公开(公告)号：DE19534163A1

公开(公告)日：1997-03-20

申请号：DE19534163

申请日：1995-09-15

Applicant: BASF AG

Inventor： GENZ MANFRED DR ,  HASELHORST WALTER ,  JESCHKE TORSTEN DR ,  BRUNS UTE ,  BOLLMANN HEINZ ,  STRAUS MICHAEL DR ,  SCHOLZ WOLFGANG ,  VOELKEL RUEDIGER DR ,  PEUKER HARTMUT ,  HELLMANN GERHARD

IPC: C08G18/40 ,  C08G18/10 ,  C08G18/65 ,  C08G18/72 ,  C08G18/76

Abstract: The invention concerns a method of preparing compact and preferably cellular polyurethane elastomers by reacting a) high molecular polyhydroxyl compounds and optionally b) low molecular chain-extending and/or crosslinking agents with c) 1,5-naphthylene diisocyanate and at least one additional aromatic diisocyanate, selected from the group comprising toluylene diisocyanate, diphenylmethane diisocyanate, 3,3'-dimethyl diphenyl diisocyante, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or aliphatic diisocyanate with between 4 and 12 carbon atoms and/or cycloaliphatic diisocyanate with between 6 and 18 carbon atoms, the structural components (a), (c) and optionally (b) advantageously being reacted by the prepolymer method, in the presence or absence of d) catalysts, e) expanding agents and f) additives. The invention further concerns isocyanate prepolymers suitable for this method.

公开(公告)号：DE10392569D2

公开(公告)日：2005-05-19

申请号：DE10392569

申请日：2003-06-04

Applicant: BASF AG

Inventor： WULF ANDREAS ,  BERELSMANN RALF ,  BOLLMANN HEINZ

IPC: F16F1/38

公开(公告)号：ES2171720T3

公开(公告)日：2002-09-16

申请号：ES96932483

申请日：1996-09-09

Applicant: BASF AG

Inventor： GENZ MANFRED ,  HASELHORST WALTER ,  JESCHKE TORSTEN ,  BRUNS UTE ,  BOLLMANN HEINZ ,  STRAUSS MICHAEL

IPC: C08G18/40 ,  C08G18/10 ,  C08G18/65 ,  C08G18/72 ,  C08G18/76

Abstract: Compact and preferably cellular polyurethane elastomers are produced by reactinga) polyhydroxyl compounds having molecular weights of from 800 to 6000 and, if desired,b) chain extenders and/or crosslinkers having molecular weights of up to 800 [lacuna]c) naphthylene 1,5-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 3,3'-dimethylbiphenyl diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or aliphatic diisocyanate having from 4 to 12 carbon atoms and/or cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are preferably reacted by the prepolymer method,in the presence or absence ofd) catalysts,e) blowing agents andf) additives. Isocyanate prepolymers suitable for this purpose are also described.

公开(公告)号：DE10123002C1

公开(公告)日：2002-08-08

申请号：DE10123002

申请日：2001-05-11

Applicant: BASF AG

Inventor： BUDER BERNDT ,  BIEDERMANN ANJA ,  BOLLMANN HEINZ ,  MUELLER JUERGEN ,  PAPENFUS HORST ,  KRECH RUEDIGER ,  MOENTER WOLFGANG

IPC: B29C44/50 ,  B29C47/40 ,  B29C67/24 ,  C08G18/08 ,  C08G18/10 ,  C08G18/42 ,  C08G18/76 ,  C08G18/79 ,  B29B7/74 ,  B29B7/48

公开(公告)号：AT217016T

公开(公告)日：2002-05-15

申请号：AT97930440

申请日：1997-06-30

Applicant: BASF AG

Inventor： GENZ MANFRED ,  HASELHORST WALTER ,  JESCHKE TORSTEN ,  NICHAU UTE ,  BOLLMANN HEINZ ,  STRAUSS MICHAEL ,  SCHOLZ WOLFGANG ,  VOELKEL RUEDIGER ,  PEUKER HARTMUT ,  HELLMANN GERHARD

IPC: C08G18/10 ,  C08G18/42 ,  C08G18/48 ,  C08G18/66 ,  C08G18/72 ,  C08G18/76 ,  C08G101/00 ,  C08J3/14

Abstract: Compact and preferably cellular polyurethane elastomers are prepared by reactinga) relatively high molecular weight polyhydroxyl compounds and if desired,b) low molecular weight chain extenders and/or crosslinkers withc) phenylene 1,4-diisocyanate (p-PDI) and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 3,3'-dimethylbiphenyl diisocyanate, 1,2-diphenylethane diisocyanate and/or aliphatic diisocyanate, having from 4 to 12 carbon atoms and/or cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are advantageously reacted by the prepolymer method,in the presence or absence ofd) catalysts,e) blowing agents andf) additives.Isocyanate prepolymers suitable for this purpose are described.

公开(公告)号：DE59608602D1

公开(公告)日：2002-02-21

申请号：DE59608602

申请日：1996-09-09

Applicant: BASF AG

Inventor： GENZ MANFRED ,  HASELHORST WALTER ,  JESCHKE TORSTEN ,  BRUNS UTE ,  BOLLMANN HEINZ ,  STRAUSS MICHAEL ,  SCHOLZ WOLFGANG ,  VOELKEL RUEDIGER ,  PEUKER HARTMUT ,  HELLMANN GERHARD

IPC: C08G18/40 ,  C08G18/10 ,  C08G18/65 ,  C08G18/72 ,  C08G18/76

Abstract: Compact and preferably cellular polyurethane elastomers are produced by reactinga) polyhydroxyl compounds having molecular weights of from 800 to 6000 and, if desired,b) chain extenders and/or crosslinkers having molecular weights of up to 800 [lacuna]c) naphthylene 1,5-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 3,3'-dimethylbiphenyl diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or aliphatic diisocyanate having from 4 to 12 carbon atoms and/or cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are preferably reacted by the prepolymer method,in the presence or absence ofd) catalysts,e) blowing agents andf) additives. Isocyanate prepolymers suitable for this purpose are also described.

公开(公告)号：AT201220T

公开(公告)日：2001-06-15

申请号：AT97930439

申请日：1997-06-30

Applicant: BASF AG

Inventor： GENZ MANFRED ,  MERGER ROLAND ,  BOLLMANN HEINZ ,  THAERIGEN RAINA ,  VOELKEL RUEDIGER ,  KRAUS RUPERT ,  POHL SIEGMUND

IPC: C08G18/10 ,  C08G18/42 ,  C08G18/48 ,  C08G18/66 ,  C08G18/76 ,  C08G18/77 ,  C08G18/81 ,  C08J9/00 ,  C08J9/14

Abstract: A process is disclosed for preparing microcellular polyurethane elastomers by reacting: (a) high-molecular polyhydroxyl compounds, optionally (b) low-molecular chain-lengthening and/or cross-linking agents with (c) 3,3'-dimethoxy-4,4'-diisocyanato-diphenyl and/or 4,4'-stilbene-diisocyanate in the presence or absence of (d) catalysts; (e) foaming agents; and (f) additives. Also disclosed are isocyanate prepolymers suitable for preparing these elastomers.

公开(公告)号：EA001514B1

公开(公告)日：2001-04-23

申请号：EA199800371

申请日：1996-09-30

Applicant: BASF AG

Inventor： GENZ MANFRED ,  HELLMANN GERHARD ,  HASELHORST WALTER ,  JESCHKE TORSTEN ,  BRUNS UTE ,  BOLLMANN HEINZ ,  STRAUSS MICHAELL ,  SCHOLZ WOLFGANG ,  VOELKEL RUDIGER ,  PEUKER HARTMUT

IPC: C08G18/10 ,  C08G18/40 ,  C08G18/72 ,  C08G18/76 ,  C08J9/14

Abstract: Описываетсясодержащийизоцианатныегруппыпреполимерс содержаниемизоцианатныхгрупп 3,3-10 мас.%, полученныйвзаимодействием, поменьшеймере, одногополигидроксильногосоединенияс молекулярноймассойотболеечем 800 до 3500 илиегосмесис низкомолекулярнымгидроксилсодержащимудлинителемцепии/илисшивающимагентом, поменьшеймере, соднимароматическимдиизоцианатом, выбраннымизгруппы, включающейдифенилметандиизоцианат, 1,2-дифенилэтандиизоцианати фенилендиизоцианат, и/илис 1,6-гексаметилендиизоцианатом, и/илис 1-изоцианато-3,3,5-триметил-5-изоцианатометилциклогексаном, ипоследующимвзаимодействиемполученного, содержащегоуретановыеи 0,05-8 мас.% изоцианатныхгруппполиаддуктас 3,3'-диметилдифенил-4,4'-диизоцианатом, приэтомсоотношениеэквивалентовгидроксильныхгруппполигидроксильногосоединенияилиегосмесис указаннымудлинителемцепии/илисшивающимагентомк изоцианатнымгруппамароматическихдиизоцианатовуказаннойгруппыи изоцианатнымгруппамуказанного 3,3'-диметилдифенил-4,4'-диизоцианатасоставляет 1:>1-6:0,02-6, амольноесоотношениеуказанного 3,3'-диметилдифенил-4,4'-диизоцианатаи ароматическихдиазоцианатовуказаннойгруппысоставляет 1:0,1-1:10. Данныйпреполимерможетприменятьсядляполучениякомпактныхилипористыхполиуретановыхполимеров.

公开(公告)号：CA2271363A1

公开(公告)日：1999-11-14

申请号：CA2271363

申请日：1999-05-10

Applicant: BASF AG

Inventor： THAERIGEN RAINA ,  KOKEL NICOLAS ,  BOLLMANN HEINZ ,  HAEBERLE KARL

IPC: C08G18/08 ,  C07C267/00 ,  C07C271/20 ,  C08G18/02 ,  C08G18/28 ,  C08G18/38 ,  C08G18/79 ,  C08G18/80 ,  C08K5/29 ,  C08L75/06 ,  C09K15/18 ,  C07C271/24 ,  C07C275/24 ,  C08G18/72

Abstract: Carbodiimides based on 1,3-bis(1-methyl-1-isocyanatoethyl)benzene contain from 12 to 40% by weight of ethylene oxide units ¢-CH2-CH2-O-!, based on the weight of the carbodiimides.

公开(公告)号：AT184034T

公开(公告)日：1999-09-15

申请号：AT96943968

申请日：1996-12-16

Applicant: BASF AG

Inventor： KRECH RUEDIGER ,  ROTERMUND UDO ,  BOLLMANN HEINZ ,  HEMPEL RENATE ,  SCHOLZ WOLFGANG ,  GENZ MANFRED

IPC: C08J9/36 ,  C08G18/08 ,  C08G18/76 ,  C08G101/00

Abstract: PCT No. PCT/EP96/05640 Sec. 371 Date Oct. 7, 1998 Sec. 102(e) Date Oct. 7, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23535 PCT Pub. Date Jul. 3, 1997A microcellular PU elastomer having improved dynamic mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and further customary constituents has a physicochemical structure which, in the gel permeation chromatograph (GPC) of a solution of the microcellular polyurethane elastomer prepared at 90 DEG C. in N,N-dimethylformamide containing 1 percent of di-n-butylamine measured against polymethyl methacrylate (PMMA) as standard, displays a signal occurring in addition to low molecular weight main signal and comprising one or more peaks at an (apparent) molar mass of greater than 250,000 g/mol which becomes smaller or disappears on addition of lithium chloride to this solution, and a urea content of from 14 to 18% by weight. A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.