Formaldehyde-free binder for mouldings

    公开(公告)号:AU1874597A

    公开(公告)日:1997-09-10

    申请号:AU1874597

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/00768 Sec. 371 Date Aug. 21, 1998 Sec. 102(e) Date Aug. 21, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31059 PCT Pub. Date Aug. 28, 1997A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50 DEG C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130 DEG C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.

    AQUEOUS SOLUTIONS OR DISPERSIONS OF COPOLYMERS

    公开(公告)号:CA2181740A1

    公开(公告)日:1995-07-27

    申请号:CA2181740

    申请日:1995-01-16

    Applicant: BASF AG

    Abstract: Aqueous solutions or dispersions of copolymers obtainable by the radical copolymerisation of A1) 50 to 60 mol% C6 to C40 mono-olefines or C6 to C40 alkyl vinyl ethers or mixtures of C6 to C40 alkyl vinyl ethers and up to 50 mol%, in relation to the entire quantity of the component A1, C6 to C40 monoolefines with B1) 60 to 40 mol% of monoethylenically unsaturated C4-C8 dicarboxylic acid anhydrides, or by the radical copolymerisation of A2) 50 to 90 wt % C6 to C40 alkyl acrylates or methyl acrylates or vinyl esters of C6 to C40 carboxylic acids or mixtures thereof with B2) 10 to 50 wt % of monoethylenically unsaturated C3 to C12 carboxylic acids, monoethylenically unsaturated C4 to C12 dicarboxylic acid anhydrides, semi-ester or semi-amides of monoethylenically unsaturated C4 to C12 dicarboxylic acids, amides of monoethylenically unsaturated C3 to C12 carboxylic acids or mixtures thereof, to form copolymers with molar masses of 500 to 30,000 whereby the carboxyl groups present in an aqueous medium are at least partly neutralised and part of the carboxyl groups may be amidated, and which are characterised by an emulsifier content of 0.5 to 40 wt % in relation to the quantity of copolymer. These aqueous solutions or dispersions are suitable for stuffing and fulling leathers and fur pelts.

    USE OF GRAFTED POLYALKYLENE OXIDE AS GRAYING INHIBITORS IN LAUNDERING

    公开(公告)号:CA2420938A1

    公开(公告)日:2003-02-27

    申请号:CA2420938

    申请日:2001-08-30

    Applicant: BASF AG

    Abstract: The invention relates to the use of grafted polymers as greying inhibitors during the washing and aftertreatment of textile goods. Said polymers are obtained by polymerising A) 10 to 95 wt. % of grafted monomers containing, i n relation to A), a) 1 to 99 wt. % of at least one vinyl ester, b) 1 to 99 wt. % of at least one N-vinyl lactam, c) 0 to 90 wt. % of at least one other monoethylenically unsaturated monomer which can be copolymerised with monome rs a) and b), and d) 0 to 5 wt. % of at least one monomer having at least two ethylenically unsaturated, non-conjugated double bonds in the molecule, in t he presence of A) 5 to 90 wt. % of at least one polymer B), chosen from polyalkylene oxides containing at least 3 units of a C2 to C4 alkylene oxide , and polytetrahydrofuranes containing at least 3 units of tetramethyl oxide units, and the mixtures thereof.

    Use of grafted polyalkylene oxides as greying inhibitors when washing

    公开(公告)号:AU8404301A

    公开(公告)日:2002-03-13

    申请号:AU8404301

    申请日:2001-08-30

    Applicant: BASF AG

    Abstract: The invention relates to the use of grafted polymers as greying inhibitors during the washing and aftertreatment of textile goods. Said polymers are obtained by polymerising A) 10 to 95 wt. % of grafted monomers containing, in relation to A), a) 1 to 99 wt. % of at least one vinyl ester, b) 1 to 99 wt. % of at least one N-vinyl lactam, c) 0 to 90 wt. % of at least one other monoethylenically unsaturated monomer which can be copolymerized with monomers a) and b), and d) 0 to 5 wt. % of at least one monomer having at least two ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of A) 5 to 90 wt. % of at least one polymer B), chosen from polyalkylene oxides containing at least 3 units of a C 2 to C 4 alkylene oxide, and polytetrahydrofuranes containing at least 3 units of tetramethyl oxide units, and the mixtures thereof.

    90.
    发明专利
    未知

    公开(公告)号:BR9909538A

    公开(公告)日:2000-12-12

    申请号:BR9909538

    申请日:1999-03-29

    Applicant: BASF AG

    Abstract: N-Vinyl-containing polymers obtainable by free-radically initiated polymerization of a monomer or monomer mixture of(A) from 5 to 100% by weight of an N-vinylamide or N-vinylamine,(B) from 0 to 95% by weight of monoethylenically unsaturated carboxylic acids having from 3 to 8 carbon atoms or their derivatives,(C) from 0 to 95% by weight of other N-vinyl and/or C-vinyl compounds and(D) from 0 to less than 10% by weight of other copolymerizable monomers,are useful in the form of aqueous solutions or dispersions as tanning materials for self-tanning, pretanning and cotanning of leather pelts and fur pelts and for retanning leather and fur.

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