公开(公告)号：US09427728B2

公开(公告)日：2016-08-30

申请号：US14092829

申请日：2013-11-27

Applicant: The Regents of the University of California

Inventor： Meera A. Sidheswaran ,  Hugo Destaillats ,  William J. Fisk

IPC: B01J23/34 ,  B01J37/03 ,  B01J21/18 ,  B01D53/86 ,  B01J35/00 ,  B01J35/06 ,  B01J35/10 ,  B01J37/02 ,  C09D1/00 ,  A61L9/00 ,  B01J20/20 ,  B01J35/04

CPC classification number: B01J23/34 ,  A61L9/00 ,  B01D53/8668 ,  B01D2253/102 ,  B01D2255/2073 ,  B01D2257/106 ,  B01D2257/708 ,  B01J20/20 ,  B01J21/18 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/04 ,  B01J35/06 ,  B01J35/1009 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0215 ,  B01J37/031 ,  B01J37/08 ,  C09D1/00 ,  C09D7/61 ,  Y02A50/235

Abstract: The present invention provides for a device for reducing a volatile organic compound (VOC) content of a gas comprising a manganese oxide (MnOx) catalyst. The manganese oxide (MnOx) catalyst is capable of catalyzing formaldehyde at room temperature, with complete conversion, to CO2 and water vapor. The manganese oxide (MnOx) catalyst itself is not consumed by the reaction of formaldehyde into CO2 and water vapor. The present invention also provides for a device for reducing or removing a particle, a VOC and/or ozone from a gas comprising an activated carbon filter (ACF) on a media that is capable of being periodically regenerated.

Abstract translation: 本发明提供一种用于还原包含氧化锰（MnO x）催化剂的气体的挥发性有机化合物（VOC）含量的装置。 氧化锰（MnOx）催化剂能够在室温下完全催化甲醛，完全转化为二氧化碳和水蒸气。 氧化锰（MnOx）催化剂本身不会被甲醛与二氧化碳和水蒸气的反应所消耗。 本发明还提供了一种用于在能够周期性再生的介质上从包含活性炭过滤器（ACF）的气体中还原或除去颗粒，VOC和/或臭氧的装置。

公开(公告)号：US09403742B2

公开(公告)日：2016-08-02

申请号：US14310230

申请日：2014-06-20

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Stefano Millefanti ,  Vito Tortelli ,  Giuseppe Marchionni

IPC: C08F12/20 ,  C08F14/24 ,  C08F114/24 ,  C08F214/24 ,  C07C17/23 ,  B01J21/18 ,  B01J23/42 ,  B01J23/44 ,  B01J37/00 ,  B01J37/18

CPC classification number: B01J23/44 ,  B01J21/18 ,  B01J23/42 ,  B01J35/023 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0009 ,  B01J37/18 ,  C07C17/23 ,  C07C21/18

Abstract: A catalytic process for the synthesis of trifluoroethylene from chlorotrifluoroethylene which comprises contacting chlorotrifluoroethylene with hydrogen in the presence of a catalyst consisting of palladium or platinum supported on extruded activated carbon.

公开(公告)号：US09387461B2

公开(公告)日：2016-07-12

申请号：US13996073

申请日：2011-12-22

Applicant: Wei Wu ,  Yunkui Li ,  Jeffery Lachapelle

Inventor： Wei Wu ,  Yunkui Li ,  Jeffery Lachapelle

IPC: B01J23/10 ,  B01J23/63 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J21/06 ,  B01J21/04 ,  B01D53/94 ,  B01J35/02

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/102 ,  B01D2255/1023 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2068 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/908 ,  B01J21/04 ,  B01J21/066 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/009 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0215 ,  B01J37/0221 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J2523/00 ,  Y02A50/2324 ,  Y02T10/22 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/48

Abstract: A new type of catalyst support with oxygen storage capacity (OSC) and methods of making the same are disclosed. The composition ratio is x(Ce1−wZrwO2):yM:zL:(1−x−y−z)Al2O3, where Ce1−wZrwO2 is the oxygen storage composition with stabilizer Zr02, molar ratio (w) in the range of 0 to about 0.8, and a weight ratio (x) of about 0.05 to about 0.8; M is an interactive promoter for oxygen storage capacity with a weight ratio (y) of 0 to about 0.10; and L is a stabilizer for the support Al2O3 with weight ratio (z) of from 0 to about 0.10. In some cases, M or L can act as both OSC promoter and thermal stabilizer. The weight percentage range of ceria-zirconia and other metal and rare earth oxides (x+y+z) is from about 5 to about 80% relative to total oxides. Combining platinum group metals (PGM) and adhesive with the catalyst supports, a new wash coat made therefrom is provided that comprises a mixture of catalyst support materials according to the relationship (a)RE-Ce—ZrO2+(3)CZMLA+(1−a−β)RE-Al2O3, where RE-Ce—ZrO2 is a commercial OSC material of rare earth elements stabilized ceria zirconia having a weight ratio (a) ranging from 0 to about 0.7; CZMLA is the catalyst support material of the present disclosure having a weight ratio (β) ranging from about 0.2 to about 1 such that (α+β)

公开(公告)号：US20160167015A1

公开(公告)日：2016-06-16

申请号：US14966534

申请日：2015-12-11

Applicant: Paul PODSIADLO ,  Jianxin WU ,  Kiara M. BENITEZ ,  Quanchang LI ,  David Charles CALABRO

Inventor： Paul PODSIADLO ,  Jianxin WU ,  Kiara M. BENITEZ ,  Quanchang LI ,  David Charles CALABRO

IPC: B01J20/26 ,  B01J20/32 ,  B01J20/16 ,  B01J20/02 ,  C10G25/00 ,  B01J20/18

CPC classification number: B01J20/262 ,  B01D15/00 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D67/0088 ,  B01D69/10 ,  B01D71/70 ,  B01D2253/20 ,  B01D2253/25 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/40 ,  B01D2257/504 ,  B01D2257/80 ,  B01J20/0229 ,  B01J20/0237 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/103 ,  B01J20/16 ,  B01J20/18 ,  B01J20/22 ,  B01J20/264 ,  B01J20/28011 ,  B01J20/28057 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/28069 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28076 ,  B01J20/28078 ,  B01J20/28083 ,  B01J20/286 ,  B01J20/3042 ,  B01J20/3204 ,  B01J20/3212 ,  B01J20/3236 ,  B01J20/3238 ,  B01J20/3272 ,  B01J23/44 ,  B01J31/0274 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J37/0213 ,  B01J37/0236 ,  B01J2220/86 ,  C01B37/00 ,  C07F7/0807 ,  C07F7/081 ,  C07F7/0818 ,  C08G77/26 ,  C08G77/60 ,  C10G25/003 ,  C10G31/09 ,  C10G35/06 ,  C10G45/00 ,  C10G45/04 ,  C10G45/34 ,  C10G45/44 ,  C10G45/46 ,  C10G45/52 ,  C10G45/60 ,  C10G45/64 ,  C10G47/02 ,  C10G50/00 ,  C10K1/32 ,  C10M101/02 ,  C23C16/56

Abstract: Adsorbent materials including a porous material support and about 0.5 wt. % to about 30 wt. % of a Group 8 metal ion are provide herein. Methods of making the adsorbent material and processes of using the adsorbent material, e.g., for heteroatom species separation, are also provided herein.

Abstract translation: 包括多孔材料载体的吸附材料和约0.5wt。 ％至约30wt。 本文提供了8族金属离子的％。 制备吸附剂材料的方法和使用吸附材料的方法，例如用于杂原子物质分离的方法也在本文中提供。

公开(公告)号：US09352987B2

公开(公告)日：2016-05-31

申请号：US14100854

申请日：2013-12-09

Applicant: REMEDIATION PRODUCTS, INC.

Inventor： Scott Noland ,  Bob Elliott

IPC: B01J20/02 ,  C02F1/58 ,  B01J20/20 ,  B01J20/28 ,  B01J20/32 ,  B01J21/18 ,  B01J23/745 ,  B01J37/08 ,  B09C1/00 ,  B09C1/08 ,  C02F1/70 ,  C02F3/10 ,  C02F3/28 ,  C02F3/34 ,  B01J20/30 ,  C09K17/02 ,  B01J35/10 ,  B01J37/16 ,  C02F1/28 ,  C02F101/10 ,  C02F101/32 ,  C02F101/36 ,  C02F103/06

CPC classification number: C02F1/58 ,  B01J20/02 ,  B01J20/20 ,  B01J20/28057 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  B01J21/18 ,  B01J23/745 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/082 ,  B01J37/088 ,  B01J37/16 ,  B09C1/002 ,  B09C1/08 ,  B09C1/10 ,  B09C2101/00 ,  C02F1/281 ,  C02F1/283 ,  C02F1/288 ,  C02F1/705 ,  C02F3/104 ,  C02F3/2806 ,  C02F3/34 ,  C02F2101/101 ,  C02F2101/32 ,  C02F2101/36 ,  C02F2103/06 ,  C02F2305/06 ,  C09K17/02 ,  Y02E50/343 ,  Y02W10/15 ,  Y10T428/12181

Abstract: The present invention provides a supported reactant for in situ remediation of soil and/or groundwater contaminated with a halogenated hydrocarbon consisting essentially of an adsorbent impregnated with elemental iron, wherein the adsorbent is capable of adsorbing the halogenated hydrocarbon. In one embodiment, the adsorbent is activated carbon.

Abstract translation: 本发明提供了用于原位修复被卤化烃污染的土壤和/或地下水的负载反应物，其基本上由浸渍有元素铁的吸附剂组成，其中吸附剂能够吸附卤代烃。 在一个实施方案中，吸附剂是活性炭。

公开(公告)号：US20150352522A1

公开(公告)日：2015-12-10

申请号：US14763428

申请日：2014-02-21

Applicant: NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD. ,  NIPPON STEEL & SUMITOMO METAL CORPORATION

Inventor： Kazuhiko MIZUUCHI ,  Takumi KOUNO ,  Masakazu KATAYAMA ,  Masakazu HIGUCHI ,  Nobuyuki NISHI ,  Takashi IIJIMA ,  Masataka HIYOSHI ,  Katsumasa MATSUMOTO

IPC: B01J21/18 ,  B01J23/50 ,  B01J37/08 ,  B01J35/10 ,  B01J37/34

CPC classification number: B01J21/18 ,  B01J23/42 ,  B01J23/50 ,  B01J35/0033 ,  B01J35/006 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/343 ,  C01B32/20 ,  H01M4/9083

Abstract: A carbon material for catalyst support use which, when used as a catalyst support, maintains a high porosity while being stable chemically, having electrical conductivity, being excellent in durability, and being excellent in diffusibility of the reaction starting materials and reaction products is provided. It is characterized by comprising dendritic carbon mesoporous structures which have 3D structures of branched carbon-containing rod shapes or carbon-containing ring shapes, having a pore size of 1 to 20 nm and a cumulative pore volume of 0.2 to 1.5 cc/g found by analyzing a nitrogen adsorption isotherm by the Dollimore-Heal method, and having a powder X-ray diffraction spectrum which has a peak corresponding to a 002 diffraction line of graphite between diffraction angles (2θ: degrees) of 20 to 30 degrees and has a peak with a half value width of 0.1 degree to 1.0 degree at 25.5 to 26.5 degrees.

Abstract translation: 用作催化剂载体的碳材料，其用作催化剂载体时，在化学稳定性方面保持高孔隙率，具有导电性，耐久性优异，反应起始原料和反应产物的扩散性优异。 其特征在于包括树枝状碳介孔结构，其具有含有支链碳的棒状或含碳环形的三维结构，其孔径为1〜20nm，累积孔体积为0.2〜1.5cc / g，由 通过Dollimore-Heal方法分析氮吸附等温线，并且具有粉末X射线衍射光谱，该衍射光谱具有对应于衍射角（2θ;度）之间的石墨的002衍射线的峰值为20至30度的峰，并且具有 峰值的半值宽度为0.1度至1.0度，为25.5度至26.5度。

公开(公告)号：US20150291888A1

公开(公告)日：2015-10-15

申请号：US14545773

申请日：2015-06-17

Applicant: Greyrock Energy, Inc.

Inventor： Robert Schuerzle ,  Dennis Schuetzle

IPC: C10G2/00 ,  C10G45/62 ,  C10L1/08 ,  C10G45/00

CPC classification number: C10G2/333 ,  B01J23/8913 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0201 ,  C10G2/32 ,  C10G2/33 ,  C10G2/331 ,  C10G2/332 ,  C10G7/00 ,  C10G45/00 ,  C10G45/02 ,  C10G45/62 ,  C10G2300/1022 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2400/04 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2290/42 ,  C10L2290/543

Abstract: A unique process and catalyst is described that operates efficiently for the direct production of a high cetane diesel type fuel or diesel type blending stock from stochiometric mixtures of hydrogen and carbon monoxide. This invention allows for, but is not limited to, the economical and efficient production high quality diesel type fuels from small or distributed fuel production plants that have an annual production capacity of less than 10,000 barrels of product per day, by eliminating traditional wax upgrading processes. This catalytic process is ideal for distributed diesel fuel production plants such as gas to liquids production and other applications that require optimized economics based on supporting distributed feedstock resources.

Abstract translation: 描述了一种独特的方法和催化剂，其有效地用于从氢和一氧化碳的化学计量混合物直接生产高十六烷值柴油型燃料或柴油型混合原料。 本发明允许但不限于，通过消除传统的蜡升级过程，经济有效地生产来自小型或分布式燃料生产设备的高品质柴油型燃料，其年产量可以低于10,000桶产品 。 该催化过程对于分布式柴油燃料生产设备（如天然气和液体生产）以及其他需要基于支持分布的原料资源优化经济性的应用而言非常理想。

公开(公告)号：US09144785B2

公开(公告)日：2015-09-29

申请号：US13498285

申请日：2010-08-05

Applicant: Atsushi Fukuoka ,  Hirokazu Kobayashi ,  Tasuku Komanoya ,  Tadashi Yoneda ,  Ichiro Fujita

Inventor： Atsushi Fukuoka ,  Hirokazu Kobayashi ,  Tasuku Komanoya ,  Tadashi Yoneda ,  Ichiro Fujita

IPC: B01J31/02 ,  C13K1/02 ,  B01J21/18 ,  B01J23/40 ,  B01J23/46 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  B01J21/06 ,  B01J29/03 ,  B01J29/04

CPC classification number: B01J21/18 ,  A23V2002/00 ,  B01J21/063 ,  B01J21/066 ,  B01J23/40 ,  B01J23/462 ,  B01J29/0325 ,  B01J29/043 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/084 ,  C13K1/02 ,  A23V2250/5108

Abstract: Disclosed are: a novel catalyst for the hydrolysis of cellulose, which does not require the use of a large quantity of sulfuric acid for the preparation thereof and from which sulfuric acid cannot be eluted; a novel catalyst for the hydrolysis of cellulose, which is not changed in structure even in hot water and therefore does not undergo the deterioration in activity; and a process for producing a cellulose hydrolysate, mainly including glucose, using any one of the aforementioned catalysts. Specifically disclosed are: a catalyst for the hydrolysis of cellulose, which comprises a porous carbon material having a specific surface area of 800 to 2500 m2/g inclusive and a phenolic hydroxy group content of 100 to 700 mmol/kg inclusive, such as a porous carbon material having such a structure that carbon is filled in pores of mesoporous silica that is used as a template; and a catalyst for the hydrolysis of cellulose or hemicellulose, which comprises the aforementioned porous carbon material and a transition metal belonging to Group 8 to Group 11 and supported on the porous carbon material.

Abstract translation: 公开了一种用于纤维素水解的新型催化剂，其不需要使用大量的硫酸来制备，硫酸不能被洗脱; 用于水解纤维素的新型催化剂，即使在热水中结构也不改变，因此不会发生活性降低; 以及使用上述任一种催化剂生产主要包括葡萄糖的纤维素水解产物的方法。 具体公开的是：纤维素水解用催化剂，其含有比表面积为800〜2500m2 / g，含有酚类羟基含量为100〜700mmol / kg的多孔碳材料，例如多孔碳 具有碳被填充在作为模板的介孔二氧化硅的孔中的结构的碳材料; 以及用于水解纤维素或半纤维素的催化剂，其包含上述多孔碳材料和属于第8族至第11族的过渡金属并负载在多孔碳材料上。

公开(公告)号：US09120081B2

公开(公告)日：2015-09-01

申请号：US14190989

申请日：2014-02-26

Applicant: Monsanto Technology LLC

Inventor： Fuchen Liu ,  Juan Arhancet ,  James P. Coleman ,  Martin P. McGrath

IPC: B01J27/22 ,  B01J27/24 ,  B01J21/18 ,  B01J35/02 ,  B01J35/10 ,  B01J37/08 ,  B82Y30/00 ,  C07C209/68 ,  C07C249/02 ,  C07F9/38 ,  B01J23/40 ,  B01J23/72

CPC classification number: B01J27/24 ,  B01J21/18 ,  B01J23/40 ,  B01J23/72 ,  B01J27/22 ,  B01J35/023 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/084 ,  B82Y30/00 ,  C07C209/68 ,  C07C249/02 ,  C07F9/3813 ,  Y02P20/582 ,  C07C251/06

Abstract: This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation and dehydrogenation reactions, including the preparation of secondary amines by the catalytic oxidation of tertiary amines and the preparation of carboxylic acids by the catalytic dehydrogenation of alcohols.

Abstract translation: 本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。 本发明还涉及催化氧化和脱氢反应的领域，包括通过叔胺的催化氧化制备仲胺和通过醇的催化脱氢制备羧酸。

公开(公告)号：US09090831B2

公开(公告)日：2015-07-28

申请号：US13999471

申请日：2014-02-27

Applicant: Greyrock Energy, Inc.

Inventor： Robert Schuetzle ,  Dennis Schuetzle

IPC: C07C27/06 ,  C10G2/00 ,  C10G45/02 ,  C10G45/62 ,  B01J23/89 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02

CPC classification number: C10G2/333 ,  B01J23/8913 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0201 ,  C10G2/32 ,  C10G2/33 ,  C10G2/331 ,  C10G2/332 ,  C10G7/00 ,  C10G45/00 ,  C10G45/02 ,  C10G45/62 ,  C10G2300/1022 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2400/04 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2290/42 ,  C10L2290/543

Abstract: A unique process and catalyst is described that operates efficiently for the direct production of a high cetane diesel type fuel or diesel type blending stock from stoichiometric mixtures of hydrogen and carbon monoxide. This invention allows for, but is not limited to, the economical and efficient production high quality diesel type fuels from small or distributed fuel production plants that have an annual production capacity of less than 10,000 barrels of product per day, by eliminating traditional wax upgrading processes. This catalytic process is ideal for distributed diesel fuel production plants such as gas to liquids production and other applications that require optimized economics based on supporting distributed feedstock resources.

Abstract translation: 描述了独特的方法和催化剂，其有效地用于从氢和一氧化碳的化学计量混合物直接生产高十六烷值柴油型燃料或柴油型混合原料。 本发明允许但不限于，通过消除传统的蜡升级过程，经济有效地生产来自小型或分布式燃料生产设备的高品质柴油型燃料，其年产量可以低于10,000桶产品 。 该催化过程对于分布式柴油燃料生产设备（如天然气和液体生产）以及其他需要基于支持分布的原料资源优化经济性的应用而言非常理想。