Multilayer coating for the interior surface of a can
    41.
    发明授权
    Multilayer coating for the interior surface of a can 失效
    罐的内表面的多层涂层

    公开(公告)号:US5069956A

    公开(公告)日:1991-12-03

    申请号:US530392

    申请日:1990-05-30

    Abstract: A multilayer coating for the interior surface of a can, said coating being composed of(A) a primer coat layer having a dry film thickness of not more than 1 micrometer formed by using a .thermosetting paint consisting of 59 to 98% by weight of a resol-type phenolic resin and 5 to 50% by weight of an epoxy-type resin having compatibility with the phenolic resin as a binder, and(B) an overcoat layer formed by overcoating a thermosetting paint to a dry film thickness of 2 to 20 micrometers, said thermosetting paint being selected from the group consisting of(a) an organic solvent-base thermosetting paint having a binder component composed of 50 to 95% by weight of an aromatic epoxy resin and 5 to 50% by weight of a resol-type phenolic resin,(b) a water-soluble (or water-dispersible) thermosetting paint having a binder component composed of an epoxy-acrylate resin which is a reaction product between a carboxyl-containing acrylic resin and an aromatic epoxy resin, and(c) a water-soluble (or water-dispersible) thermosetting paint resulting from substituting a resol-type phenolic resin for 1 to 50% by weight of the binder component of the paint (b).

    Abstract translation: 一种用于罐内表面的多层涂层,所述涂层由(A)通过使用由59-98%(重量)以下的热固性涂料形成的干膜厚度不大于1微米的底漆涂层组成 酚醛树脂型酚醛树脂和5〜50重量%的与酚醛树脂作为粘合剂相容的环氧树脂类树脂,(B)通过将热固性涂料外涂至干膜厚度为2〜 所述热固性涂料选自(a)具有50至95重量%的芳族环氧树脂和5至50重量%的甲阶酚醛树脂的粘合剂组分的有机溶剂基热固性涂料 型酚醛树脂,(b)具有由含羧基的丙烯酸树脂和芳族环氧树脂之间的反应产物的环氧丙烯酸酯树脂组成的粘合剂组分的水溶性(或水分散性)热固性涂料,以及 (c)水溶性 e(或水分散性)热固性涂料,其取代了甲阶酚醛树脂型酚醛树脂1至50重量%的涂料(b)的粘合剂组分。

    Highly corrosion-resistant, colored thin film-coated steel sheet having
excellent press-processability and spot-weldability
    42.
    发明授权
    Highly corrosion-resistant, colored thin film-coated steel sheet having excellent press-processability and spot-weldability 失效
    高抗腐蚀性,具有优异的压力加工性和点焊性的彩色薄膜涂层钢板

    公开(公告)号:US5059492A

    公开(公告)日:1991-10-22

    申请号:US503979

    申请日:1990-04-04

    Abstract: This invention provides a highly corrosion-resistant, colored thin film-coated steel sheet having excellent press-processability and spot-weldability, which comprises a plated steel sheet, a first layer of a sparingly soluble chromate film formed on surface(s) of the plated steel sheet and having a water soluble content of 1 to 30%, a Cr.sup.6+ /Cr.sup.3+ ratio of 0.01 to 1.0 and a total chromium build-up of 10 to 150 mg/m.sup.2 on one surface, and a second layer of a 0.3 to 5 .mu. thick solid coating film formed of an organic solvent-type coating composition, the solid coating film being comprised, based on the weight of the nonvolatile content, of(a) a urethanated epoxy ester resin having a number average molecular weight of 300 to 100,000: 30 to 90%,(b) a hydrophilic polyamide resin having a polymerization degree of 50 to 1,000: 5 to 40%,(c) a silica powder having an average particle diameter of 1 to 100 .mu.m: 5 to 40%,(d) a lubricant: 1 to 20%, and(e) at least one member selected from a group consisting of inorganic, and insoluble azo-type, azolake-type or phthalocyanine-type organic pigments having an average particle diameter of 0.05 to 5 .mu.m: 0.1 to 20%.

    Abstract translation: 本发明提供一种具有优异的加压加工性和点焊性的高耐腐蚀性有色薄膜包覆钢板,其包括镀覆钢板,在第一表面上形成的可溶性铬酸盐膜的第一层 水溶性含量为1〜30%,Cr6 + / Cr3 +比为0.01〜1.0,总铬浓度为10〜150mg / m 2,第1层为0.3〜 由有机溶剂型涂料组合物形成的5微米厚的固体涂膜,所述固体涂膜基于不挥发物含量的重量包含(a)数均分子量为300至 100,000:30〜90%,(b)聚合度为50〜1000:5〜40%的亲水性聚酰胺树脂,(c)平均粒径为1〜100μm的二氧化硅粉末:5〜40质量% ,(d)润滑剂:1〜20%,(e)选自组c的至少一种 存在平均粒径为0.05〜5μm的无机和不溶性偶氮型,唑酮型或酞菁型有机颜料:0.1〜20%。

    Composite-coated flat-rolled steel can stock and can product
    43.
    发明授权
    Composite-coated flat-rolled steel can stock and can product 失效
    复合涂层平轧钢可以库存和可以生产

    公开(公告)号:US4952461A

    公开(公告)日:1990-08-28

    申请号:US247487

    申请日:1988-09-21

    Abstract: Composite-coated flat-rolled steel can stock processing and product for fabrication of drawn one-piece cup-shaped work product or can end walls. Single or double-reduced flat-rolled steel, after cleaning, is chemically treated to apply a chrome oxide coating of about three hundred (300) to five hundred (500) micrograms per square foot to each substrate surface followed by utilization of a dual-organic coating system with application and curing of an organic primer to each chemically-treated surface of the substrate followed by application and curing of an added organic coating on at least one such substrate surface; such composite-coating process resulting in an exterior surface of a drawn can body or end wall having at least about two and one-half (2.5) to about five (5) milligrams of organic coating per square inch and an interior can surface with organic coating weight of at least about seven and one-half (7.5) to ten (10) milligrams per square inch. In cup forming applications, both such surfaces are lubricated with a suitable lubricant approved for food and beverage usage prior to cupping and any redraw operation.

    Abstract translation: 复合涂层平轧钢可以进行库存加工,制成拉丝单件杯形工件或罐壁端面产品。 化学处理单层或双层扁平轧制钢,以对每个基材表面施加约三百(300)至五百(500)微克/平方英尺的铬氧化物涂层,然后使用双 有机涂层系统,将有机底漆施加和固化到基底的每个化学处理的表面,然后在至少一个这样的基底表面上施加和固化添加的有机涂层; 这种复合涂覆方法产生拉制罐体或端壁的外表面,其具有至少约2.5和5(5)毫克有机涂层/平方英寸的内表面和具有有机物的内部表面 涂层重量至少约七分之一(7.5)至十(10)毫克每平方英寸。 在杯形成应用中,两个这样的表面均被润滑,在拔罐之前和任何重新拉拔操作之前都用适合食品和饮料的润滑剂进行润滑。

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