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    METHOD FOR RECOVERING ANILINES
    71.
    发明专利
    METHOD FOR RECOVERING ANILINES 失效

    公开(公告)号：JPH01203353A

    公开(公告)日：1989-08-16

    申请号：JP2839788

    申请日：1988-02-09

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： KISO YOSHIHISA

    IPC: C07C209/78 ,  B01J23/46 ,  C07B61/00 ,  C07C67/00 ,  C07C209/00 ,  C07C211/46

    Abstract: PURPOSE:To obtain anilines useful as a synthetic raw material for organic compounds at a high recovery ratio, by bringing a condensate of aniline with formaldehyde into contact with hydrogen in the presence of an iridium catalyst in an ether based solvent. CONSTITUTION:Aniline is condensed with formaldehyde in the presence of an acidic catalyst to provide a condensate, which is then reacted with hydrogen in the presence of an iridium catalyst in an ether based solvent (e.g., triethylene glycol dimethyl ether) at 150-400 deg.C under 10-100kg/cm pressure to recover the aniline. Methylenedianiline is formed together with a high polymer condensate of the aniline with the formaldehyde as a by-product by condensing the aniline with the formaldehyde. Thereby, the anilines can be recovered from the 2,4'-isomer, 2,2'-isomer, etc., and high polymer condensates having low availability in the methylenedianiline in high yield.

    SYNTHESIS OF ALKANE POLYOL
    72.
    发明专利
    SYNTHESIS OF ALKANE POLYOL 失效

    公开(公告)号：JPS57128645A

    公开(公告)日：1982-08-10

    申请号：JP1436381

    申请日：1981-02-04

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： KISO YOSHIHISA ,  NAKAMURA HIDEO ,  SAEKI KENJI

    IPC: C07C27/06 ,  B01J31/00 ,  B01J31/20 ,  B01J31/26 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/158 ,  C07C31/04 ,  C07C31/20 ,  C07C67/00

    Abstract: PURPOSE:To prepare the titled compound from CO and H2 in high yield, under low reaction pressure, by the use of a homogeneous liquid-phase catalyst obtained by dissolving a rhodium compound and an alkali metal iodide at a ratio within a specific range in an organic solvent. CONSTITUTION:The objective compound, esp. ethylene glycol, is prepared by reacting CO with H2 pref. at about 200-300 deg.C in the presence of a homogeneous liquid-phase catalyst comprising an organic solvent solution of a rhodium compound and an alkali metal iodide wherein the gram-atom ratio of the alkali metal in the alkali metal iodide to rhodium in the rhodium compound is 1-100, pref. 5-30. The molar ratio of CO/H2 is usually about 2/1-1/5.

    CONVERSION OF PLASTIC MATERIAL INTO OIL
    73.
    发明专利
    CONVERSION OF PLASTIC MATERIAL INTO OIL 失效

    公开(公告)号：JPH108066A

    公开(公告)日：1998-01-13

    申请号：JP16972396

    申请日：1996-06-28

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： OYOSHI HAJIME ,  SHIMAMOTO KENJI ,  KISO YOSHIHISA

    IPC: C08J11/16 ,  B01J21/16 ,  C10G1/10

    Abstract: PROBLEM TO BE SOLVED: To convert a plastic material into an oil in high efficiency by the catalytic decomposition of the plastic material in the presence of an activated clay. SOLUTION: An oily substance is produced by the catalytic decomposition of a plastic material such as polyethylene, polypropylene, polystyrene or ethylene-vinyl acetate copolymer resin, a wax, a rubber, an elastomer, etc., in the presence of an activated clay of grade K500 produced by Nihon Kassei- Hakudo Co.

    CONVERSION OF PLASTIC INTO OIL
    74.
    发明专利
    CONVERSION OF PLASTIC INTO OIL 失效

    公开(公告)号：JPH09302358A

    公开(公告)日：1997-11-25

    申请号：JP12378396

    申请日：1996-05-17

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： OYOSHI HAJIME ,  SHIMAMOTO KENJI ,  KISO YOSHIHISA

    IPC: C08J11/16 ,  B01J21/12 ,  C10G1/10

    Abstract: PROBLEM TO BE SOLVED: To efficiently convert plastics, esp. mixed plastics containing polyolefin(s) and polystyrene, into oil. SOLUTION: Plastics are catalytically pyrolyzed to obtain an oily product in the presence of a silica-alumina catalyst which is prepared by metallic ion treatment of a silica-alumina catalyst having the following characteristics: degree of crystallinity calculated by the formula described below based on the diffraction line spectrum intensity determined by powder X-ray diffractometry is

    PRODUCTION OF OILY SUBSTANCE BY DECOMPOSING SYNTHETIC POLYMER
    75.
    发明专利
    PRODUCTION OF OILY SUBSTANCE BY DECOMPOSING SYNTHETIC POLYMER 失效

    公开(公告)号：JPH09227878A

    公开(公告)日：1997-09-02

    申请号：JP5848896

    申请日：1996-02-21

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： KISO YOSHIHISA ,  SHIMAMOTO KENJI

    IPC: B29B17/00 ,  C08J11/00 ,  C08J11/10 ,  C08J11/18 ,  C08J11/20 ,  C10B53/00 ,  C10B53/07 ,  C10G1/10

    Abstract: PROBLEM TO BE SOLVED: To accelerate the decomposition and liquefaction of a synthetic polymer in a process for thermally decomposing and liquefying the polymer and to thereby improve the productivity of the process by using a specific catalyst. SOLUTION: In this process for producing an oily substance, a synthetic polymer is liquefied by thermal decomposition at 300-600 deg.C in the presence of at least one compd. which generates a free radical under the decomposition conditions and is selecterd from among vic.-diarylalkanes represented by the formula (Ar and Ar are each arom.; and R to R are each alkyl) in an amt. of 0.01-10% of the polymer. Pref. Ar and Ar are each independently phenyl, tolyl, or xylyl.

    PRODUCTION OF 1-INDANONES
    76.
    发明专利
    PRODUCTION OF 1-INDANONES 失效

    公开(公告)号：JPH0812615A

    公开(公告)日：1996-01-16

    申请号：JP12514194

    申请日：1994-06-07

    Applicant: MITSUI PETROCHEMICAL IND

    Inventor： IMUTA JIYUNICHI ,  SAITO JUNJI ,  UEDA TAKASHI ,  KISO YOSHIHISA

    IPC: B01J27/08 ,  C07B61/00 ,  C07C45/68 ,  C07C49/633 ,  C07C49/687 ,  C07C49/703 ,  C07C49/753 ,  C07F7/08 ,  C07F9/50

    Abstract: PURPOSE:To produce a l-indanone compound useful e.g. as a starting substance for an olefin polymerization catalyst by a single-stage reaction in high yield by reacting a specific benzene derivative with a methacrylic acid halide in the presence of a Lewis acid or a strong acid. CONSTITUTION:A 1-indanone compound of formula Ia and/or formula Ib is produced by reacting a compound of formula II [R to R are each H, a halogen, a 1-20C (halogenated)hydrocarbon group, a silicon-containing group, an oxygen- containing group, an S-containing group, an N-containing group or a P- containing group or adjacent groups are bonded with each other to form a ring] with a compound of formula III (R is same as R to R ; X is a halogen) in the presence of a Lewis acid or a strong acid. The Lewis acid is preferably aluminum trichloride, tin tetrachloride, etc., and the strong acid is preferably trifluoromethanesulfonic acid, hydrogen fluoride, etc. The compound of formula II is e.g. p-cymene and the compound of formula Ia or formula Ib is e.g. 2,4- dimethyl-7-isopropyl-1-indanone or 2,7-dimethyl-4-isopropyl-1-indanone.

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