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公开(公告)号:DE60143178D1
公开(公告)日:2010-11-18
申请号:DE60143178
申请日:2001-06-15
Inventor: NISHIMURA YUKIO , YAMAHARA NOBORU , YAMAMOTO MASAFUMI , KAJITA TORU , SHIMOKAWA TSUTOMU , ITO HIROSHI
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公开(公告)号:AU2003273924A1
公开(公告)日:2004-04-19
申请号:AU2003273924
申请日:2003-08-28
Applicant: IBM
Inventor: VARANASI PUSHKARA RAO , NISHIMURA YUKIO , KOBAYASHI EIICHI , KHOJASTEH MAHMOUD M , CHEN KUANG-JUNG
IPC: G03F7/039
Abstract: Acid-catalyzed positive resist compositions which are imageable with 193 nm radiation and/or possibly other radiation and are developable to form resist structures of improved development characteristics and improved etch resistance are enabled by the use of resist compositions containing imaging polymer component comprising an acid-sensitive polymer having a monomeric unit with a pendant group containing a remote acid labile moiety.
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公开(公告)号:JP2004012551A
公开(公告)日:2004-01-15
申请号:JP2002162110
申请日:2002-06-03
Inventor: NISHIMURA YUKIO , NISHIMURA ISAO , ITO HIROSHI , TOMAS I WOROU , VARANASI PUSHKARA RAO
IPC: G03F7/039 , C08F220/10 , C08F232/00 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition having high transparency to a radiation, excellent in basic properties as a resist, such as sensitivity, resolution, dry etching resistance and pattern shape and suitable for use as a chemically amplified resist. SOLUTION: The radiation-sensitive resin composition comprises (A) a resin which contains a repeating unit derived from α-perfluoroalkylacrylic esters typified by t-butyl α-trifluoromethylacrylate and a repeating unit derived from a norbornene compound typified by 5-ä2-hydroxy-2, 2-di(trifluoromethyl)ethyl}bicyclo[2.2.1]hept-2-ene or a compound of formula 7 as essential units and becomes alkali-soluble by the action of an acid and (B) a radiation-sensitive acid generator. COPYRIGHT: (C)2004,JPO
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公开(公告)号:JP2004012545A
公开(公告)日:2004-01-15
申请号:JP2002162080
申请日:2002-06-03
Applicant: JSR CORP , JSR MICRO INC , IBM
Inventor: YAMAMOTO MASASHI , ISHII HIROYUKI , ISHIDA EIKO , NISHIMURA YUKIO , MARK SLEZAK , BRUNSVOLD WILLIAM R , CHEN KUANG-JUNG , VARANASI PUSHKARA RAO
IPC: G03F7/039 , C08F20/28 , G03F7/004 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition having high transparency to a radiation, excellent in basic physical properties as a resist, such as sensitivity, resolution and pattern shape, and useful particularly as a chemically amplified resist excellent in focus latitude. SOLUTION: The radiation-sensitive resin composition comprises (A) a mixture of alkali-insoluble or slightly alkali-soluble resins having separate repeating units protected with acid-dissociating protective groups and typified by repeating units derived from 2-methyl-2-adamantyl (meth)acrylate, 1-ethylcyclohexyl (meth)acrylate, etc., wherein the acid-dissociating protective group of at least one of the resins is different from that of the other, and (B) a radiation-sensitive acid generator. COPYRIGHT: (C)2004,JPO
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公开(公告)号:JP2003241383A
公开(公告)日:2003-08-27
申请号:JP2002046520
申请日:2002-02-22
Inventor: NISHIMURA YUKIO , HOSHI MICHIAKI , SOYANO AKIMASA , KAJITA TORU , ALLEN ROBERT D , VARANASI PUSHKARA RAO
IPC: G03F7/039 , C08F220/26 , C08F220/34 , C08F220/38 , C08F222/06 , C08F232/08 , G03F7/004 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition excellent in contrast, capable of forming a fine resist pattern with a high degree of accuracy and excellent also in transparency to a radiation, sensitivity and resolution. SOLUTION: The radiation-sensitive resin composition comprises (A) a resin comprising an acid-dissociable group-containing norbornene compound typified by 5-[(1-methylcyclohexyl)oxycarbonyl]norbornene or 5-(2-methyl-1- adamantyloxycarbonyl)norbornene and maleic anhydride, (B) a radiation-sensitive acid generator and (C) a compound typified by a di-t-butyl 1,3- adamantanedicarboxylate or 2,5-dimethyl-2,5-di(1-adamantylcarbonyloxy)hexane. Preferably the resin (A) further comprises a polar group-containing alicyclic ester of (meth)acrylic acid typified by 3-hydroxy-1-adamantyl (meth)acrylate. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2011070209A
公开(公告)日:2011-04-07
申请号:JP2010246045
申请日:2010-11-02
Applicant: Internatl Business Mach Corp
, Jsr Corp , Jsr株式会社 , インターナショナル・ビジネス・マシーンズ・コーポレーションInternational Business Maschines Corporation Inventor: NISHIMURA YUKIO , YAMAHARA NOBORU , YAMAMOTO MASASHI , KAJITA TORU , SHIMOKAWA TSUTOMU , ITO HIROSHI
IPC: G03F7/039 , C08F214/18 , C08F220/22 , C08F220/24 , C08F232/08 , C08G61/08 , C08K5/10 , C08L27/12 , C08L33/06 , C08L33/16 , C08L35/00 , C08L101/08 , G03F20060101 , G03F7/004 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a novel radiation sensitive resin composition having high transparency to radiation, excellent basic physical properties for a resist pattern such as in sensitivity, resolution, and pattern shapes, without causing development defects during fine machining, to manufacture semiconductor elements at a high yield.
SOLUTION: The radiation-sensitive resin compositions comprises (A) a resin containing an acid dissociable group obtained by the open ring polymerization of the norbornene derivative having a structure shown by the following general formula (1), and (B) a radiation-sensitive acid generator. In the general formula (1), R
1 represents a hydrogen atom and a univalent acid dissociation group, X
1 a low-grade fluorinated alkyl group, and R
2 a hydrogen atom, an alkyl group or a fluorinated alkyl group.
COPYRIGHT: (C)2011,JPO&INPITAbstract translation: 要解决的问题:提供一种对辐射具有高透明度的新颖的辐射敏感性树脂组合物,用于抗敏剂图案的极好的基本物理性能,例如灵敏度,分辨率和图案形状,而不会在精加工期间引起显影缺陷, 以高产率制造半导体元件。 解决方案:辐射敏感性树脂组合物包含(A)含有通过具有下列通式(1)所示结构的降冰片烯衍生物的开环聚合获得的酸解离基的树脂,(B) 辐射敏感酸发生器。 在通式(1)中,R
1 SP>表示氢原子和一价酸解离基团,低级氟化烷基,X 1, 2个氢原子,烷基或氟化烷基。 版权所有(C)2011,JPO&INPIT -
公开(公告)号:JP2003241384A
公开(公告)日:2003-08-27
申请号:JP2002046679
申请日:2002-02-22
Applicant: JSR CORP , IBM , JSR MICRO INC
Inventor: NISHIMURA YUKIO , YAMAMOTO MASASHI , ISHII HIROYUKI , MARK SLEZAK , BRUNSVOLD WILLIAM R , MARGARET C LAWSON , CHEN KUANG-JUNG , KWONG RANEE W , VARANASI PUSHKARA RAO
IPC: G03F7/039 , C08F220/18 , C08F220/28 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition having high transparency to a radiation and useful as a chemically amplified resist excellent in sensitivity, resolution, dry etching resistance and pattern shape. SOLUTION: The radiation-sensitive resin composition comprises (A) a resin typified by a copolymer of 2-methyl-2-adamantyl methacrylate, 3-hydroxy-1- adamantyl methacrylate and a methacrylic ester of formula (1), (B) a radiation- sensitive acid generator typified by triphenylsulfonium nonafluoro-n- butanesulfonate or 1-(4-n-butoxy-1-naphthyl)tetrahydrothiophenium perfluoro-n- octanesulfonate and (C) a solvent. Preferably the solvent (C) includes at least one selected from the group comprising propylene glycol monomethyl ether acetate, 2-heptanone and cyclohexanone. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2004029089A
公开(公告)日:2004-01-29
申请号:JP2002181130
申请日:2002-06-21
Applicant: Internatl Business Mach Corp
, Jsr Corp , Jsr株式会社 , インターナショナル・ビジネス・マシーンズ・コーポレーションInternational Business Maschines Corporation Inventor: NISHIMURA YUKIO , NISHIMURA ISAO , SAITO AKIO , KOBAYASHI HIDEKAZU , TOMAS I WOROU , ALLEN ROBERT D , VARANASI PUSHKARA RAO
IPC: G03F7/039 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition having high transparency to a radiation and suitable for use as a chemically sensitized resist excellent in basic properties as a resist, such as sensitivity, resolution, dry etching resistance and pattern shape. SOLUTION: The radiation-sensitive resin composition comprises (A) an acid-dissociating group-containing resin containing a (meth)acrylic ester repeating unit typified by a unit derived from 2-ethyladamantan-2-yl ester or 1-methylcyclopentyl ester of (meth)acrylic acid and a repeating unit having a norbornane skeleton in the backbone typified by a unit derived from 1-methylcyclopentyl ester or (2-ethyladamantan-2-yl) ester of a bicyclo[2,2,1]hept-2-ene-5-carboxylic acid and not containing a repeating unit derived from maleic anhydride and (B) a radiation-sensitive acid generator. COPYRIGHT: (C)2004,JPO
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公开(公告)号:JP2003255539A
公开(公告)日:2003-09-10
申请号:JP2002056522
申请日:2002-03-01
Inventor: NISHIMURA YUKIO , ISHII HIROYUKI , KOBAYASHI HIDEKAZU , TOMAS I WOROU , ALLEN ROBERT D , VARANASI PUSHKARA RAO
IPC: G03F7/039 , C08F220/18 , C08F220/28 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition having high transparency to a radiation and suitable for use as a chemically amplified resist excellent in basic performances as a resist, such as sensitivity, resolution, dry etching resistance and pattern shape. SOLUTION: The radiation-sensitive resin composition comprises (A) an alkali-insoluble or slightly alkali-soluble resin which has a repeating unit represented by formula (1-1) (where R 1 is H or methyl) and a (meth)acrylic repeating unit typified by 2-ethyl-2-adamantyl (meth)acrylate, 2-norbornyl-2-(meth) acryloyloxypropane or 1-methylcyclopentyl (meth)acrylate as essential units and becomes alkali-soluble under the action of an acid and (B) a radiation- sensitive acid generator. COPYRIGHT: (C)2003,JPO
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公开(公告)号:JP2003248313A
公开(公告)日:2003-09-05
申请号:JP2002046974
申请日:2002-02-22
Inventor: NISHIMURA YUKIO , ISHII HIROYUKI , KATAOKA ATSUKO , TOMAS I WOROU , ALLEN ROBERT D , VARANASI PUSHKARA RAO
IPC: G03F7/039 , C08F222/06 , C08F232/08 , H01L21/027
Abstract: PROBLEM TO BE SOLVED: To provide a new radiation-sensitive resin composition having high transparency to a radiation, excellent in basic physical properties as a resist, such as sensitivity, resolution, pattern shape and adhesion to a substrate, causing no development defect in microfabrication and capable of producing semiconductor devices in a high yield. SOLUTION: The radiation-sensitive resin composition comprises (A) an acid-dissociable group-containing resin having a repeating unit represented by formula (I) and a repeating unit represented by formula (II) and (B) a radiation-sensitive acid generator. In the formula (I), X is methylene or carbonyl; R 1 and R 2 are each H, a 1-4C alkyl, a monovalent O-containing polar group or a monovalent N-containing polar group; R 3 is H, a 1-6C alkyl, a 1-6C alkoxyl or a 2-7C alkoxycarbonyl; and n is an integer of 0-2. COPYRIGHT: (C)2003,JPO
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