公开(公告)号：MY117553A

公开(公告)日：2004-07-31

申请号：MYPI9700831

申请日：1997-03-01

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS ,  STEIN FRANK ,  RUST HARALD ,  BAUR KARL GERHARD ,  FISCHER ROLF ,  PINKOS ROLF DR

IPC: B01J23/80 ,  C07C29/149 ,  B01J23/889 ,  C07B61/00 ,  C07C31/20

Abstract: 1,6-HEXANEDIOL IS PREPARED FROM A CARBOXYLIC ACID MIXTURE COMPRISING ADIPIC ACID, 6-HYDROXYCAPROIC ACID AND SMALL AMOUNTS OF 1,4- CYCLOHEXANEDIOLS WHICH IS OBTAINED AS A BY-PRODUCT IN THE OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE/CYCLOHEXANOL BY WATER EXTRACTION OF THE REACTION MIXTURE, BY ESTERIFICATION OF THE ACIDS AND HYDROGENATION WHEREIN A) THE MONOCARBOXYLIC AND DICARBOXYLIC ACIDS PRESENT IN THE AQUEOUS DICARBOXYLIC ACID MIXTURE ARE REACTED WITH A LOW MOLECULAR WEIGHT ALCOHOL TO GIVE THE CORRESPONDING CARBOXYLIC ESTERS, B) THE RESULTING ESTERIFICATION MIXTURE IS FREED OF EXCESS ALCOHOL AND LOW BOILERS IN A FIRST DISTILLATION STAGE, C) THE BOTTOMS ARE FRACTIONATED IN A SECOND DISTILLATION STAGE TO GIVE AN ESTER FRACTION ESSENTIALLY FREE OF 1,4-CYCLOHEXANEDIOSL AND A FRACTION COMPRISING AT LEAST THE MAJOR PART OF THE 1,4-CYCLOHEXANEDIOLS, D) THE ESTER FRACTION ESSENTIALLY FREE OF 1,4-CYCLOHEXANEDIOLS IS CATALYTICALLY HYDROGENATED AND E) IN A PURE DISTILLATION STAGE, 1,6-HEXANEDIOL IS ISOLATED FROM THE HYDROGENATION PRODUCT IN A MANNER KNOWN PER SE. 3

公开(公告)号：DK1008573T3

公开(公告)日：2002-07-15

申请号：DK99122885

申请日：1999-11-18

Applicant: BASF AG

Inventor： PINKOS ROLF DR

IPC: B01J31/24 ,  C07B61/00 ,  C07C5/05 ,  C07C5/09 ,  C07C13/263 ,  C07C13/275

Abstract: A carboxylic acid is used in a process to hydrogenate polyene compounds to monoenes using a ruthenium catalyst. A process to hydrogenate a polyene to a monoene uses a ruthenium catalyst in the presence of a carboxylic acid.

公开(公告)号：AT219035T

公开(公告)日：2002-06-15

申请号：AT99122885

申请日：1999-11-18

Applicant: BASF AG

Inventor： PINKOS ROLF DR

IPC: B01J31/24 ,  C07B61/00 ,  C07C5/05 ,  C07C5/09 ,  C07C13/263 ,  C07C13/275

Abstract: A carboxylic acid is used in a process to hydrogenate polyene compounds to monoenes using a ruthenium catalyst. A process to hydrogenate a polyene to a monoene uses a ruthenium catalyst in the presence of a carboxylic acid.

公开(公告)号：DE19756913A1

公开(公告)日：1999-06-24

申请号：DE19756913

申请日：1997-12-19

Applicant: BASF AG

Inventor： BRUNNER MELANIE DR ,  BOETTCHER ARND DR ,  BREITSCHEIDEL BORIS DR ,  HALBRITTER KLAUS DR ,  HENKELMANN JOCHEM DR ,  THIL LUCIEN DR ,  PINKOS ROLF DR

IPC: C07C51/36 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12 ,  B01J23/46 ,  C08K5/10

Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.

公开(公告)号：DE19739441A1

公开(公告)日：1999-03-11

申请号：DE19739441

申请日：1997-09-09

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  LIANG SHELUE DR ,  PINKOS ROLF DR ,  STEIN FRANK DR

IPC: B01J21/04 ,  B01J21/06 ,  B01J23/06 ,  B01J23/10 ,  C07B61/00 ,  C07C45/54 ,  C07C49/395 ,  C07C51/377 ,  C07C61/20 ,  C07C67/317 ,  C07C67/333 ,  C07C69/74 ,  C07C51/347 ,  C07C45/48 ,  C07D223/10

Abstract: The invention relates to a method for producing cyclopentanone and cyclopentene-1-carboxylic acid or their esters of formula (I) COOR, wherein R represents hydrogen or an aliphatic radical with 1 to 6 C-atoms or a cycloaliphatic, araliphatic or aromatic radical with 6 to 12 C-atoms. According to said method, compounds of formula (II) X-(CH2)4-COOR, wherein X represents a formyl- or hydroxymethyl radical and R has the meaning given above, and/or compounds which can be converted into compounds of formula (II) with water or alcohols ROH under the reaction conditions are heated in the gaseous or liquid phase to temperatures of 200 to 450 DEG C in the presence of heterogeneous oxidic catalysts.

公开(公告)号：DE19727715A1

公开(公告)日：1999-01-07

申请号：DE19727715

申请日：1997-06-30

Applicant: BASF AG

Inventor： MASSONNE KLEMENS DR ,  SCHUBERT ERICH ,  KRUG GEORG ,  PINKOS ROLF DR ,  KARCHER MICHAEL DR ,  KAIBEL GERD DR

IPC: B01D61/14 ,  B01D63/06 ,  C07C29/17 ,  C07C31/20 ,  B01D61/00 ,  C07C29/76

Abstract: In a process for separating suspended catalysts from a liquid reaction mixture by cross-flow filtration of the catalyst-containing reaction mixture on a membrane, the membrane is made of an inorganic material and has a mean pore diameter of less than 1000 nm. These membranes can be used for separating suspended catalysts from catalyst-containing reaction mixtures used for catalytically hydrogenating 2-butin-1,4-diol and producing 1,4-butanediol.

公开(公告)号：DE19720657A1

公开(公告)日：1998-11-19

申请号：DE19720657

申请日：1997-05-16

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR ,  WULFF-DOERING JOACHIM DR

IPC: B01J31/32 ,  B01J23/42 ,  B01J23/56 ,  B01J23/656 ,  B01J23/68 ,  B01J23/89 ,  B01J31/34 ,  C07B61/00 ,  C07C29/136 ,  C07C29/149 ,  C07C31/20 ,  C07D307/33

Abstract: The invention relates to a method for producing aliphatic alcohols by hydrogenating aliphatic carboxylic acids, anhydrides or esters thereof or lactones in the presence of a catalyst containing Pt and Re in metallic or oxidic form. Said catalyst also contains at least one other element from groups 5 to 12 and 14 and from the group of lanthanides of the periodic table of elements in metallic or oxidic form.

公开(公告)号：DE19648244A1

公开(公告)日：1998-05-28

申请号：DE19648244

申请日：1996-11-21

Applicant: BASF AG

Inventor： STEIN FRANK DR ,  LIANG SHELUE DR ,  FISCHER ROLF DR ,  PINKOS ROLF DR ,  BREITSCHEIDEL BORIS DR

IPC: C07D315/00 ,  C07D309/30 ,  C07B41/12 ,  C07B43/06 ,  C07C275/64 ,  C07D313/04 ,  C07H1/00 ,  C07K1/10

Abstract: Method for producing delta - and epsilon -lactones of formula (I), in which the radical R may be the same or different, and stand for hydrogen, optionally substituted aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic radicals, which can also be optionally bond to an oxygen atom of C atom and n stands for the numbers 3 or 4. According to said method, dialdehyde of the formula (II) OCH- (CR2)n-CHO, wherein R and n have the meaning cited above, or the mono- and the dihydrates and/or the mono- and the dihemiacetales of said dialdehydes are made to react in heterogeneous catalyzers during the gas or liquid phase at temperatures ranging from 20 to 300 DEG C and pressures ranging from 0.1 to 100 bar and the lactones are obtained in pure form by distillation.

公开(公告)号：DE19637429A1

公开(公告)日：1998-03-19

申请号：DE19637429

申请日：1996-09-13

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR ,  RIEBER NORBERT DR ,  SCHULZ MICHAEL DR ,  TELES JOAQUIM HENRIQUE DR

IPC: B01J27/128 ,  B01J27/138 ,  B01J31/02 ,  B01J31/12 ,  C07B61/00 ,  C07C27/02 ,  C07C35/06 ,  C07C67/03 ,  C07C67/04 ,  C07C69/06 ,  C07C67/38 ,  C07C29/128

Abstract: The following are claimed; (A) preparation of cyclopentyl formates of formula (II) comprising reacting cyclopentenes of formula (I) with formic acid in presence of an acid catalyst. R1-R3 = H or 1-8C alkyl; (B) production of the corresponding cyclopentanols of formula (III) by reacting (II) with a compound of formula (R4)nXH (IV). X = N (when n = 2) or O (when n = 1); and R4 = H, 1-12C alkyl or 7-12C aralkyl; (C) use of C5 streams from a cracker or refinery, especially with a 2-pentene content of not more than 10 wt%, for the production of optionally substituted cyclopentyl formates and/or cyclopentanols.

公开(公告)号：DE19544405A1

公开(公告)日：1997-06-05

申请号：DE19544405

申请日：1995-11-29

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF DR ,  FISCHER ROLF DR ,  KAIBEL GERD DR ,  PINKOS ROLF DR

IPC: B01J37/02 ,  C07D307/08 ,  C23C14/16 ,  C23C14/22 ,  B01J23/44

Abstract: The invention relates to a process for the catalytic hydrogenation of 2,5- and 2,3-dihydrofurane with hydrogen to form tetrahydrofurane. Use is made of a catalyser in which one or more metals are deposited on a metal wire mesh or metal foil carrier by vacuum evaporation or sputtering.