公开(公告)号：US08986642B2

公开(公告)日：2015-03-24

申请号：US13770577

申请日：2013-02-19

Applicant: BASF SE

Inventor： Angela Siegel ,  Tobias Eckardt ,  Andreas Braedikow ,  Thorsten Puvogel

IPC: C03C11/00 ,  C01B33/193 ,  C08F4/02 ,  C08F4/00 ,  B01J21/08 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J37/03 ,  C01B13/32 ,  C01B33/16 ,  C01B33/187 ,  B01J23/24 ,  B01J23/40 ,  B01J23/70 ,  C08F110/02 ,  C08F110/06

CPC classification number: C01B33/193 ,  B01J21/08 ,  B01J23/24 ,  B01J23/40 ,  B01J23/70 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/031 ,  C01B13/328 ,  C01B33/166 ,  C01B33/187 ,  C01P2004/32 ,  C01P2004/52 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/14 ,  C08F4/00 ,  C08F4/02 ,  C08F110/02 ,  C08F110/06 ,  Y10T428/2982

Abstract: The present invention relates to spherical beads comprising at least one metal and/or semimetal oxide, having a mean diameter in the range from 10 to 120 μm, a BET surface area in the range from 400 to 800 m2/g and a pore volume in the range from 0.3 to 3.0 cm3/g, wherein the diameter of a given bead at any one point of said bead deviates by less than 10% from the average diameter of said bead and the surface of said bead is substantially smooth, and also to a process for producing these spherical beads, to a particulate catalyst comprising the spherical beads and to the use of the spherical beads as catalysts or catalyst carriers.

Abstract translation: 本发明涉及包含至少一种金属和/或半金属氧化物的球形珠粒，其平均直径为10至120μm，BET表面积为400-800m2 / g，孔体积为 范围为0.3至3.0cm 3 / g，其中在所述珠的任何一点处的给定珠粒的直径与所述珠粒的平均直径相差小于10％，并且所述珠粒的表面基本上平滑，并且还 用于制备这些球形珠粒的方法，包括球形珠粒的颗粒催化剂和使用球形珠粒作为催化剂载体。

公开(公告)号：US08986580B2

公开(公告)日：2015-03-24

申请号：US13503132

申请日：2011-03-11

Applicant: Manabu Furudate ,  Tomohiro Inoue ,  Yoshitsugu Eguchi ,  Tadashi Amano

Inventor： Manabu Furudate ,  Tomohiro Inoue ,  Yoshitsugu Eguchi ,  Tadashi Amano

IPC: C01G23/053 ,  C01B15/047 ,  C01G23/047 ,  C09C1/36 ,  B01J37/03 ,  B01J37/10 ,  B01J21/06 ,  B01J23/835 ,  B01J35/00 ,  B01J35/08

CPC classification number: C01G23/047 ,  B01J21/063 ,  B01J23/835 ,  B01J35/004 ,  B01J35/006 ,  B01J35/08 ,  B01J37/031 ,  B01J37/10 ,  C01P2004/04 ,  C01P2006/60 ,  C09C1/3653 ,  Y10T428/2991

Abstract: Disclosed are: a visible-light-responsive titanium oxide microparticle dispersion comprising an aqueous dispersion medium and titanium oxide microparticles dispersed therein, and a peroxotitanium component, an iron component and/or a copper component and a tin component, wherein the content of the peroxotitanium component is 0.1 to 20 mass % relative to the titanium oxide content; and a process for producing a visible-light-responsive titanium oxide microparticle dispersion, comprising (1) producing peroxotitanic acid containing a tin compound from a raw material titanium compound, a tin compound and hydrogen peroxide, (2) heating an aqueous solution of peroxotitanic acid containing the tin compound to 80 to 250° C. under a high pressure to produce a titanium oxide microparticle dispersion containing a peroxotitanium component and a tin component, and (3) adding an iron compound and/or a copper compound to the titanium oxide microparticle dispersion to cause a reaction between the iron compound and/or the copper compound with the dispersion.

Abstract translation: 本发明公开了一种包含水分散介质和分散在其中的氧化钛微粒以及过氧钛组分，铁组分和/或铜组分和锡组分的可见光响应的氧化钛微粒分散体，其中过氧钛 成分相对于氧化钛含量为0.1〜20质量％ 以及（1）从原料钛化合物，锡化合物和过氧化氢制备含有锡化合物的过氧钛酸的方法，（2）将过氧钛酸水溶液 含有锡化合物的酸在80〜250℃下高压制造含有过氧钛成分和锡成分的氧化钛微粒分散体，（3）将铁化合物和/或铜化合物加入氧化钛 微粒分散体引起铁化合物和/或铜化合物与分散体之间的反应。

公开(公告)号：US20130026072A1

公开(公告)日：2013-01-31

申请号：US13191939

申请日：2011-07-27

Applicant: Abdennour BOURANE ,  Omer Refa Koseoglu ,  Zinfer Ismagilov ,  Svetlana Yashnik ,  Mikhail Kerzhentsev ,  Valentin Parmon

Inventor： Abdennour BOURANE ,  Omer Refa Koseoglu ,  Zinfer Ismagilov ,  Svetlana Yashnik ,  Mikhail Kerzhentsev ,  Valentin Parmon

IPC: C10G29/16 ,  B01J35/08 ,  B01J37/08 ,  B01J35/10 ,  B01J37/03 ,  B01J21/02 ,  B01J35/02

CPC classification number: B01J35/023 ,  B01J23/005 ,  B01J23/80 ,  B01J23/83 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/009 ,  B01J37/031 ,  C10G27/00 ,  C10G29/16

Abstract: A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide, with a spinel formula and highly dispersed crystals of ZnO, CuO, and optionally CeO2. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.

Abstract translation: 公开了一种催化组合物，其显示出具有尖晶石配方的X射线无定形氧化物和ZnO，CuO和任选的CeO 2的高度分散的晶体。 该组合物可用于从气态烃中除去硫的氧化过程。

公开(公告)号：US20110212829A1

公开(公告)日：2011-09-01

申请号：US13049412

申请日：2011-03-16

Applicant: Felice DiMascio

Inventor： Felice DiMascio

IPC: B01J21/06 ,  B01J31/06 ,  B01J27/182 ,  B01J27/06 ,  B01J27/053 ,  B01J27/24 ,  B01J21/16 ,  B01J21/12 ,  B01J37/04 ,  B01J37/08 ,  B01J35/10 ,  B01J35/08

CPC classification number: B01J37/0009 ,  B01J35/08 ,  B01J37/0072 ,  B01J38/02 ,  C04B35/565 ,  C04B35/6303

Abstract: A process for making a ceramic catalyst material includes mixing a catalyst precursor material with a mineral particulate to form a mixture; adding a binder, silicon carbide, and a parting agent to the mixture to form unfired spheroids; and heating the unfired spheroids at a temperature effective to oxidize the silicon carbide and the catalyst precursor material to form the ceramic catalyst material. In another embodiment, the process includes the addition of a catalyst metal oxide salt to an aluminosilicate hydrogel aggregate mixture. Once the mixture sets, the set mixture is heated to a temperature to effective to produce a high surface area ceramic catalyst material.

Abstract translation: 制备陶瓷催化剂材料的方法包括将催化剂前体材料与矿物颗粒混合以形成混合物; 向混合物中加入粘合剂，碳化硅和脱模剂以形成未烧结的球体; 并在有效氧化碳化硅和催化剂前体材料的温度下加热未烧结的球体以形成陶瓷催化剂材料。 在另一个实施方案中，该方法包括向铝硅酸盐水凝胶骨料混合物中加入催化剂金属氧化物盐。 一旦混合物组合，将固化混合物加热到有效的温度以产生高表面积的陶瓷催化剂材料。

公开(公告)号：US20110195013A1

公开(公告)日：2011-08-11

申请号：US13087523

申请日：2011-04-15

Applicant: Seung Yong BAE ,  Byeong Yeol KIM ,  Yun Tack LEE ,  Young Kyu CHANG ,  Young Sil LEE

Inventor： Seung Yong BAE ,  Byeong Yeol KIM ,  Yun Tack LEE ,  Young Kyu CHANG ,  Young Sil LEE

IPC: D01F9/127 ,  B01J21/04 ,  B01J21/10 ,  B01J21/08 ,  B01J35/10 ,  B01J35/08 ,  B01J37/08 ,  B01J23/745 ,  B01J23/755 ,  B01J23/75 ,  D01F9/12 ,  B82Y40/00

CPC classification number: B82Y40/00 ,  B01J23/002 ,  B01J23/74 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0045 ,  B01J37/08 ,  B01J2523/00 ,  B82Y30/00 ,  C01B32/15 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845

Abstract: The present invention provides a supported catalyst for synthesizing carbon nanotubes. The supported catalyst includes a metal catalyst supported on a supporting body, and the supported catalyst has a surface area of about 15 to about 100 m2/g. The supported catalyst for synthesizing carbon nanotubes according to the present invention can lower production costs by increasing surface area of a catalytic metal to thereby allow production of a large amount of carbon nanotubes using a small amount of the catalyst.

Abstract translation: 本发明提供了一种用于合成碳纳米管的载体催化剂。 负载型催化剂包括负载在支撑体上的金属催化剂，负载型催化剂的表面积为约15〜约100m 2 / g。 根据本发明的用于合成碳纳米管的载体催化剂可以通过增加催化金属的表面积来降低生产成本，从而允许使用少量的催化剂生产大量的碳纳米管。

公开(公告)号：US20110180513A1

公开(公告)日：2011-07-28

申请号：US13080738

申请日：2011-04-06

Applicant: Claudia Luhrs ,  Jonathan Phillips ,  Monique N. Richard ,  Angela Michelle Knapp

Inventor： Claudia Luhrs ,  Jonathan Phillips ,  Monique N. Richard ,  Angela Michelle Knapp

IPC: B01J35/08 ,  B01J37/02 ,  H05H1/24 ,  C23C16/26 ,  B05D3/14 ,  H05H1/32 ,  C03C25/68

CPC classification number: B01J21/18 ,  B01J13/04 ,  B01J23/40 ,  B01J23/48 ,  B01J23/74 ,  B01J35/08 ,  B01J37/0018 ,  C01B32/05 ,  C04B35/62839 ,  C04B38/009 ,  C04B2111/0081 ,  C04B2235/40 ,  Y10T428/2982 ,  Y10T428/2991 ,  C04B35/52 ,  C04B38/0054

Abstract: A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.

Abstract translation: 公开了一种具有碳壳和内芯的中空碳球。 中空碳球的总体积等于碳壳的体积加上碳壳内的内部自由体积。 内部自由体积是总体积的至少25％。 在一些情况下，中空碳球的公称直径在10和180纳米之间。

公开(公告)号：US07803266B2

公开(公告)日：2010-09-28

申请号：US11086556

申请日：2005-03-23

Applicant: Denis Guillaume ,  Stéphane Kressmann ,  Magalie Roy-Auberger

Inventor： Denis Guillaume ,  Stéphane Kressmann ,  Magalie Roy-Auberger

IPC: C10G11/00 ,  C10G45/04 ,  C10G45/08 ,  C10G45/60 ,  C10G47/00 ,  B01J35/08 ,  B01J35/10

CPC classification number: B01J23/24 ,  B01J21/04 ,  B01J23/85 ,  B01J23/883 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/0207 ,  C10G45/00 ,  C10G45/04 ,  C10G65/02 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/703

Abstract: A catalyst and process for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, said catalyst comprising a support in the form of beads based on alumina, at least one catalytic metal or a compound of a catalytic metal from group VIB (column 6 in the new periodic table notation), optionally at least one catalytic metal or compound of a catalytic metal from group VIII (columns 8, 9 and 10 of the new periodic table notation), with a pore structure composed of a plurality of juxtaposed agglomerates, each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially orientated with respect to each other and with respect to the center of the agglomerate. The catalyst also comprises at least one doping element selected from the group constituted by phosphorus, boron, silicon (or silica which does not belong to that which could be contained in the selected support) and halogens.

Abstract translation: 用于加氢处理和/或加氢转化含重金属的烃进料的催化剂和方法，所述催化剂包含基于氧化铝的珠粒形式的载体，至少一种催化金属或来自VIB族的催化金属的化合物 新的周期表符号），任选的至少一种催化金属或来自第VIII族的催化金属（新的周期表符号的第8,9和10条）的化合物，具有由多个并置的附聚物组成的孔结构，每个 由多个针状血小板形成，每个附聚物的血小板通常相对于彼此和相对于附聚物的中心径向取向。 所述催化剂还包含至少一种选自磷，硼，硅（或二氧化硅）的掺杂元素，该组不属于所选载体中可包含的掺杂元素）和卤素。

公开(公告)号：US07442365B1

公开(公告)日：2008-10-28

申请号：US10867200

申请日：2004-06-14

Applicant: Lance L. Jacobsen ,  Brian S. Konrad ,  David A. Lesch ,  Beckay J. Mezza ,  James G. Vassilakis ,  Cynthia R. Berinti-Vondrasek

Inventor： Lance L. Jacobsen ,  Brian S. Konrad ,  David A. Lesch ,  Beckay J. Mezza ,  James G. Vassilakis ,  Cynthia R. Berinti-Vondrasek

IPC: C01B39/02 ,  C01B39/54 ,  B01J35/08 ,  B01J29/04 ,  B01J29/06 ,  B01J29/08

CPC classification number: C01B39/54 ,  B01J29/06 ,  B01J29/084 ,  B01J35/023 ,  B01J35/08 ,  B01J37/009 ,  B01J37/10 ,  B01J2229/36 ,  B01J2229/62 ,  C01B37/08 ,  C10G11/05 ,  C10G25/03 ,  C10G45/34 ,  C10G45/46 ,  C10G45/60 ,  C10G47/16 ,  C10G49/08

Abstract: A process for preparing beads of various compositions has been developed. The process involves preparing a reaction mixture of sources of framework elements of a molecular sieve. The reaction mixture can optionally contain molecular sieve seeds. Additional sources of the framework elements are added to give a concentration above the critical supersaturation limit thereby forming beads. Depending on the composition of the reaction mixture and the reaction conditions one can obtain beads which are substantially amorphous, to beads that are substantially crystalline molecular sieve. These beads in turn can be further processed to deposit a molecular sieve layer onto the beads.

Abstract translation: 已经开发了制备各种组合物的珠粒的方法。 该方法包括制备分子筛骨架元素来源的反应混合物。 反应混合物可任选地含有分子筛种子。 加入骨架元素的其它来源以提供高于临界过饱和极限的浓度，从而形成珠粒。 根据反应混合物的组成和反应条件，可以获得基本上无定形的珠子，其为基本上为结晶分子筛的珠粒。 这些珠又可以进一步加工，以将分子筛层沉积在珠上。

公开(公告)号：US20080177105A1

公开(公告)日：2008-07-24

申请号：US12015741

申请日：2008-01-17

Applicant: Andreas Raichle ,  Frank Rosowski ,  Sabine Huber ,  Ulrich Cremer ,  Stefan Altwasser ,  Klaus Joachim Mueller-Engel

Inventor： Andreas Raichle ,  Frank Rosowski ,  Sabine Huber ,  Ulrich Cremer ,  Stefan Altwasser ,  Klaus Joachim Mueller-Engel

IPC: C07C51/16 ,  C07C51/235 ,  C07C45/27 ,  B01J21/18 ,  B01J35/08

CPC classification number: B01J32/00 ,  B01J21/18 ,  B01J23/002 ,  B01J23/8885 ,  B01J27/186 ,  B01J37/0009 ,  B01J37/0018 ,  B01J2523/00 ,  C07C51/215 ,  C07C51/252 ,  C07C57/04 ,  C07C57/145 ,  B01J2523/13 ,  B01J2523/27 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/845 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62 ,  B01J2523/69

Abstract: A process for preparing shaped catalyst bodies whose active composition is a multielement oxide, in which a finely divided precursor mixture with addition of graphite having a specific particle size is shaped to the desired geometry and then treated thermally.

Abstract translation: 一种制备活性组合物为多元素氧化物的成形催化剂体的方法，其中加入具有特定粒度的石墨的细碎前体混合物成形为所需几何形状，然后热处理。

公开(公告)号：US20070264181A1

公开(公告)日：2007-11-15

申请号：US11576049

申请日：2005-07-05

Applicant: Steffen Heidenreich ,  Manfred Nacken

Inventor： Steffen Heidenreich ,  Manfred Nacken

IPC: B01D53/56 ,  B01J35/08

CPC classification number: B01J35/04 ,  B01D39/2075 ,  B01D39/2086 ,  B01D53/8628 ,  B01D53/8668 ,  B01D67/0041 ,  B01D67/0083 ,  B01D67/0088 ,  B01D69/04 ,  B01D71/024 ,  B01D2239/0258 ,  B01D2255/20707 ,  B01D2257/708 ,  B01D2323/46 ,  B01D2325/10 ,  B01J21/063 ,  B01J23/30 ,  B01J35/06 ,  B01J37/0018 ,  B01J37/0242 ,  F01N3/035 ,  F01N3/2825 ,  F01N2330/06 ,  F01N2330/14 ,  F01N2570/14 ,  Y02A50/2344

Abstract: A catalytically active porous element for promoting catalytic gas phase reactions is proposed, said element comprising a porous structural element of sintered ceramic or metallic primary particles, which are selected from fibrous and/or granular particles, a secondary structure of titania nano particles deposited on the surface of said sintered primary particles and a catalytic component deposited on the surface of the titania nano particles. Thereby porous catalytic elements for catalytic gas phase reactions which are useful not only in NOX reduction reactions but also for other catalytic gas phase reactions are provided.

Abstract translation: 提出了用于促进催化气相反应的催化活性多孔元件，所述元件包括选自纤维和/或粒状颗粒的烧结陶瓷或金属一次粒子的多孔结构元件，沉积在其上的二氧化钛纳米颗粒的二级结构 所述烧结的一次粒子的表面和沉积在二氧化钛纳米颗粒的表面上的催化组分。 因此，提供用于催化气相反应的多孔催化元件，其不仅可用于NO X X还原反应，而且可用于其它催化气相反应。