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    4.
    发明专利
    未知

    公开(公告)号：DE59808566D1

    公开(公告)日：2003-07-10

    申请号：DE59808566

    申请日：1998-03-27

    Applicant: BASF AG

    Inventor： FUCHS DR ,  BREITSCHEIDEL DR ,  BECKER DR ,  NEUHAUSER DR

    IPC: B01J23/44 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C213/02 ,  C07C215/08

    Abstract: Preparation of mono- or polyfunctional tertiary amines of formula X(CH2NR1R2)n (I) involves reacting a nitrile of formula (R1R2NCH2)n-mX(CN)m (II) with a secondary amine of formula NHR1R2 (III) and hydrogen. The reaction is at 50-250 degrees C and 5-350 bars, in presence of a palladium-based catalyst (IV), comprising (based on total catalyst) 0.1-10 wt.% palladium and 0.01-10 wt.% of at least one other metal, selected from Group IB and VIII elements, cerium and lanthanum, on a carrier. In (I)-(III), R1, R2 = 1-20C alkyl, 3-8C cycloalkyl, 4-20C alkylcycloalkyl, 4-20C cycloalkylalkyl, aryl, 7-20C alkaryl, 7-20C aralkyl, 2-8C hydroxyalkyl, 2-8C mercaptoalkyl or 8-20C aryloxyalkyl; or R1 + R2 = optionally unsaturated 2-6C alkylene chain (optionally substituted by 1-3 1-4C alkyl and optionally interrupted by O); X = n-valent 1-20C alkyl, 2-20C alkenyl or 3-8C cycloalkyl group (optionally substituted by 1-20C alkyl, 3-8C cycloalkyl, 4-20C alkylcycloalkyl, 4-20C cycloalkylalkyl, 2-20C alkoxyalkyl, aryl, 7-20C alkaryl, 7-20C aralkyl, 1-20C alkoxy, OH, 1-20C hydroxyalkyl, 1-20C alkylamino, 2-20C dialkylamino, 2-12C alkenylamino, 3-8C cycloalkylamino, arylamino, diarylamino, aryl-(1-8C)alkylamino, halo, SH, 2-20C alkenyloxy, 3-8C cycloalkoxy, aryloxy or 2-8C alkoxycarbonyl); n = 1-4; and m = 1 to n. Also claimed is the use of (IV) as catalyst for the reaction of secondary amines with nitriles and hydrogen to give tertiary amines in general.

    8.
    发明专利
    未知

    公开(公告)号：DE59705243D1

    公开(公告)日：2001-12-13

    申请号：DE59705243

    申请日：1997-06-17

    Applicant: BASF AG

    Inventor： SIMON DR ,  DOSTALEK DR ,  LINGK HEINZ ,  BECKER DR ,  HENNE DR ,  LEBKUECHER DR ,  FREIRE ERDBRUEGGER DR ,  HESSE DR ,  KRATZ DR

    IPC: C07D295/02 ,  B01J23/72 ,  B01J37/02 ,  C07B61/00 ,  C07D295/03

    Abstract: Preparation of N-substituted cyclic amines of formula (I) comprises reacting primary amines of formula R NH2 (II) with diols of formula HO-A-OH (III) in the presence of hydrogen and a catalyst containing copper obtained by impregnating an inert support with an aqueous solution of an ammine complex of a Cu compound (IV) that readily undergoes thermal decomposition, then drying and calcining to give a catalyst containing 5-50 wt.% Cu, calculated as oxide. A = alkylene or (CH2)n-ÄO-CH2)mÜr (optionally substituted by one or more R ); R , R = alkyl, alkoxyalkyl, optionally alkyl- or alkoxy-substituted cycloalkyl, cycloalkylalkyl, aryl or arylalkyl; n, m = 2-8; r = 1-3.

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