СПОСОБ ПОЛУЧЕНИЯ БУТАДИЕНА ИЗ Н-БУТАНА

    公开(公告)号:EA007394B1

    公开(公告)日:2006-10-27

    申请号:EA200500176

    申请日:2003-07-10

    Applicant: BASF AG

    Abstract: Изобретениеотноситсяк способуполучениябутадиенаизн-бутана, включающемуследующиестадии: (A) подготовкасодержащегон-бутанисходногогазовогопотока, (B) загрузкасодержащегон-бутанисходногогазовогопотокав первуюзонудегидрированияи неокислительноекаталитическоедегидрированиен-бутанав 1-бутен, 2-бутени, вслучаенеобходимости, бутадиен, причемполучаютпервыйгазовыйпотокпродукта, содержащийн-бутан, 1-бутен, 2-бутен, вслучаенеобходимости, бутадиени, вслучаенеобходимости, побочныекомпоненты, (C) загрузкасодержащегон-бутан, 1-бутен, 2-бутен, вслучаенеобходимости, бутадиени, вслучаенеобходимости, побочныекомпонентыпервогогазовогопотокапродуктавовторуюзонудегидрированияи окислительноедегидрирование 1-бутенаи 2-бутенав бутадиен, причемполучаютсодержащийбутадиен, н-бутан, водянойпари, вслучаенеобходимости, побочныекомпонентывторогогазовогопотокапродукта, (D) получениебутадиенаизвторогогазовогопотокапродукта.

    119.
    发明专利
    未知

    公开(公告)号:AT291017T

    公开(公告)日:2005-04-15

    申请号:AT02754895

    申请日:2002-07-17

    Applicant: BASF AG

    Abstract: A process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of an n-butene-containing hydrocarbon stream by means of oxygen-containing gases in a shell-and-tube reactor having two successive reaction zones, where the first, feed-side reaction zone contains at least one catalyst which is suitable for the oxydehydrogenation of n-butenes to 1,3-butadiene and the second, product-side reaction zone contains at least one catalyst which is suitable for the oxidation of 1,3-butadiene to maleic anhydride, is carried out using a shell-and-tube reactor which has at least one heat transfer medium circuit in the region of the first, feed-side reaction zone and at least one further heat transfer medium circuit in the region of the second, product-side reaction zone.

    120.
    发明专利
    未知

    公开(公告)号:NO20043872L

    公开(公告)日:2004-09-15

    申请号:NO20043872

    申请日:2004-09-15

    Applicant: BASF AG

    Abstract: The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.

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