公开(公告)号：US09254506B2

公开(公告)日：2016-02-09

申请号：US12829535

申请日：2010-07-02

Applicant: Mark A. Roehrig ,  Alan K. Nachtigal ,  Mark D. Weigel

Inventor： Mark A. Roehrig ,  Alan K. Nachtigal ,  Mark D. Weigel

IPC: B05D7/04 ,  B05D1/00 ,  B05D3/06 ,  C23C14/08 ,  C23C14/34 ,  C08J7/04 ,  B05D7/00 ,  H01L51/52

CPC classification number: C23C14/081 ,  B05D1/60 ,  B05D3/068 ,  B05D7/04 ,  B05D7/586 ,  B05D2252/02 ,  C08J7/045 ,  C23C14/08 ,  C23C14/10 ,  C23C14/12 ,  C23C14/24 ,  C23C14/34 ,  C23C14/54 ,  H01L51/5256 ,  Y10T428/31663

Abstract: A barrier film having a substrate, a base polymer layer applied to the substrate, an oxide layer applied to the base polymer layer, and a top coat polymer layer applied to the oxide layer. An optional inorganic layer can be applied over the top coat polymer layer. The top coat polymer includes a silane and an acrylate co-deposited to form the top coat layer. The use of a silane co-deposited with an acrylate to form the top coat layer of the barrier films provide for enhanced resistance to moisture and improved peel strength adhesion of the top coat layer to the underlying barrier stack layers.

Abstract translation: 具有基板，施加到基板的基底聚合物层，施加到基础聚合物层的氧化物层和施加到氧化物层的顶涂层聚合物层的阻挡膜。 可以在顶涂层聚合物层上施加任选的无机层。 面漆聚合物包括共沉积以形成顶涂层的硅烷和丙烯酸酯。 与丙烯酸酯共沉积形成阻挡膜的顶涂层的硅烷的使用提供了增强的耐湿性和提高的顶涂层与下层阻挡层叠层的剥离强度粘附性。

公开(公告)号：US20150114457A1

公开(公告)日：2015-04-30

申请号：US14381761

申请日：2012-08-01

Applicant: Mark D. Weigel ,  Michael D. Delmore ,  Dennis M. Brunner ,  Andrew T. Ruff

Inventor： Mark D. Weigel ,  Michael D. Delmore ,  Dennis M. Brunner ,  Andrew T. Ruff

IPC: H01L31/048 ,  B32B37/22

CPC classification number: H01L31/048 ,  B32B7/12 ,  B32B15/04 ,  B32B15/20 ,  B32B27/08 ,  B32B27/281 ,  B32B27/285 ,  B32B27/286 ,  B32B27/288 ,  B32B27/304 ,  B32B27/32 ,  B32B27/36 ,  B32B27/365 ,  B32B37/223 ,  B32B37/226 ,  B32B2250/44 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2307/41 ,  B32B2307/54 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2307/7265 ,  B32B2327/12 ,  B32B2457/00 ,  B32B2457/12 ,  Y02E10/50 ,  Y10T156/1095 ,  Y10T156/1097

Abstract: This disclosure generally relates to films capable of use in a flexible photovoltaic solar module, rolls of films capable of use in a flexible photovoltaic solar module, processes of making the films and rolls of films, to flexible photovoltaic solar modules including such films, and to methods of making flexible solar modules. One exemplary process involves providing at least two discrete segments of a multilayer barrier film and placing a segment of protective layer adjacent to two of the adjacent discrete segments of multilayer barrier film such that the first and second terminal edges of the segment of protective layer span the gap between the discrete segments of barrier film to form a continuous film.

Abstract translation: 本公开一般涉及能够用于柔性光伏太阳能模块的膜，能够在柔性光伏太阳能电池组件中使用的膜卷，制造薄膜和薄膜的工艺，包括这种膜的柔性光伏太阳能模块，以及 制造柔性太阳能电池组件的方法。 一个示例性方法包括提供多层阻挡膜的至少两个离散段并且将保护层的一段与多层阻挡膜的相邻离散区段中的两个相邻，使得保护层段的第一和第二末端边缘跨越 阻隔膜的离散段之间的间隙形成连续膜。

公开(公告)号：US20120003448A1

公开(公告)日：2012-01-05

申请号：US13175598

申请日：2011-07-01

Applicant: Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal ,  Samuel Kidane ,  Andrew J. Henderson

Inventor： Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal ,  Samuel Kidane ,  Andrew J. Henderson

IPC: B32B7/02

CPC classification number: H01L31/0481 ,  B32B7/02 ,  B32B7/12 ,  B32B17/10018 ,  B32B27/08 ,  B32B27/281 ,  B32B27/283 ,  B32B27/286 ,  B32B27/302 ,  B32B27/304 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2307/412 ,  B32B2307/416 ,  B32B2307/42 ,  B32B2307/546 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2307/732 ,  B32B2327/12 ,  B32B2367/00 ,  B32B2457/12 ,  B32B2551/00 ,  Y02E10/50 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/31663 ,  Y10T428/31667

Abstract: An assembly that includes a barrier film interposed between a first polymeric film substrate and a first major surface of a pressure sensitive adhesive layer is provided. The first polymeric film substrate has a first coefficient of thermal expansion that is, in some embodiments, up to 50 parts per million per Kelvin. The pressure sensitive adhesive layer has a second major surface opposite the first major surface that is disposed on a second polymeric film substrate. The second polymeric film substrate is typically resistant to degradation by ultraviolet light. In some embodiments, the second polymeric film substrate has a second coefficient of thermal expansion that is at least 40 parts per million per Kelvin higher than the first coefficient of thermal expansion. The assembly is transmissive to visible and infrared light.

Abstract translation: 提供了一种包括介于第一聚合物膜基材和压敏粘合剂层的第一主表面之间的阻挡膜的组合件。 第一聚合物膜基材具有第一热膨胀系数，在一些实施方案中为高达每百万开氏百万分之50。 压敏粘合剂层具有与设置在第二聚合物膜基材上的第一主表面相对的第二主表面。 第二聚合物膜基底通常耐紫外线降解。 在一些实施方案中，第二聚合物膜基材具有比第一热膨胀系数高至少40ppm /开氏度的第二热膨胀系数。 组件对可见光和红外光透射。

公开(公告)号：US5322731A

公开(公告)日：1994-06-21

申请号：US028338

申请日：1993-03-09

Applicant: Joseph P. Callahan, Jr. ,  Rudyard M. Enanoza ,  Mark D. Weigel

Inventor： Joseph P. Callahan, Jr. ,  Rudyard M. Enanoza ,  Mark D. Weigel

IPC: C08F291/00 ,  C08J3/12 ,  C08J3/16 ,  C09J7/02 ,  C09J151/00 ,  B32B9/00

CPC classification number: C09J151/00 ,  C08F291/00 ,  C08J3/124 ,  C09J7/0207 ,  Y10T428/24826 ,  Y10T428/254 ,  Y10T428/2998

Abstract: Adhesive beads comprise a core comprising a pressure sensitive adhesive material and an essentially discontinuous organic polymer disposed about the core. The beads are free-flowing at room temperature. Upon application of heat and/or pressure the core is activated and blends with the coating to provide a pressure sensitive adhesive.

Abstract translation: 粘合珠粒包括芯，其包含压敏粘合剂材料和围绕芯部布置的基本上不连续的有机聚合物。 珠在室温下自由流动。 在施加热和/或压力时，芯被激活并与涂层混合以提供压敏粘合剂。

公开(公告)号：US10038111B2

公开(公告)日：2018-07-31

申请号：US13175598

申请日：2011-07-01

Applicant: Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal ,  Samuel Kidane ,  Andrew J. Henderson

Inventor： Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal ,  Samuel Kidane ,  Andrew J. Henderson

IPC: B32B7/02 ,  H01L31/048 ,  B32B17/10 ,  B32B27/08 ,  B32B27/30 ,  B32B27/36 ,  B32B7/12 ,  B32B27/28 ,  B32B27/32 ,  B32B27/34

CPC classification number: H01L31/0481 ,  B32B7/02 ,  B32B7/12 ,  B32B17/10018 ,  B32B27/08 ,  B32B27/281 ,  B32B27/283 ,  B32B27/286 ,  B32B27/302 ,  B32B27/304 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2307/412 ,  B32B2307/416 ,  B32B2307/42 ,  B32B2307/546 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2307/732 ,  B32B2327/12 ,  B32B2367/00 ,  B32B2457/12 ,  B32B2551/00 ,  Y02E10/50 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/31663 ,  Y10T428/31667

Abstract: An assembly that includes a barrier film interposed between a first polymeric film substrate and a first major surface of a pressure sensitive adhesive layer is provided. The first polymeric film substrate has a first coefficient of thermal expansion that is, in some embodiments, up to 50 parts per million per Kelvin. The pressure sensitive adhesive layer has a second major surface opposite the first major surface that is disposed on a second polymeric film substrate. The second polymeric film substrate is typically resistant to degradation by ultraviolet light. In some embodiments, the second polymeric film substrate has a second coefficient of thermal expansion that is at least 40 parts per million per Kelvin higher than the first coefficient of thermal expansion. The assembly is transmissive to visible and infrared light.

公开(公告)号：US20140290736A1

公开(公告)日：2014-10-02

申请号：US14236697

申请日：2012-07-24

Applicant: Mark D. Weigel ,  Mark A. Roehrig ,  Michael D. Delmore ,  Andrew T. Ruff

Inventor： Mark D. Weigel ,  Mark A. Roehrig ,  Michael D. Delmore ,  Andrew T. Ruff

IPC: H01L31/048

CPC classification number: H01L31/048 ,  H01L31/0481 ,  Y02E10/50

Abstract: The present application is directed to an assembly comprising an electronic device and a multilayer film. The multilayer film comprises a barrier stack adjacent the electronic device, and a weatherable sheet adjacent the barrier stack opposite the electronic device. The weatherable sheet is bonded to the electronic device.

Abstract translation: 本申请涉及一种包括电子器件和多层膜的组件。 多层膜包括邻近电子器件的阻挡层叠层，以及与电子器件相对的阻挡层叠层的耐候性片。 耐候片粘合到电子装置上。

公开(公告)号：US08628859B2

公开(公告)日：2014-01-14

申请号：US13453569

申请日：2012-04-23

Applicant: Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal

Inventor： Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal

IPC: B32B27/06 ,  B05D1/36

CPC classification number: H01L31/0481 ,  B32B7/02 ,  B32B7/12 ,  B32B17/10018 ,  B32B27/08 ,  B32B27/281 ,  B32B27/283 ,  B32B27/286 ,  B32B27/302 ,  B32B27/304 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2307/412 ,  B32B2307/416 ,  B32B2307/42 ,  B32B2307/546 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2307/732 ,  B32B2327/12 ,  B32B2367/00 ,  B32B2457/12 ,  B32B2551/00 ,  Y02E10/50 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/31663 ,  Y10T428/31667

Abstract: A barrier film is disclosed that includes a polymeric film substrate and at least first and second polymer layers separated by an inorganic barrier layer. The first polymer layer is disposed on the polymeric film substrate. At least one of the first or second polymer layers is prepared from co-deposited amino silane and acrylate or methacrylate monomer. A method of making the barrier film is also disclosed.

Abstract translation: 公开了一种阻挡膜，其包括聚合物膜基材和由无机阻挡层分开的至少第一和第二聚合物层。 第一聚合物层设置在聚合物膜基材上。 第一或第二聚合物层中的至少一个由共沉积的氨基硅烷和丙烯酸酯或甲基丙烯酸酯单体制备。 还公开了制造阻挡膜的方法。

公开(公告)号：US20120229893A1

公开(公告)日：2012-09-13

申请号：US13509851

申请日：2010-11-11

Applicant: Timothy J. Hebrink ,  Mark A. Roehrig ,  Mark D. Weigel

Inventor： Timothy J. Hebrink ,  Mark A. Roehrig ,  Mark D. Weigel

IPC: G02B5/26

CPC classification number: G02B5/208 ,  G02B1/04 ,  G02B1/105 ,  G02B1/14 ,  G02B5/0841 ,  G02B5/0891 ,  G02B5/283 ,  G02B5/287 ,  C08L67/00 ,  C08L33/08 ,  C08L33/12

Abstract: Multi-layer optical film (10) comprising optical layers reflecting at least 50 percent of incident UV light over specified wavelength ranges. Embodiments of the multi-layer optical films are useful, for example, as a UV protective covering.

Abstract translation: 多层光学膜（10）包括在特定波长范围内反射入射的UV光的至少50％的光学层。 多层光学膜的实施例可用作例如UV保护层。

公开(公告)号：US20120208033A1

公开(公告)日：2012-08-16

申请号：US13453569

申请日：2012-04-23

Applicant: Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal

Inventor： Mark D. Weigel ,  Mark A. Roehrig ,  Alan K. Nachtigal

IPC: B32B27/06 ,  B05D3/02

CPC classification number: H01L31/0481 ,  B32B7/02 ,  B32B7/12 ,  B32B17/10018 ,  B32B27/08 ,  B32B27/281 ,  B32B27/283 ,  B32B27/286 ,  B32B27/302 ,  B32B27/304 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2255/10 ,  B32B2255/20 ,  B32B2307/412 ,  B32B2307/416 ,  B32B2307/42 ,  B32B2307/546 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2307/732 ,  B32B2327/12 ,  B32B2367/00 ,  B32B2457/12 ,  B32B2551/00 ,  Y02E10/50 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/31663 ,  Y10T428/31667

Abstract: A barrier film is disclosed that includes a polymeric film substrate and at least first and second polymer layers separated by an inorganic barrier layer. The first polymer layer is disposed on the polymeric film substrate. At least one of the first or second polymer layers is prepared from co-deposited amino silane and acrylate or methacrylate monomer. A method of making the barrier film is also disclosed.

Abstract translation: 公开了一种阻挡膜，其包括聚合物膜基材和由无机阻挡层分开的至少第一和第二聚合物层。 第一聚合物层设置在聚合物膜基材上。 第一或第二聚合物层中的至少一个由共沉积的氨基硅烷和丙烯酸酯或甲基丙烯酸酯单体制备。 还公开了制造阻挡膜的方法。

公开(公告)号：US20120003484A1

公开(公告)日：2012-01-05

申请号：US12829535

申请日：2010-07-02

Applicant: Mark A. Roehrig ,  Alan K. Nachtigal ,  Mark D. Weigel

Inventor： Mark A. Roehrig ,  Alan K. Nachtigal ,  Mark D. Weigel

IPC: B32B27/06 ,  C23C16/00 ,  C23C14/34 ,  B05D5/00 ,  B32B27/30 ,  C23C14/08

CPC classification number: C23C14/081 ,  B05D1/60 ,  B05D3/068 ,  B05D7/04 ,  B05D7/586 ,  B05D2252/02 ,  C08J7/045 ,  C23C14/08 ,  C23C14/10 ,  C23C14/12 ,  C23C14/24 ,  C23C14/34 ,  C23C14/54 ,  H01L51/5256 ,  Y10T428/31663

Abstract: A barrier film having a substrate, a base polymer layer applied to the substrate, an oxide layer applied to the base polymer layer, and a top coat polymer layer applied to the oxide layer. An optional inorganic layer can be applied over the top coat polymer layer. The top coat polymer includes a silane and an acrylate co-deposited to form the top coat layer. The use of a silane co-deposited with an acrylate to form the top coat layer of the barrier films provide for enhanced resistance to moisture and improved peel strength adhesion of the top coat layer to the underlying barrier stack layers.

Abstract translation: 具有基板，施加到基板的基底聚合物层，施加到基础聚合物层的氧化物层和施加到氧化物层的顶涂层聚合物层的阻挡膜。 可以在顶涂层聚合物层上施加任选的无机层。 面漆聚合物包括共沉积以形成顶涂层的硅烷和丙烯酸酯。 与丙烯酸酯共沉积形成阻挡膜的顶涂层的硅烷的使用提供了增强的耐湿性和提高的顶涂层与下层阻挡层叠层的剥离强度粘附性。