公开(公告)号：DE10137543A1

公开(公告)日：2003-02-13

申请号：DE10137543

申请日：2001-08-01

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  WENZEL ANNE ,  RUDOLF PETER ,  RIEBER NORBERT ,  BASLER PETER

IPC: C07D301/12 ,  C07D301/32 ,  C07D303/04 ,  B01D3/00 ,  B01D1/00

Abstract: Production of propylene oxide comprises: (a) reaction of propene with hydrogen peroxide (H2O2) in solvent in the presence of a catalyst to produce a mixture of propylene oxide, solvent, unreacted propene and H2O2 and oxygen; (b) separation of propylene oxide from the mixture to leave a mixture (M1) containing unreacted propene and oxygen; and (c) utilization of (M1).

公开(公告)号：CA2414756A1

公开(公告)日：2003-01-06

申请号：CA2414756

申请日：2001-07-05

Applicant: BASF AG

Inventor： WENZEL ANNE ,  RUDOLF PETER ,  REHFINGER ALWIN ,  TELES JOAQUIM HENRIQUE ,  BASSLER PETER ,  RIEBER NORBERT

IPC: C07D20060101 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04

Abstract: The invention relates to a method for the production of propylene oxide, whereby (i) propylene is reacted with hydrogen peroxide in the presence of methanol to form propylene oxide, resulting in a mixture (Gi), comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) from mixture (Gi) a mixture (Gii), comprising methanol, water and hydrogen peroxi de is separated off, yielding a mixture (Ga), comprising propylene oxide. Water is separated off from mixture (Gii) to give a mixture (Giii), comprising methanol and methyl formate.

公开(公告)号：DE10105527A1

公开(公告)日：2002-08-08

申请号：DE10105527

申请日：2001-02-07

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  WENZEL ANNE ,  RUDOLF PETER ,  RIEBER NORBERT ,  BASLER PETER

IPC: C07D301/12 ,  C07D301/19 ,  C07D301/32

Abstract: The invention relates to a method for the epoxidation of an organic compound comprising at least one C-C double bond, using hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent. Said method is characterised in that a product mixture containing alpha -hydroperoxy alcohols is reduced using at least one reductant. The invention also relates to a method for the epoxidation of an organic compound comprising at least one C-C double bond, using hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent, characterised in that said method comprises at least the following steps: (i) an organic compound comprising at least one C-C double bond is reacted with hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent to obtain a product mixture P1 containing alpha -hydroperoxy alcohols; (ii) an epoxide that has been obtained by the reaction in step (i) is separated from P1 or P1', together with the non-converted organic compound comprising at least one C-C double bond, to obtain a product mixture P2 or P2', P2 containing the alpha -hydroperoxy alcohols that have occurred as by-products in the reaction in step (i) and P2' being substantially devoid of alpha -hydroperoxy alcohols. (iii) at least one reductant is added to P1 and/or P2, whereby the alpha -hydroperoxy alcohols are converted into corresponding glycols, obtained in a product mixture P1' or P3.

公开(公告)号：DE10044798A1

公开(公告)日：2002-04-04

申请号：DE10044798

申请日：2000-09-11

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASLER PETER ,  WENZEL ANNE ,  RIEBER NORBERT ,  MUELLER ULRICH ,  RUDOLF PETER

IPC: B01J29/89 ,  B01J29/90 ,  B01J38/14 ,  C07D301/12

Abstract: The invention relates to a method for regenerating a zeolite catalyst, comprising a thermal treatment of the catalyst in the presence of a gas stream at temperatures above 120 DEG C, whereby the mass-dependent residence time of the gas stream over the catalyst during the thermal treatment is more than 2 hours.

公开(公告)号：DE10044788A1

公开(公告)日：2002-04-04

申请号：DE10044788

申请日：2000-09-11

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  WENZEL ANNE ,  HARDER WOLFGANG ,  RUDOLF PETER ,  REHFINGER ALWIN ,  BASLER PETER ,  RIEBER NORBERT

IPC: B01J29/89 ,  B01J29/90 ,  C07D301/12

Abstract: The invention relates to a method for regenerating a zeolite catalyst, comprising the thermal treatment of the catalyst in the presence of a gas stream at temperatures above 120 DEG C, said gas stream containing hydrogen. The regenerated zeolite catalyst can be used in an integrated method for oxidising an alkene using a hydroperoxide.

公开(公告)号：DE10044787A1

公开(公告)日：2002-04-04

申请号：DE10044787

申请日：2000-09-11

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  MUELLER ULRICH ,  WENZEL ANNE ,  RUDOLF PETER ,  HARDER WOLFGANG ,  RIEBER NORBERT ,  BASLER PETER

IPC: B01J29/89 ,  B01J29/90 ,  B01J38/62 ,  C07D301/12

Abstract: A process for the preparation of an epoxide in the presence of a zeolite catalyst, in which (i) an alkene is reacted with a hydroperoxide in the presence of the catalyst to obtain the epoxide, at least one alkali metal salt being fed into the reaction in at least one precursor stream, wherein (ii) during the reaction the addition of the at least one alkali metal salt is stopped and hydroperoxide and alkene are still fed into the reaction.

公开(公告)号：DE3466819D1

公开(公告)日：1987-11-19

申请号：DE3466819

申请日：1984-07-10

Applicant: BASF AG

Inventor： LEHNER AUGUST ,  HACK JOACHIM ,  KRUCKER KARL DR ,  BALZ WERNER DR ,  ROEMER KARL HEINZ ,  RUDOLF PETER ,  FALK ROLAND DR ,  ECKERT GUENTER DR

IPC: G11B5/845 ,  C09D5/23 ,  G11B5/70 ,  G11B5/702 ,  G11B5/842

公开(公告)号：DE3516885A1

公开(公告)日：1986-11-13

申请号：DE3516885

申请日：1985-05-10

Applicant: BASF AG

Inventor： STECK WERNER ,  FESER RAINER ,  LOESER WERNER ,  RUDOLF PETER ,  VAETH GUENTER ,  JAKUSCH HELMUT ,  KOVACS JENOE

IPC: C01G49/00 ,  C01G49/06 ,  C09D5/23 ,  G11B5/706 ,  H01F1/11 ,  C01G49/02 ,  C01G51/00 ,  C08K3/22 ,  C09D7/12 ,  G11B5/84 ,  B05D5/12 ,  C04B35/26

Abstract: The preparation of acicular ferrimagnetic iron oxides which contain cobalt and phosphate ions and, if desired, further additives, and their use for manufacturing magnetic recording media.

公开(公告)号：CA2440114C

公开(公告)日：2010-10-26

申请号：CA2440114

申请日：2002-03-07

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  HESSE MICHAEL ,  LOBREE LISA ,  HOELZLE MARKUS ,  ARNDT JAN-DIRK ,  RUDOLF PETER

IPC: B01J31/04 ,  C07F1/08 ,  A61K9/52 ,  B01J31/02 ,  B01J31/16 ,  B01J31/22 ,  B01J35/10 ,  C07B61/00 ,  C07C41/08 ,  C07C43/16 ,  C07C51/41 ,  C07C63/28 ,  C07C67/04 ,  C07C69/78 ,  C07F3/06 ,  C07F19/00 ,  C08F4/42

Abstract: An organometallic framework material is prepared by a process which comprises reacting a fluid mixture comprising a metal salt with at least one at least bidentate organic compound capable of coordination to metal ions in the presence of at least one base and a solvent, where the solvent comprises at least one cyclic amide (lactam) and/or at least one cyclic ester (lactone).

公开(公告)号：BR0207063A

公开(公告)日：2008-07-22

申请号：BR0207063

申请日：2002-02-06

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BERG ANNE ,  RUDOLF PETER ,  RIEBER NORBERT ,  BASSLER PETER

IPC: C07D301/12 ,  C07D301/19 ,  C07D301/32 ,  C07D303/04

Abstract: An organic compound having at least one C-C double bond is epoxidized by means of hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent, wherein a product mixture comprising alpha-hydroperoxyalcohols is reduced using at least one reducing agent. The process advantageously comprises at least the following steps: (i) reacting an organic compound having at least one C-C double bond with hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent to give a product mixture P1 comprising alpha-hydroperoxyalcohols; (ii) separating an epoxide formed in the reaction in step (i) and the unreacted organic compound having at least one C-C double bond from P1 or P1' to give a product mixture P2 or P2', where P2 comprises the alpha-hydroperoxyalcohols formed as by-product in the reaction in step (i) and P2' is largely free of alpha-hydroperoxyalcohols; (iii) treating P1 and/or P2 with at least one reducing agent so that the alpha-hydroperoxyalcohols are converted into corresponding glycols to give a product mixture P1' or P3.