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    11.
    发明专利
    未知

    公开(公告)号：DE19646679A1

    公开(公告)日：1998-05-14

    申请号：DE19646679

    申请日：1996-11-12

    Applicant: BASF AG

    Inventor： BROECKER FRANZ JOSEF DR ,  AQUILA WERNER DR ,  FLICK KLEMENS DR ,  KAIBEL GERD DR ,  LANGGUTH ERNST DR

    IPC: B01J23/44 ,  B01J27/057 ,  B01J35/10 ,  C07B35/08 ,  C07B61/00 ,  C07C29/56 ,  C07C33/03 ,  C07C41/32 ,  C07C43/15 ,  C07C67/293 ,  C07C69/145 ,  C07C33/025

    Abstract: A solid bed catalyst containing either palladium and selenium and/or tellurium on a silica carrier, has a BET surface area of 80-380 m /g, a pore volume of 0.6-0.95 cm /g and a pore diameter of 3 nm to 300 mu m. The proportion of the pore volume with a pore diameter of 10-100 nm is 80-95%. Also claimed are: (i) the preparation of the above catalyst; and (ii) the preparation of 2-buten-1-ol compounds of formula H2R1C-R2C=CR3-CR4R5-OR6 (I) by isomerising 3-buten-1-ol compounds of formula HR1C=CR2-CHR3-CR4R5-OR6 (II) in the presence of hydrogen and the catalyst. In the formulae: R1-R6 = H or aliphatic group (optionally substituted with OH, OR, halogen or carboxyl), or R2 may also be -CHO, or R2 and R5 can combine with the C atoms between them to form an alicyclic ring, or R6 can also be a cycloaliphatic, arylaliphatic or aromatic group or a group of formula C(=O)-R7; R = aliphatic group; and R7 = aliphatic, cycloaliphatic, arylaliphatic or aromatic group.

    12.
    发明专利
    未知

    公开(公告)号：DE19636768A1

    公开(公告)日：1998-03-12

    申请号：DE19636768

    申请日：1996-09-10

    Applicant: BASF AG

    Inventor： FLICK KLEMENS DR ,  FISCHER ROLF DR ,  EBEL KLAUS DR ,  SCHNURR WERNER DR ,  VOIT GUIDO DR

    IPC: B01J23/75 ,  B01J23/74 ,  B01J23/76 ,  B01J25/00 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24 ,  C07C255/25

    Abstract: The invention concerns catalysts suitable for preparing aliphatic alpha-, omega-aminonitriles by partial hydrogenation of aliphatic dinitriles, containing: (a) metallic cobalt, a cobalt compound or their mixtures, the metallic cobalt portion being between 20 and 100 wt % relative to (a); (b) between 10 and 70 wt %, relative to (a), of metallic iron, iron oxide, a further iron compound or their mixtures, the iron oxide portion being between 20 and 100 wt % relative to (b); and (c) between 0 and 1 wt %, relative to (a), of a compound based on an alkali metal, alkaline earth metal or zinc.

    Simple, economical production of aliphatic alpha,omega-amino-nitrile from di:nitrile with high selectivity
    13.
    发明专利
    Simple, economical production of aliphatic alpha,omega-amino-nitrile from di:nitrile with high selectivity 未知

    公开(公告)号：DE19636767A1

    公开(公告)日：1998-03-12

    申请号：DE19636767

    申请日：1996-09-10

    Applicant: BASF AG

    Inventor： EBEL KLAUS DR ,  FISCHER ROLF DR ,  FLICK KLEMENS DR ,  MERGER MARTIN DR ,  VOIT GUIDO DR

    IPC: C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

    Abstract: In the production of aliphatic alpha ,w-aminonitriles (I) by catalytic partial hydrogenation of aliphatic alpha ,w-dinitriles (II), the catalyst contains: (a) iron (Fe) and/or Fe compound(s); (b) 0.01-5 wt.%, with respect to (a), of a promoter based on group 2, 3, 4 or 5 elements selected from aluminium, silicon, zirconium, titanium and vanadium; and (c) 0-0.5 wt.%, with respect to (a), of an alkali(ne earth) metal compound. Preferably component (a) is based on Fe oxide(s) and (b) on Al, Si and V. The catalyst is optionally supported. Simultaneous production of ACN and HMD from ADN comprises: (1) catalytic partial hydrogenation of ADN to a mixture containing ACN, HMD and ADN; (2) separation of ACN and HMD from the mixture; (3) adding an acid or acid ion exchanger to the mixture containing ADN especially in an amount of 0.01-10 wt.% with respect to ADN, ADN is then separated. If ADN is separated by distillation, the acid used has a boiling point above that of ADN at the pressure used for distillation and a pKa value \} 10. The purified ADN is then recycled. Hydrogenation may be carried out in a suspension or stationary bed reactor.

    17.
    发明专利
    未知

    公开(公告)号：ES2154660T3

    公开(公告)日：2001-04-16

    申请号：ES94117574

    申请日：1994-11-08

    Applicant: BASF AG

    Inventor： FLICK KLEMENS DR ,  POLANEK PETER DR ,  POSSELT DIETMAR DR

    IPC: B01J23/44 ,  B01J23/50 ,  B01J37/00 ,  B01J37/02 ,  C07C5/05 ,  C07C5/09 ,  C10G45/34

    Abstract: Supported catalysts, obtainable by a) dissolving a catalytically active component or precursor compound thereof in a solvent, b) adding to the solution thus obtained an organic polymer which has the ability to bind at least ten times its own weight of water, c) subsequent mixing of the polymer with a catalyst support material, d) shaping the composition thus obtained, drying and calcination, a process for the production thereof and use thereof.

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