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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    2.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开

    公开(公告)号：WO2021001232A1

    公开(公告)日：2021-01-07

    申请号：PCT/EP2020/067640

    申请日：2020-06-24

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F4/651 ,  C08F110/06 ,  C08F4/654

    Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where the R 1 and R 5 groups, equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups, R 2 group is selected from C 2 -C 10 hydrocarbon groups, R 3 to R 4 groups, independently, are selected from hydrogen or C 1 -C 20 hydrocarbon groups, optionally fused together to form one or more cycles, with the proviso that at least one of R 3 to R 4 groups is a C 1 -C 20 alkyl group. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    3.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：WO2018060116A1

    公开(公告)日：2018-04-05

    申请号：PCT/EP2017/074180

    申请日：2017-09-25

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GUIDOTTI, Simona ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F210/16 ,  C08F4/651 ,  C08F4/656 ,  C08F4/658

    CPC classification number: C08F10/02 ,  C08F210/16 ,  C08F2410/01 ,  C08F210/08 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6494 ,  C08F4/6567

    Abstract: A process for the preparation of a solid catalyst component for the homo or copolymerization of olefins which comprises Mg, Ti, halogen and an electron donor selected from cycloalkyl ethers, said process comprising (a) dissolving a Mg based compound and a TiCI 3 based compound in a liquid medium further comprising a cycloalkyl ether and a compound of formula R 2 OH where R 2 is a C 1 -C 20 hydrocarbon group, in which the Ti/Mg molar ratio ranges from 0.1 to 0.5, the cycloalkyl ether/Mg ratio ranges from 1 to 4 and the R 2 OH/Mg molar ratio ranges from 1 to 4; and (b) adding, to the solution coming from step (a), SiCI4 in an amount such that the R 2 OH/SiCI4 molar ratio ranges from 0.5 to 1.5 and maintaining the temperature in the range 50-150°C thereby allowing precipitation of the solid catalyst component particles.

    Abstract translation: 一种制备用于烯烃均聚或共聚的固体催化剂组分的方法，该组分包含Mg，Ti，卤素和选自环烷基醚的电子供体，所述方法包括：（a）将Mg 在液体介质中进一步包含环烷基醚和式R 2 OH的化合物，其中R 2是（CH 3）2基团的化合物和基于TiCl 3的化合物 C 1 -C 20烃基，其中Ti / Mg摩尔比范围为0.1至0.5，环烷基醚/ Mg比率范围为1至4，且 R 2 OH / Mg摩尔比范围为1至4; 和（b）向来自步骤（a）的溶液中加入一定量的SiCl 4，使R 2 / OH / SiCl 4摩尔比为0.5-1.5，并保持温度在50℃ -150℃，从而使固体催化剂组分颗粒沉淀。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    4.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：WO2017186623A1

    公开(公告)日：2017-11-02

    申请号：PCT/EP2017/059619

    申请日：2017-04-24

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GUIDOTTI, Simona ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F10/02 ,  C08F4/654 ,  C08F4/651

    Abstract: A solid catalyst component obtainable by a process comprising: (a) a first step in which a titanium compound of formula Ti(OEt) 4 , is reacted with a Mg based compound at a Ti/Mg molar ratio between 0.2 and 0.4, at a reaction temperature between 110 and 130°C during 2 to 5 hours; and (b) a subsequent step in which the product obtained in (a) is reacted with a Ti compound formula Ti(OR I ) 4-y Cl y , where y is a number between 3 and 4.

    Abstract translation: （a）第一步，其中使式Ti（OEt）4的钛化合物与基于Mg Ti / Mg摩尔比为0.2-0.4的化合物，反应温度为110-130℃，时间为2-5小时; 和（b）随后的步骤，其中使（a）中获得的产物与Ti化合物式Ti（OR 1）4-yCl y ，其中y是3到4之间的数字。

    CATALYST FOR THE POLYMERIZATION OF OLEFINS
    7.
    发明申请
    CATALYST FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    烯烃聚合催化剂

    公开(公告)号：WO2018011086A1

    公开(公告)日：2018-01-18

    申请号：PCT/EP2017/067130

    申请日：2017-07-07

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： DALL'OCCO, Tiziano ,  GUIDOTTI, Simona ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F210/16 ,  C08F4/651

    Abstract: A catalyst component for the (co)polymerization of olefins, comprising Ti, Mg, halogen, an electron donor (ID) selected from aliphatic cyclic ethers or alkyl esters of aliphatic monocarboxylic acids and a compound of a metal selected from Zn or Cu which is devoid of Zn-C or Cu-C bonds in which the Mg/Ti molar ratio ranges from 4.0 to 50.0 is capable to produce LLDPE with excellent quality due to capability of comonomer randomization.

    Abstract translation: 用于烯烃（共）聚合的催化剂组分包括Ti，Mg，卤素，选自脂肪族环状醚或脂肪族一元羧酸的烷基酯的电子供体（ID）和 选自无Zn-C或Cu-C键的Zn或Cu中的Mg / Ti摩尔比范围为4.0-50.0的金属由于共聚单体随机化的能力而能够生产具有优良品质的LLDPE。

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