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    New cyclohexene-di:carboxylic acid di:amide derivs. - used as selective herbicides, plant growth regulators, desiccants and defoliants
    155.
    发明专利
    New cyclohexene-di:carboxylic acid di:amide derivs. - used as selective herbicides, plant growth regulators, desiccants and defoliants 未知

    公开(公告)号：DE4213715A1

    公开(公告)日：1993-10-28

    申请号：DE4213715

    申请日：1992-04-25

    Applicant: BASF AG

    Inventor： KLINTZ RALF DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  PLATH PETER DR ,  KARDORFF UWE DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

    IPC: A01N37/30 ,  A01N37/32 ,  A01N37/34 ,  A01N37/46 ,  A01N43/12 ,  A01N43/16 ,  A01N43/40 ,  A01N43/74 ,  C07C233/61 ,  C07C233/63 ,  C07C255/13 ,  C07C255/46 ,  C07D209/48 ,  C07D295/185 ,  C07D307/12 ,  C07D307/90 ,  C07D309/06 ,  C07D339/08 ,  C07D401/10 ,  C07D413/10 ,  C07D417/10 ,  C07C233/57 ,  A01N37/22 ,  A01N37/24 ,  A01N43/54 ,  C07D403/10 ,  C07D405/10 ,  C07D409/10

    Abstract: N-(Substd. phenyl)-cyclohexene -1,2-dicarboxylic acid diamide derivs. of formula (I) and their salts are new. In (I), R1, R2 = (i) H; (ii) alkyl, alkenyl or alkynyl all opt. substd. (iii) 3-8C cycloalkyl; or (iv) phenyl or heterocyclyl (contg. 1-4 heteroatoms selected from 1-4N, 1 or 2 O and 1 or 2 S), both opt. C-substd. by one or more of OH, halogen, CN, NO2, CF3, halogen and alkyl; if R1 = H or alkyl, then additionally: R2 = (v) OH, alkoxy, alkenyloxy, alkynyloxy, 3-7C cycloalkoxy, 5-7C cycloalkenyloxy, haloalkoxy, haloalkenyloxy, (3-7C) cycloalkyl-alkoxy, alkoxycarbonyl, cyanoalkoxy, hydroxyalkoxy, alkoxyalkoxy, alkoxycarbonylalkoxy, alkylthioalkoxy or mono- or dialkylamino-alkoxy; (vi) phenylalkoxy, phenylalkenyloxy or phenylalkynyloxy (in which 1 or 2 CH2 gps. of the aliphatic chain are opt. replaced by O, S and/or N (alkyl) and phenyl rings are opt. substd. by 1-3 of alkyl, 2-6C alkenyl, halogen, CN, NO2, haloalkyl alkoxy and alkoxycarbonyl), or (vii) NR7R8; or NR1R2 = non-aromatic heterocycle which can contain 1-3 N and/or one O or S and 1 or 2 CO gps. and is opt. mono-, di- or tri-alkyl substd.; R7, R8 = H, alkyl, alkenyl, alkynyl, 3-6C cycloalkyl, haloalkyl, alkylcarbonyl, alkoxycarbonyl, alkoxyalkyl or phenyl, opt. substd.; or NR7R8 = 4-7 membered heterocycle opt. contg. a further N, 0 or S heteroatom; R3 = H or alkyl; R4 = H or halogen; R5 = H, halogen, NO2, CN or CF3; R6 = e.g. heterocyclyl (contg. 1-4 heteroatoms selected from 1-4N, 1-2 O and 1-2 S, opt. with 1 or 2 CH2 gps. replaced by CO), opt. C-substd. etc. or R5 + R6 = satd. or partially or completely unsatd. 3-5 membered hydrocarbon chain (opt. contg. 1 or 2 O, S or N and/or one CO or alkoxyimino as chain member; and opt. substd. by 1 or 2 of CN, NO2, NH2, halogen, alkyl, haloalkyl, 2-6C alkenyl, 2-6C alkynyl, cyanoalkyl, alkoxycarbonylalkyl, phenylalkyl and heterocyclyl-alkyl (where heterocyclyl contains 1-4 heteroatoms selected from 1-4N, 1-2 O and 1-2 S)); unless otherwise specified, all alkyl moieties contain 1-6C, and alkenyl and alkynyl moieties 3-6C; and heterocycles are satd. or partially or completely unsatd. and have 3-8 members. Also claimed are certain new 3,4,5,6-tetrahydrophthalimide, 3,4,5,6-tetrahydro-phthalisoimide and tetrahydrophthalamic acid deriv. intermediates. USE/ADVANTAGE - (I) are herbicides (claimed), plant growth regulators, defoliants (claimed) and desiccants (claimed); the new intermediates have the same activities. As herbicides, the cpds. are esp. useful for combatting dicotyledonous weeds and are useful as selective herbicides in wheat, rice, maize, soya and cotton. (I) have good herbicidal activity and higher selectivity (better culture plant compatibility) than related known cpds. The cpds. are useful as desiccants/defoliant for defoliation of cotton or desiccating the ground parts of potatoes, sunflowers, soybeans and rape to facilitate mechanical harvesting. They also promote abscission of citrus fruits, olives and other fruits. The cpds. are applied pre- or post-emergence at 0.001-3 (pref. 0.01-1) kg/ha, or to seeds.

    156.
    发明专利
    未知

    公开(公告)号：DE4204206A1

    公开(公告)日：1993-08-19

    申请号：DE4204206

    申请日：1992-02-13

    Applicant: BASF AG

    Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  RANG HARALD DR ,  SIEGEL HARDO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  KARDORFF UWE DR

    IPC: C07D333/22 ,  A01N35/10 ,  A01N43/14 ,  A01N43/18 ,  A01N43/36 ,  A01N43/80 ,  C07C239/20 ,  C07C251/54 ,  C07C323/47 ,  C07D231/12 ,  C07D261/08 ,  C07D309/04 ,  C07D309/06 ,  C07D335/02

    Abstract: Mixtures of optically active cyclohexenone oxime ethers, with an R and S configuration in the oxime ether section of formula (I) where R = C1-C6 alkyl; X = NO2, CN, halogen, C1-C4 alkyl, C1-C4 halogen alkyl; n = 0-3 or 1-5 if all X substituents are halogen; R = C1-C4-alkoxy-C1-C6-alkyl, C1-C4-alkythio-C1-C6-alkyl, optionally substituted C3-C7 cycloalkyl, optionally substituted C5-C7 cycloalkenyl, optionally substituted 5-membered saturated heterocyclic ring containing 1 or 2 oxygen and/or sulphur atoms, optionally substituted 6 or 7-membered heterocyclic ring with 1 or 2 non-adjacent oxygen and/or sulphur atoms which may be saturated or singly or doubly unsaturated, optionally substituted aromatic 5-membered heterocyclic ring containing one to two N atoms and one O or S atom, phenyl or pyridyl both of which may bear 1-3 substituents: halogen, NO2, CN, alkyl, alkoxy, alkylthio, halogen alkyl, alkenyloxy, alkinyloxy and/or -NR R ; R = H, alkyl, alkenyl or alkinyl and R = H, alkyl, alkenyl, alkinyl, acyl or optionally substituted benzoyl; and their agriculturally usable salts, and esters of C1-C10 carboxylic acids and inorganic acids of compounds (I), with the proviso that the mixtures contain at least 75 mol % isomers with R configuration in the oxime ether part.

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