Abstract:
고전압 적용시 전지의 성능은 그대로 유지하면서 보존특성이 우수하고 수명을 향상시킬 수 있는 리튬 2차전지용 비수성 전해액이 제공된다. 본 발명에 따른 리튬 2차전지용 비수성 전해액은 카보네이트계 용매, 에스테르계 용매, 에테르계 용매, 및 케톤계 용매로 이루어진 군에서 선택되는 하나 이상의 용매를 포함하는 비수성 유기용매와, 상기 비수성 유기용매에 용해되어 있는 리튬염을 포함하는 기본전해액; 기본전해액에 하기 화학식 1로 표시되는 플루오로 트리 페닐 실란(Fluorotriphenylsilane)이 첨가되는 것을 특징으로 한다.
Abstract:
A nonaqueous electrolyte solution for a lithium secondary battery, and a lithium secondary battery containing the nonaqueous electrolyte solution are provided to improve high temperature storage characteristics and lifetime without the deterioration of battery performance. A nonaqueous electrolyte solution comprises a nonaqueous organic solvent comprising at least one solvent selected from the group consisting of a carbonate-based solvent, an ester-based solvent, an ether-based solvent and a ketone-based solvent; a lithium salt dissolved in the nonaqueous organic solvent; and 0.1-10 parts by weight of the trimethoxyboroxine represented by the formula 1 based on 100 parts by weight of the nonaqueous organic solvent.
Abstract:
A non-aqueous electrolyte is provided to improve life characteristic and storage characteristic of a battery while maintaining performances of a battery when high voltage is applied to a battery. A non-aqueous electrolyte for a lithium secondary battery includes: a base electrolyte comprising a non-aqueous organic solvent and a lithium salt dissolved in the non-aqueous organic solvent, wherein the non-aqueous organic solvent contains at least one solvent selected from the group comprising carbonate-based solvents, ester-based solvents, ether-based solvents, and ketone-based solvents; and fluorotriphenylsilane represented by the following formula 1 to be added to the base electrolyte.
Abstract:
PURPOSE: A composition for forming a silica-based insulation layer is provided to remarkably reduce defects in the silica based insulation layer, thereby capable of improving gap-fill performance, insulative performance required for the silica-based insulation layer. CONSTITUTION: A composition for forming a silica-based insulation layer comprises hydrogenated polysiloxazane comprising a moiety in chemical formula 1, and a moiety in chemical formula 2, and has chlorine content of 1 ppm or less. In chemical formulas R1-R7 is respectively hydrogen, a substituted or unsubstituted C1-30 alkyl group, a substituted or unsubstituted C3-30 cycloalkyl group, a substituted or unsubstituted C6-30 aryl group, a substituted or unsubstituted C7-30 arylalkyl group, a substituted or unsubstituted C1-30 heteroalkyl group, a substituted or unsubstituted C2-30 heterocycloalkyl group, a substituted or unsubstituted C2-30 alkenyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted carbonyl group, hydroxy group, or combinations thereof, and at least one of R1-R7 is hydrogen.
Abstract:
A non-aqueous electrolyte for a lithium secondary battery is provided to impart improved lifespan characteristics and high-temperature storage characteristics to a lithium secondary battery. A non-aqueous electrolyte for a lithium secondary battery comprises: a non-aqueous organic solvent including at least one solvent selected from the group consisting of carbonate solvents, ester solvents, ether solvents and ketone solvents, and a lithium salt dissolved in the non-aqueous organic solvent; and 1-10 parts by weight of pentafluorobenzene represented by the following formula 1 based on 100 parts by weight of the non-aqueous organic solvent.
Abstract:
Provided is a non-aqueous electrolyte for a lithium secondary battery, which causes no decomposition during repeated charge/discharge cycles, and imparts improved charge/discharge characteristics and cycle life characteristics to a battery. The non-aqueous electrolyte for a lithium secondary battery comprises: an organic solvent containing a lithium salt; and a mixture of at least one succinic anhydride derivative represented by the following formula 1 or 2 with trimethylsilyl borate represented by the following formula 3. In formulae 1-3, R_1, R_2, R_3 and R_4 are the same or different, and each represents a halogen atom, a halogen-substituted or non-substituted C1-C10 alkyl group, alkenyl group or alkoxy group.
Abstract:
본 발명은 리튬전지용 비수전해액에 대한 것으로, 보다 상세하게는 리튬염이 0.8 내지 2M로 용해된 유기용매 100 중량부에 테트라에틸렌 설폰아미드를 0.1 내지 10 중량부 첨가하여 제조된 리튬 전지용 비수전해액에 대한 것이며, 본 발명에 의해 고온 방치시 전지의 두께 증가율이 현저히 감소되고, 고온에서의 용량 저장 특성이 향상된 리튬 전지용 비수전해액을 제공할 수 있다.
Abstract:
PURPOSE: A composition for forming a silica layer is provided to remarkably reduce defects and form a silica layer with improved insulation and gap-fill properties. CONSTITUTION: A composition for forming a silica layer comprises one selected from hydrogenated polysilazane, hydrogenated polysiloxazane, and combinations thereof. The concentration of the hydrogenated polysilazane and hydrogenated polysiloxazane more than an average molecular weight of polystyrene of 50,000 is 0.1% or less. The number of particulates of the composition in the solution is 0-100 /cc. The weight average molecular weight of the hydrogenated polysilazane and hydrogenated polysiloxazane is 1,000-10,000. The total contents of the hydrogenated polysilazane and the hydrogenated polysiloxazane is 0.1-50 weight%.
Abstract:
비수성 전해액 및 이를 포함하는 리튬 2차 전지가 제공된다. 상기 비수성 전해액은 리튬염을 포함하는 기본 유기 용매; 및 하기 화학식 1 또는 2로 표시되는 숙신산 무수물 유도체의 하나 이상과 하기 화학식 3으로 표시되는 트리메틸실릴 보레이트의 혼합물을 포함한다. [화학식 1]
[화학식 2]
[화학식 3]
상기 식에서, R 1 , R 2 , R 3 및 R 4 는 서로 동일하거나 상이하고, 할로겐, 할로겐으로 치환되거나 치환되지 않은 탄소수 1 내지 10의 알킬기, 알케닐기 또는 알콕시 기이다. 리튬 2차 전지, 전해액, 숙신산 무수물 유도체, 트리메틸실릴 보레이트
Abstract:
A gel type polymer electrolyte for a lithium secondary battery, and a lithium secondary battery containing the polymer electrolyte are provided to improve the mobility of ions and the binding force between an electrode and a separator and to enhance the charge/discharge characteristics, lifetime characteristics and durability of a battery. A gel type polymer electrolyte comprises a polymer matrix; and an electrolyte solution which comprises a solvent and a lithium salt and is infiltrated in the polymer matrix, wherein the polymer matrix has a hybrid polymer network structure formed by the copolymerization of a first monomer(10) having 3-8 functional groups at terminal and a linear hydrophobic second monomer(11-14) having two functional groups at terminal. Preferably the ratio of the first monomer and the second monomer is 95:5 to 50:50 by weight.