Phenylacetic acid derivatives, process for their preparation and their use as pesticides and fungicides

    公开(公告)号:NZ320139A

    公开(公告)日:2000-05-26

    申请号:NZ32013996

    申请日:1996-09-30

    Applicant: BASF AG

    Abstract: The invention concerns phenylacetic acid derivatives of the above formula in which the substituents and the indices have the following meanings: X denotes NOCH3, CHOCH3 and CHCH3; Y denotes oxygen or NRa; Ra denotes hydrogen or alkyl R denotes cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m stands for 0, 1 or 2, wherein the radicals R can be different if m is 2; R1 denotes hydrogen or alkyl; R2 and R3, independently of each other, denote hydrogen, cyano, nitro, hydroxy, amino, halogen, optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkynyl, alkynyloxy, alkynylthio, alkynylamino, N-alkynyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino and N-hetaryl-N-alkylamino; R4 denotes one of the groups mentioned in the case of R2 or a CRd=NORe group; Rd denotes one of the groups mentioned in the case of R2; and Re denotes hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl, alkylsulphonyl, aryl, arylcarbonyl, arylsulphonyl, hetaryl, hetarylcarbonyl or hetarylsulphonyl. The invention also concerns their salts, a process for the preparation of these substances and their use.

    METHOD FOR PRODUCING 1-SUBSTITUTED 5-HYDROXYPYRAZOLES

    公开(公告)号:CA2349244A1

    公开(公告)日:2000-05-18

    申请号:CA2349244

    申请日:1999-10-30

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing substituted hydroxypyrazoles and new intermediate products. It relates in particular to a method for producing compounds of formula (I) in which R1 is hydrogen, an aliphatic gro up with between 1 and 8 carbon atoms, C1-C6-alkoxycarbonyl, C1-C6-alkyl thiocarbonyl or a cyclic ring system with between 3 and 14 ring atoms; R2 is hydrogen, an aliphatic group with between 1 and 8 carbon atoms; or R1 and R2 together with the carbon atom to which they are bound are a cyclic or bicycl ic ring system with between 3 and 14 ring atoms. Said method comprises the production, as starting or intermediate products, of compounds of formula (I I) in which R3 and R4 are readily cleavable groups and R1 and R2 have the meanings given above. Said compounds are cyclized under suitable reaction conditions to yield compounds of formula (I).

    99.
    发明专利
    未知

    公开(公告)号:ES2137510T3

    公开(公告)日:1999-12-16

    申请号:ES95917966

    申请日:1995-04-26

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/01581 Sec. 371 Date Nov. 4, 1996 Sec. 102(e) Date Nov. 4, 1996 PCT Filed Apr. 26, 1995 PCT Pub. No. WO95/30648 PCT Pub. Date Nov. 16, 1995Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib (Ia): H2NOCH2CH(R1)OAr (Ib): H2NOCH(R1)CH2OAr and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb (IIa): (III): into a mixture of sulfonates IVa and IVb (IVa): (IVb): b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb (VIa): (VIb): c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.

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