公开(公告)号：US09573862B2

公开(公告)日：2017-02-21

申请号：US14419135

申请日：2013-08-09

Applicant: ASAHI KASEI CHEMICALS CORPORATION

Inventor： Takehiro Iitsuka ,  Yoshikazu Takamatsu

IPC: C07C2/42 ,  B01J21/08 ,  B01J29/40 ,  B01J8/18 ,  B01J8/00 ,  C07C1/20 ,  B01J37/10 ,  B01J37/28 ,  B01J29/06 ,  B01J29/064 ,  B01J35/00 ,  B01J37/00 ,  B01J37/08 ,  B01J29/068 ,  C07C6/04 ,  C07C2/76 ,  C10G3/00 ,  B01J38/00 ,  B01J38/14 ,  B01J38/30

CPC classification number: C07C2/42 ,  B01J8/0055 ,  B01J8/1809 ,  B01J21/08 ,  B01J29/061 ,  B01J29/064 ,  B01J29/068 ,  B01J29/40 ,  B01J35/0026 ,  B01J35/0033 ,  B01J37/0045 ,  B01J37/084 ,  B01J37/105 ,  B01J37/28 ,  B01J38/00 ,  B01J38/14 ,  B01J38/30 ,  B01J2208/0007 ,  B01J2208/00584 ,  B01J2208/00681 ,  B01J2208/00734 ,  B01J2229/12 ,  B01J2229/186 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C07C1/20 ,  C07C2/76 ,  C07C6/04 ,  C07C2529/40 ,  C10G3/44 ,  C10G3/49 ,  C10G3/57 ,  C10G3/60 ,  C10G2300/703 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P20/52 ,  Y02P20/582 ,  Y02P20/584 ,  Y02P20/588 ,  C07C11/06 ,  C07C15/02

Abstract: A method for converting an olefin or an alcohol has a pretreatment step of obtaining a conductive catalyst by a pretreatment for suppressing electrostatic charging of a non-conductive catalyst and a step of converting an olefin or an alcohol by a fluidized bed reaction using the conductive catalyst.

Abstract translation: 用于转化烯烃或醇的方法具有通过用于抑制非导电催化剂的静电充电的预处理获得导电催化剂的步骤和使用导电催化剂通过流化床反应转化烯烃或醇的步骤 。

公开(公告)号：US20170022238A1

公开(公告)日：2017-01-26

申请号：US15124939

申请日：2015-03-10

Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY

Inventor： Michikazu HARA ,  Kiyotaka NAKAJIMA ,  Daiki TAKEDA

IPC: C07H3/02 ,  B01J27/18 ,  B01J37/28 ,  B01J27/16

CPC classification number: C07H3/02 ,  B01J21/04 ,  B01J23/08 ,  B01J27/16 ,  B01J27/1811 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/28 ,  C07H1/00

Abstract: A novel catalyst capable of selectively catalyzing conversion from glucose to fructose in water or in an aqueous solution is provided. The catalyst is a solid catalyst for a hydride isomerization reaction from glucose to fructose performed in water or in an aqueous solution, comprising a group 13 element oxide whose surface has been subjected to a phosphoric acid treatment.

Abstract translation: 提供了能够选择性催化从水中或水溶液中的葡萄糖转化为果糖的新型催化剂。 该催化剂是在水中或在水溶液中进行的从葡萄糖到果糖的氢化物异构化反应的固体催化剂，其包含其表面进行了磷酸处理的13族元素氧化物。

公开(公告)号：US09527064B2

公开(公告)日：2016-12-27

申请号：US13818113

申请日：2011-11-24

Applicant: Kenji Akagishi ,  Ryusuke Miyazaki

Inventor： Kenji Akagishi ,  Ryusuke Miyazaki

IPC: B01J29/06 ,  B01J29/40 ,  C07C1/20 ,  C07C2/00 ,  C07C11/06 ,  B01J29/80 ,  B01J29/90 ,  B01J35/00 ,  B01J35/08 ,  C10G3/00 ,  B01J37/00 ,  B01J37/28 ,  B01J29/70 ,  B01J29/85

CPC classification number: C07C1/20 ,  B01J21/08 ,  B01J29/06 ,  B01J29/40 ,  B01J29/7015 ,  B01J29/80 ,  B01J29/85 ,  B01J29/90 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/08 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/10 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/42 ,  C07C1/24 ,  C07C2/00 ,  C07C2/12 ,  C07C2/86 ,  C07C2/862 ,  C07C2/864 ,  C07C2/865 ,  C07C11/06 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/82 ,  C07C2529/85 ,  C10G3/49 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/04

Abstract: The present invention provides a method for producing a silica composite by the steps of: preparing a raw material mixture containing silica and zeolite; drying the raw material mixture to obtain a dried product; and calcining the dried product, wherein the method comprising the step of allowing the raw material mixture to contain phosphoric acid and/or phosphate or bringing a solution of phosphoric acid and/or phosphate into contact with the zeolite and/or the dried product, or a combination thereof to thereby adjust a phosphorus content in the silica composite to 0.01 to 1.0% by mass based on the total mass of the silica composite.

Abstract translation: 本发明提供了一种通过以下步骤制备二氧化硅复合材料的方法：制备含有二氧化硅和沸石的原料混合物; 干燥原料混合物得到干燥产品; 和煅烧所述干燥产物，其中所述方法包括使所述原料混合物含有磷酸和/或磷酸盐或使磷酸和/或磷酸盐溶液与沸石和/或干燥产物接触的步骤，或 由此将二氧化硅复合体中的磷含量相对于二氧化硅复合体的总质量调整为0.01〜1.0质量％。

公开(公告)号：US09486789B2

公开(公告)日：2016-11-08

申请号：US14663731

申请日：2015-03-20

Applicant: IFP Energies nouvelles ,  ENI S.P.A.

Inventor： Dominique Decottignies ,  Fabrice Diehl ,  Vincent Lecocq ,  Marie Velly

IPC: B01J21/04 ,  B01J21/12 ,  B01J23/34 ,  B01J23/58 ,  B01J27/185 ,  B01J23/75 ,  C10G2/00 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J27/1853 ,  B01J21/12 ,  B01J23/005 ,  B01J23/75 ,  B01J23/755 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0209 ,  B01J37/08 ,  B01J37/088 ,  B01J37/28 ,  C10G2/33 ,  C10G2/332 ,  C10G2/342

Abstract: The present invention describes a catalyst containing an active phase comprising at least one metal of group VIIIB selected from cobalt, nickel, ruthenium and iron deposited on an oxides support comprising alumina, silica, a spinel and phosphorus. It also concerns the process for preparation of said catalyst and its use in a Fischer-Tropsch process. The catalyst has an improved hydrothermal and mechanical resistance in a Fischer-Tropsch process while improving its catalytic performances.

Abstract translation: 本发明描述了一种含有活性相的催化剂，该活性相包含沉积在包含氧化铝，二氧化硅，尖晶石和磷的氧化物载体上的至少一种选自钴，镍，钌和铁的ⅧB族金属。 它还涉及制备所述催化剂的方法及其在费 - 托方法中的应用。 催化剂在费 - 托方法中具有改进的水热和机械阻力，同时改善其催化性能。

公开(公告)号：US20160130195A1

公开(公告)日：2016-05-12

申请号：US14982035

申请日：2015-12-29

Applicant: Total Research & Technology Feluy

Inventor： Nikolai Nesterenko ,  Walter Vermeiren ,  Sander Van Donk

IPC: C07C1/20 ,  C08F10/06 ,  C07C4/06

CPC classification number: C07C1/20 ,  B01J21/16 ,  B01J23/00 ,  B01J27/16 ,  B01J29/06 ,  B01J29/08 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/7007 ,  B01J29/7026 ,  B01J29/7038 ,  B01J29/7046 ,  B01J37/10 ,  B01J37/28 ,  B01J2029/081 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/42 ,  C07C4/06 ,  C07C2529/40 ,  C08F10/06 ,  Y02P30/42 ,  C07C11/02

Abstract: A catalyst composite may include a molecular sieve having pores of 10- or more-membered rings and a metal silicate different from the molecular sieve. The metal silicate may include at least one alkaline earth metal and one or more of the following metals: Ga, Al, Ce, In, Cs, Sc, Sn, Li, Zn, Co, Mo, Mn, Ni, Fe, Cu, Cr, Ti and V. The catalyst composite may include at least 0.1 wt % of silicate. The catalyst composite may be used in an XTO reactor or for catalytic cracking.

Abstract translation: 催化剂复合物可以包括具有10或更多元环孔和不同于分子筛的金属硅酸盐的分子筛。 金属硅酸盐可以包括至少一种碱土金属和一种或多种以下金属：Ga，Al，Ce，In，Cs，Sc，Sn，Li，Zn，Co，Mo，Mn，Ni，Fe，Cu， Cr，Ti和V.催化剂复合材料可以包括至少0.1重量％的硅酸盐。 催化剂复合材料可用于XTO反应器或用于催化裂化。

公开(公告)号：US09284492B2

公开(公告)日：2016-03-15

申请号：US13900725

申请日：2013-05-23

Applicant: Saudi Arabian Oil Company ,  King Fahd University of Petroleum and Minerals

Inventor： Musaed Salem Al-Ghrami ,  Cemal Ercan ,  Sulaiman S. Al-Khattaf ,  Mohammed Abdul Bari Siddiqui ,  Abdullah M. Aitani

IPC: B01J29/06 ,  C10G11/05 ,  B01J29/80 ,  B01J38/00 ,  B01J38/02 ,  B01J29/08 ,  B01J29/40 ,  B01J29/90 ,  B01J35/02 ,  C10G11/18 ,  B01J35/00 ,  B01J21/16 ,  B01J37/28

CPC classification number: C10G11/05 ,  B01J21/16 ,  B01J29/084 ,  B01J29/40 ,  B01J29/80 ,  B01J29/90 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/28 ,  B01J38/00 ,  B01J38/02 ,  B01J2229/186 ,  B01J2229/24 ,  C07C4/06 ,  C10G11/18 ,  C10G11/182 ,  C10G2400/02 ,  C10G2400/20

Abstract: A fluid catalytic cracking catalyst for increased production of propylene and gasoline from heavy hydrocarbon feedstock, the catalyst comprising between 10 and 20% by weight of an ultra-stable Y-type zeolite, between 10 and 20% by weight of a phosphorous modified sub-micron ZSM-5, between 20 and 30% by weight of a pseudoboehmite alumina, and between 30 and 40% by weight kaolin.

Abstract translation: 一种用于从重质烃原料增加丙烯和汽油生产的流化催化裂化催化剂，该催化剂包含10至20重量％的超稳定Y型沸石，10至20重量％的磷改性亚烷基， 微米级ZSM-5，20〜30重量％的假勃姆石氧化铝，以及30〜40重量％的高岭土。

公开(公告)号：US09260356B2

公开(公告)日：2016-02-16

申请号：US14592756

申请日：2015-01-08

Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY

Inventor： Nikolai Nesterenko ,  Sander Van Donk ,  Delphine Minoux ,  Jean-Pierre Dath

IPC: C07C1/24 ,  B01J29/06 ,  B01J29/40 ,  B01J37/00 ,  B01J37/28 ,  C07C1/20 ,  B01J29/85 ,  B01J37/06 ,  B01J37/08 ,  B01J27/16

CPC classification number: C07C1/24 ,  B01J27/16 ,  B01J29/06 ,  B01J29/40 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C07C1/20 ,  C07C2529/40 ,  C07C2529/85 ,  C07C11/02

Abstract: The present invention is the use of a catalyst in a MTO process to convert an alcohol or an ether into light olefins wherein said catalyst comprises a phosphorus modified zeolite and is made by a method comprising the following steps in this order,a) the essential portion of the phosphorus is introduced into a zeolite comprising at least one ten members ring in the structure,b) the phosphorus modified zeolite of step a) is mixed with at least a component selected among one or more binders, salts of alkali-earth metals, salts of rare-earth metals, clays and shaping additives,b)* making a catalyst body from mixture b),c) an optional drying step or an optional drying step followed by a washing step,d) a calcination step,d*) an optional washing step followed by drying,e) optionally a small portion of phosphorus is introduced in the course of step b) or b)* or at end of step b) or b)*.

公开(公告)号：US20150367328A1

公开(公告)日：2015-12-24

申请号：US14764350

申请日：2014-01-31

Applicant: UMICORE SHOKUBAI JAPAN CO., LTD.

Inventor： Masanori IKEDA ,  Kazuyoshi KOMATA ,  Shigekazu MINAMI ,  Yuji OGINO ,  Hideki GOTO

IPC: B01J23/63 ,  B01D53/94 ,  B01J35/00

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/40 ,  B01D2255/407 ,  B01D2255/9022 ,  B01J23/002 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0036 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/04 ,  B01J37/28 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/31 ,  B01J2523/36 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/824

Abstract: As a way to suppress deterioration of catalytic performance in an exhaust gas purification catalyst even after being exposed to an exhaust gas containing a phosphorus compound, an exhaust gas purification catalyst is provided. The catalyst purifies an exhaust gas containing a phosphorus compound, and the catalyst includes a catalyst layer containing rhodium (Rh), palladium (Pd), and either a ceria-zirconia-lanthana complex oxide or a ceria-zirconia-lanthana-yttria complex oxide as catalyst active components. Further, an average value of distances between Rh particles and the nearest Pd particles of the Rh and the Pd is within 4000 nm, a weight ratio of the Pd to the Rh is from 0.2 to 4.9, and a content rate of yttria in the ceria-zirconia-lanthana-yttria complex oxide is 19% by weight or less.

Abstract translation: 作为排出气体净化催化剂的催化性能劣化的方法，即使在暴露于含有磷化合物的废气的情况下也能够提供排气净化催化剂。 催化剂净化含有磷化合物的废气，催化剂包括含有铑（Rh），钯（Pd）和二氧化铈 - 氧化锆 - 氧化镧复合氧化物或二氧化铈 - 氧化锆 - 氧化镧 - 氧化钇复合氧化物的催化剂层 作为催化剂活性成分。 此外，Rh颗粒与Rh和Pd的最近的Pd颗粒之间的距离的平均值在4000nm以内，Pd与Rh的重量比为0.2-4.9，二氧化铈中的氧化钇含量 氧化锆 - 氧化镧 - 氧化钇复合氧化物的重量百分比为19重量％以下。

公开(公告)号：US09212116B2

公开(公告)日：2015-12-15

申请号：US14416209

申请日：2012-07-24

Applicant: Kunyuan Wang ,  Yunpeng Xu ,  Zhongmin Liu

Inventor： Kunyuan Wang ,  Yunpeng Xu ,  Zhongmin Liu

IPC: C07C37/11 ,  C07C37/16 ,  B01J29/00 ,  B01J29/40 ,  B01J29/70

CPC classification number: C07C37/11 ,  B01J29/00 ,  B01J29/40 ,  B01J29/46 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7615 ,  B01J29/7676 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C07C37/16 ,  Y02P20/52 ,  C07C39/07

Abstract: The present invention relates to a method for producing cresol from phenol and methanol via gas phase alkylation, in which phenol and methanol are preheated and mixed with diluent gas, then the mixture continuously go through a catalyst bed comprising the catalyst for alkylation of phenol with methanol, to produce cresol by gas phase reaction at the reaction temperature of 200˜500° C. and the weight hourly space velocity of 0.5˜20 h−1. The catalyst for alkylation of phenol with methanol is obtained by modification steps and using ZSM-5 zeolite, MCM-22 zeolite or Beta zeolite as an active composition. Using phenol and methanol as feedstock, the cresol selectivity can reach to 90%, and the p-cresol selectivity can reach to 58%. The catalyst is environmental friendly and non-corrosive to the equipment with a good stability and a broad prospect in industrial application.

Abstract translation: 本发明涉及一种通过气相烷基化从苯酚和甲醇生产甲酚的方法，其中苯酚和甲醇被预热并与稀​​释气体混合，然后将混合物连续地通过催化剂床，该催化剂床包含用甲醇烷基化苯酚的催化剂 在200〜500℃的反应温度下通过气相反应生产甲酚，重时空速为0.5〜20h-1。 用甲醇烷基化苯酚的催化剂是通过改性步骤和使用ZSM-5沸石，MCM-22沸石或β沸石作为活性组合物得到的。 使用苯酚和甲醇作为原料，甲酚选择性可以达到90％，对甲酚的选择性可以达到58％。 催化剂环保，无腐蚀性，稳定性好，工业应用前景广阔。

公开(公告)号：US20150352541A1

公开(公告)日：2015-12-10

申请号：US14378767

申请日：2013-02-15

Applicant: Dennis Stamires ,  Michael Brady

Inventor： Dennis Stamires ,  Michael Brady

IPC: B01J31/26 ,  B01J35/02 ,  B01J31/06

CPC classification number: B01J31/26 ,  B01J21/16 ,  B01J29/06 ,  B01J29/08 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J31/06 ,  B01J35/023 ,  B01J35/1061 ,  B01J35/1071 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/42 ,  B01J2231/005 ,  B01J2231/49 ,  C10G1/086 ,  C10G3/49 ,  Y02P30/20

Abstract: Processes for making a catalytic system and catalytic systems for converting solid biomass into fuel or specialty chemical products, or for upgrading bio-oils are described. The catalyst system may comprise a non-zeolitic matrix with a hierarchical pore structure ranging from 300 to about 104 Angstrom pore size, a zeolite, such as MFI-type or IM-5 zeolite, and a binder.

Abstract translation: 描述了制备用于将固体生物质转化为燃料或特种化学产品或用于升级生物油的催化体系和催化体系的方法。 催化剂体系可以包含具有300至约104埃孔径的分级孔结构的沸石基质，诸如MFI型或IM-5沸石的沸石和粘合剂。