65,000 by solution polymerization of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols which are masked on the end groups at one end, if desired together with another monomer in at least one hydrocarbon at monomer concentrations of from 70 to 95% by weight in the presence of free-radical-forming polymerization initiators and, if desired, polymerization regulators at temperatures of up to 200° C., removal of the solvent used in the solution polymerization, and dissolution of the polymers in water to give from 50 to 80% strength by weight solutions, with polymers containing acid groups being neutralized if desired.

    79.
    发明专利
    未知

    公开(公告)号：AT264877T

    公开(公告)日：2004-05-15

    申请号：AT00979613

    申请日：2000-11-21

    Applicant: BASF AG

    Inventor： KRONER MATTHIAS ,  BUECHNER KARL-HEINZ ,  PERNER JOHANNES

    IPC: C04B24/26 ,  C04B24/32 ,  C08F2/06 ,  C08F8/44 ,  C08F220/28 ,  C08F290/06 ,  C08F290/14 ,  C08G65/332 ,  C08L71/02

    Abstract: The invention relates to a process for the preparation of water-soluble polymers containing polyalkylene glycol ether side chains and having molecular weights of from 15,000 to 65,000 by solution polymerization of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols which are masked on the end groups at one end, if desired together with another monomer in at least one hydrocarbon at monomer concentrations of from 70 to 95% by weight in the presence of free-radical-forming polymerization initiators and, if desired, polymerization regulators at temperatures of up to 200° C., removal of the solvent used in the solution polymerization, and dissolution of the polymers in water to give from 50 to 80% strength by weight solutions, with polymers containing acid groups being neutralized if desired.

    80.
    发明专利
    未知

    公开(公告)号：DE50101617D1

    公开(公告)日：2004-04-08

    申请号：DE50101617

    申请日：2001-03-27

    Applicant: BASF AG

    Inventor： KRONER MATTHIAS ,  PERNER JOHANNES ,  BUECHNER KARL-HEINZ ,  WILD JOCHEN ,  PFISTER JUERGEN

    IPC: C08G81/02 ,  C04B24/26 ,  C08F8/14 ,  C08F8/30

    Abstract: Polymers containing acid groups are modified by reaction of(a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4,with(b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acidsat up to 250° C.

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