公开(公告)号：DE10033697A1

公开(公告)日：2002-01-24

申请号：DE10033697

申请日：2000-07-12

Applicant: BASF AG

Inventor： VOELLINGER FRANK ,  MEISENBURG UWE ,  BECK ERICH ,  SCHWALM REINHOLD

IPC: C08G18/80 ,  C09D175/16 ,  C09D5/02 ,  C08G18/72 ,  C08J3/28 ,  C08L75/14 ,  C09D175/14

Abstract: UV- and heat-curable aqueous polyurethane dispersion based on aliphatic polyisocyanates and low-mol. wt. aliphatic compounds with at least 2 hydroxyl, mercapto or amino groups also contains compounds with NCO-reactive groups and UV-polymerizable double bonds, carboxylic or sulfonic acids with NCO-reactive groups and an isocyanate blocking agent. UV- and heat-curable aqueous polyurethane dispersions (PD), essentially comprising: (a) aliphatic polyisocyanates with an NCO functionality of 2-4.5, (b) compounds with isocyanate-reactive group(s) and C=C double bond(s) which can be polymerized with UV in presence of a photoinitiator, (c) aliphatic compounds with a mol. wt. of less than 500 and at least 2 isocyanate-reactive hydroxyl, mercapto or prim. and/or sec. amino groups, (d) compounds with isocyanate-reactive group(s) and carboxylic or sulfonic acid group(s), (e) a basic compound for at least partial neutralization of the acid groups in (d), (f) an isocyanate blocking agent (f1) with a deblocking temperature of 70-160 deg C or an added low-mol. wt. compound (f2) with blocked isocyanate groups, and (g) optionally compounds other than (b-f) with only one isocyanate-reactive group. Dispersions (PD) are obtained by reacting (a) with (b) and (c) using a stoichiometric excess of NCO groups over OH groups and with sufficient (d) and (e) for good dispersibility in aqueous media, and then introducing blocked isocyanate groups by reaction with (f1) or by addition of (f2) containing (b) as additive.

公开(公告)号：DE10031258A1

公开(公告)日：2002-01-10

申请号：DE10031258

申请日：2000-06-27

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  BRUCHMANN BERND ,  VOELLINGER FRANK ,  BECK ERICH ,  SCHROF WOLFGANG ,  MEISENBURG UWE

IPC: C08K3/18 ,  C08G18/67 ,  C08G18/78 ,  C08G18/81 ,  C08K5/00 ,  C08L75/04 ,  C09D5/00 ,  C09D5/02 ,  C09D5/46 ,  C09D175/14 ,  C09D175/16 ,  C08G18/72

Abstract: The invention relates to a curable aqueous polyurethane dispersion that substantially consists of a) at least one compound that has two free isocyanate groups, at least one allophanate group and at least one radically polymerizable C=C double bond, a carbonyl group or an oxygen atom in ether function being directly bound to the double bond, b) at least one compound that has at least one isocyanate reactive group and one radically polymerizable C=C double bond, c) optionally at least one compound that has at least one isocyanate reactive group and at least one acidic group, e) at least one alkaline compound that neutralizes or partially neutralizes the acidic groups of compound d), and a thermal initiator. The invention also relates to the use of these dispersions for coating substrates.

公开(公告)号：DE19949383A1

公开(公告)日：2001-04-19

申请号：DE19949383

申请日：1999-10-13

Applicant: BASF AG

Inventor： MEIER ANTJE ,  KRANIG WOLFGANG ,  BECK ERICH ,  REICH WOLFGANG ,  PAULUS WOLFGANG ,  SCHROF WOLFGANG

IPC: C08F222/10 ,  C08F222/20 ,  C08F290/06 ,  C09D133/06 ,  B05D3/06

Abstract: The invention relates to a method for the production of adhesive-free, reduced-migration and reduced-yellowing coatings, in particular Foliendeckstrichen. Inventive coating materials containing less than 0.1 weight % of a photoinitiator and even in the absence of a photoinitiator can be hardened by exposure to UV-radiation, if the coating materials contain (meth)acrylate groups (A) and >CH-O-ether structure units (B) in certain minimum amounts, whereby (A) and (B) can also be accommodated in one molecule or in different molecules. The method exhibits many economic, technical and toxicological advantages due to said reduction of the amount of photoinitiators or the absence of photoinitiators.

公开(公告)号：CA2386222A1

公开(公告)日：2001-04-05

申请号：CA2386222

申请日：2000-09-29

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  PAULUS WOLFGANG ,  MEISENBURG UWE ,  SCHROF WOLFGANG ,  VOLLINGER FRANK ,  BRUCHMANN BERND ,  BECK ERICH

IPC: C08L75/04 ,  C08G18/00 ,  C08G18/08 ,  C08G18/67 ,  C08G18/78 ,  C08G18/79 ,  C08G18/80 ,  C09D4/00 ,  C09D175/04 ,  C09D175/14 ,  C09D175/16

Abstract: The invention relates to aqueous polyurethane dispersions which can be hardened with UV radiation and thermally. Said polyurethane dispersions contain the following: compounds bonded with polyisocyanates, with C=C doubl e bonds that can be polymerised with UV-radiation; aliphatic diols inserted wi th isocyanates, with a molecular weight of less than 500 g/mol; compounds bonde d with isocyanates, with carboxylic acid or sulphonic acid groups and/or salts thereof, free hydroxyl groups and compounds with blocked isocyanate groups. The inventive polyurethane dispersions are suitable for coating thermostable substrates such as metal substrates and can be advantageously used for clear automobile lacquers.

公开(公告)号：DE19941136A1

公开(公告)日：2001-03-01

申请号：DE19941136

申请日：1999-08-30

Applicant: BASF AG

Inventor： LEUBE HARTMANN F ,  LEIDINGER KURT ,  GEISENDOERFER MATTHIAS ,  BECK ERICH

IPC: C07C67/08 ,  C07C69/54

Abstract: Production of (meth)acrylate esters by refluxing high-boiling mono- or polyhydric alcohols with (meth)acrylic acid in presence of acid catalyst, entraining agent (I). Production of (meth)acrylate esters by refluxing high-boiling mono- or polyhydric alcohols with (meth)acrylic acid in presence of acid catalyst, entraining agent (I) for water and polymerisation inhibitor, in which (I) is returned to the reaction at a rate such that the mixture boils at essentially constant temperature.

公开(公告)号：DE19937563A1

公开(公告)日：2001-02-15

申请号：DE19937563

申请日：1999-08-09

Applicant: BASF AG

Inventor： SCHWARTZ MANFRED ,  MENZEL KLAUS ,  BECHERT BERTOLD ,  BECK ERICH ,  REICH WOLFGANG

IPC: C04B41/48 ,  C04B41/63

Abstract: A mineral based product is produced by a conventional method and a fluid polymer or prepolymer is applied to the surface and hardened to form a spacer. Independent claims are made for a mineral based product produced by the claimed process; b) a stack of such products where the applied polymer forms spacers between the products.

公开(公告)号：CA2356685A1

公开(公告)日：2000-07-06

申请号：CA2356685

申请日：1999-12-14

Applicant: BASF AG

Inventor： REICH WOLFGANG ,  BRUCHMANN BERND ,  LOKAI MATTHIAS ,  BECK ERICH ,  SCHWALM REINHOLD ,  KONIGER RAINER ,  RENZ HANS

IPC: G03F7/027 ,  A61K6/893 ,  C07C265/14 ,  C07C275/60 ,  C08G18/67 ,  C08G18/78 ,  C08G18/81 ,  C09D4/00 ,  C09D5/00 ,  C09D175/04 ,  C09D175/14 ,  C09D175/16 ,  C09D201/02

Abstract: The invention relates to compounds comprising isocyanate groups or capped isocyanate groups, allophanate groups and radically polymerizable C-C double covalent bonds, whereby the C-C double covalent bonds are activated by a carbonyl group bonded directly thereon or by an O-atom in ether function (activated double covalent bonds), derived from polyisocyanates and alcohols A which, in addition to the alcohol group, carry another activated double covalent bond (compounds (I)). The invention also relates to radiation- hardenable preparations and coating agents which contain compounds (I), to methods for coating while using these substances, and to coated articles produced according to these methods. The invention additionally relates to t he use of compounds (I) in radiation-hardenable materials such as in casting materials, dental materials, composite materials, sealants, adhesives, fillers, printing inks, in photostructurable materials such as solder resist s, photoresists, photopolymeric printing plates, and stereolithographic resins.

公开(公告)号：DE19860041A1

公开(公告)日：2000-06-29

申请号：DE19860041

申请日：1998-12-23

Applicant: BASF AG

Inventor： BRUCHMANN BERND ,  BECK ERICH ,  RENZ HANS ,  KOENIGER RAINER ,  SCHWALM REINHOLD ,  LOKAI MATTHIAS ,  REICH WOLFGANG

IPC: G03F7/027 ,  A61K6/893 ,  C07C265/14 ,  C07C275/60 ,  C08G18/67 ,  C08G18/78 ,  C08G18/81 ,  C09D4/00 ,  C09D5/00 ,  C09D175/04 ,  C09D175/14 ,  C09D175/16 ,  C09D201/02 ,  A61K6/08 ,  C08L75/04

Abstract: The invention relates to compounds comprising isocyanate groups or capped isocyanate groups, allophanate groups and radically polymerizable C-C double covalent bonds, whereby the C-C double covalent bonds are activated by a carbonyl group bonded directly thereon or by an O-atom in ether function (activated double covalent bonds), derived from polyisocyanates and alcohols A which, in addition to the alcohol group, carry another activated double covalent bond (compounds (I)). The invention also relates to radiation-hardenable preparations and coating agents which contain compounds (I), to methods for coating while using these substances, and to coated articles produced according to these methods. The invention additionally relates to the use of compounds (I) in radiation-hardenable materials such as in casting materials, dental materials, composite materials, sealants, adhesives, fillers, printing inks, in photostructurable materials such as solder resists, photoresists, photopolymeric printing plates, and stereolithographic resins.

公开(公告)号：DE19806035A1

公开(公告)日：1999-08-19

申请号：DE19806035

申请日：1998-02-13

Applicant: BASF AG

Inventor： SCHROF WOLFGANG ,  SCHWALM REINHOLD ,  SCHUHMACHER PETER ,  REICH WOLFGANG ,  BECK ERICH ,  MEISENBURG UWE ,  MEYER-ROSCHER BERND

IPC: B29C35/02 ,  B29C35/08 ,  G01J3/44 ,  G01N33/44 ,  G01N21/47 ,  G01J3/28

Abstract: Determination of the effectiveness of an irradiation wavelength(s) in a light-driven reaction(s) in at least one position of a probe comprises irradiating the probe with light and evaluating the condition of the probe. Determination of the effectiveness of an irradiation wavelength(s) in a light-driven reaction(s) in at least one position of a probe comprises irradiating the probe with light and evaluating the condition of the probe. Independent claims are also included for two evaluation apparatus, both comprising a light source with variable wavelength and a focussing apparatus, one further including an apparatus for irradiating monochromatic light and detecting the resulting scattered light and the other an apparatus for focussing irradiated light on or in the probe along the axis and detecting the scattered light.

公开(公告)号：AT178636T

公开(公告)日：1999-04-15

申请号：AT95939291

申请日：1995-11-21

Applicant: BASF AG

Inventor： BECK ERICH ,  MEYER FRANK ,  POTH ULRICH ,  SIEMENSMEYER KARL ,  SIERAKOWSKI CLAUDIA ,  GREIF NORBERT ,  OSTERTAG WERNER ,  ZIRNSTEIN MICHAEL ,  LEYRER REINHOLD ,  JAHNS EKKEHARD ,  ETZBACH KARL-HEINZ ,  SCHUHMACHER PETER

IPC: C09K19/38 ,  C08F20/28 ,  C09B67/00 ,  C09D4/00 ,  C09D4/06 ,  C09D5/29 ,  C09D5/36 ,  C09D11/02 ,  C09D11/10 ,  C09D11/16 ,  C09K19/00 ,  C09K19/54 ,  C09K19/58

Abstract: PCT No. PCT/EP95/04576 Sec. 371 Date May 23, 1997 Sec. 102(e) Date May 23, 1997 PCT Filed Nov. 21, 1995 PCT Pub. No. WO96/02597 PCT Pub. Date Feb. 1, 1996A process for coating or printing substrates with a coating or printing composition comprises applying a polymerizable material containing liquid-crystalline, polymerizable monomers which carry at least two polymerizable groups for coating and at least one polymerizable group for printing, to the substrate, and subsequently carrying out the polymerization, where the coating composition or the printing composition comprises a1) a chiral liquid-crystalline monomer and b) a polymeric binder and/or monomeric compounds which can be converted into the polymeric binder by polymerization, or, in the case of emulsion coatings and printing inks, a dispersion auxiliary d), or the coating composition or the printing composition comprises a2) an achiral liquid-crystalline monomer, b) a polymeric binder and/or monomeric compounds which can be converted into the polymeric binder by polymerization, or, in the case of emulsion coatings and printing inks, a dispersion auxiliary d), and c) a non-liquid-crystalline chiral compound.