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公开(公告)号:DE59712176D1
公开(公告)日:2005-03-03
申请号:DE59712176
申请日:1997-02-25
Applicant: BASF AG
Inventor: LICHT ULRIKE , KOKEL NICOLAS , HAEBERLE KARL , WUESTEFELD RENATE
IPC: C08G18/00 , C08G18/08 , C08G18/67 , C08G18/83 , C08K5/10 , C08G73/02 , C08G75/04 , C08L75/14 , C08L79/02 , C08L81/02 , C09D175/14 , C09D179/02 , C09D181/02 , C09J11/06 , C09J175/14 , C09J179/02 , C09J181/02
Abstract: Latent-crosslinking aqueous polyurethane (PU) dispersions, containing (I) a disperse phase (P.I) containing (Ia) a polyurethane (PUR.Ia) with groups which produce the water- dispersibility and also groups containing a C=C double bond activated by a directly attached carbonyl group or (Ib) a mixture of a PU (PUR.Ib) with water dispersibility-producing groups but no activated double bonds as above and a compound (V.I) other than PUR.Ia and PUR.Ib which contains groups with a CO-activated C=C bond as above, and (II) a disperse phase (P.II) containing a compound other than the above which contains several thiol, prim. amino or sec. amino groups. Also claimed are objects made of wood, metal, textile, leather or plastic, which are bonded, impregnated or coated with these PU dispersions.
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公开(公告)号:ES2175760T3
公开(公告)日:2002-11-16
申请号:ES98941363
申请日:1998-07-20
Applicant: BASF AG
Inventor: BEUTLER KUNO , HAEBERLE KARL , HUMMERICH RAINER , LICHT ULRIKE , KOKEL NICOLAS , TREIBER REINHARD
IPC: C08G18/00 , C08G18/08 , C08G18/10 , C08G18/70 , C08G18/79 , C09D175/04 , C09D175/06 , C09J175/04 , C14C11/00 , D06M15/564 , D06M15/572 , D06N3/14 , E04D5/02
Abstract: Aqueous dispersions comprising a polyurethane which comprises carbodiimide structural units of the formula (I)
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公开(公告)号:AT215102T
公开(公告)日:2002-04-15
申请号:AT98941363
申请日:1998-07-20
Applicant: BASF AG
Inventor: BEUTLER KUNO , HAEBERLE KARL , HUMMERICH RAINER , LICHT ULRIKE , KOKEL NICOLAS , TREIBER REINHARD , KAEHS HELMUT , MOSSBACH RALF , GOETZ THOMAS
IPC: C08G18/00 , C08G18/08 , C08G18/10 , C08G18/70 , C08G18/79 , C09D175/04 , C09D175/06 , C09J175/04 , C14C11/00 , D06M15/564 , D06M15/572 , D06N3/14 , E04D5/02
Abstract: Aqueous dispersions comprising a polyurethane which comprises carbodiimide structural units of the formula (I)
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公开(公告)号:CA2219835A1
公开(公告)日:1998-05-21
申请号:CA2219835
申请日:1997-11-20
Applicant: BASF AG
Inventor: GYOPAR RAU MARIA , FISCHER GERHARD , GULBINS ERICH , KOKEL NICOLAS
IPC: C08G18/08 , C08G18/38 , C08G18/84 , C09D11/102 , C08L75/04 , C09D175/04
Abstract: Aqueous dispersions containing a polyurethane(A) having structural units derived from compounds of the formula (I) (see fig. I) in which the substituents have the following meanings: R1, R2, R3 independently denote hydrogen, C1-C24 alkyl or C6-C24 alkenyl R4 denotes hydrogen R5, R6 (a) together denote C4-C10 alkanediyl, (b) each denotes C2-C10 alkyl, C5-C8 cycloalkyl or C7-C20 aralkyl, (c) each denotes a hydroxyl-terminated poly(C2-C4 alkylene oxide), or (d) one radical R5 or R6 has the meaning stated under (a) to (c) and the other is hydrogen or a radical of the formula II (see fig. II) in which X denotes C2-C6 alkanediyl and R7 has the same meaning as R5 or R6 except that R7 does not denote a radical of the formula II, where . - the radicals R5 and R6 in each of the cases (a) and (d) carry a total of one (1 ) hydroxyl group attached to an aliphatic carbon atom, - optionally the radical R5 and/or R6 carries 1 or 2 hydroxyl groups bonde d to an aromatic carbon atom or one nitrile, tertiary amino, carboxylic acid or sulfonic acid group which are optionally present in the form of their salts, and - the average functionality (F) of all structural components of the polyur ethane (A) is from 1.5 to 2.2, based on the functionalities which interreact during the synthesis of the polyurethane (A) in an addition reaction.
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公开(公告)号:DE59800994D1
公开(公告)日:2001-08-16
申请号:DE59800994
申请日:1998-04-02
Applicant: BASF AG
Inventor: KOKEL NICOLAS , MENZEL KLAUS , REICH WOLFGANG
IPC: C09D175/04 , C09D175/16
Abstract: Aqueous dispersions which are essentially free from protective colloids or emulsifiers, comprise, in dispersed form,A. a polyurethane (A) comprising hydrophilic groups, which bring about the water-dispersibility of the polyurethane, this polyurethane (A) being essentially free from C-C double bonds, andB. a prepolymer having a content of from 0.1 to 1 mol of free-radically polymerizable C-C double bonds per 100 g of prepolymer.
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公开(公告)号:DE19821666A1
公开(公告)日:1999-11-25
申请号:DE19821666
申请日:1998-05-14
Applicant: BASF AG
Inventor: BOLLMANN HEINZ , HAEBERLE KARL , KOKEL NICOLAS , THAERIGEN RAINA
IPC: C08G18/08 , C07C267/00 , C07C271/20 , C08G18/02 , C08G18/28 , C08G18/38 , C08G18/79 , C08G18/80 , C08K5/29 , C08L75/06 , C09K15/18 , C07C275/24 , C07C271/28 , C07C269/02 , C07C273/18 , C08G18/64
Abstract: Carbodi-imides (I) based on 1,3-bis-(1-methyl-1-isocyanato-ethyl)-benzene (BMIEB), containing 12-40 wt% ethylene oxide (EO) units. Independent claims are also included for: (a) a process for the production of (I) by reaction of BMIEB in presence of catalysts with cleavage of carbon dioxide, followed by reaction of the isocyanate groups with a suitable reactive compound (i) which also contains EO units; (b) another process for the production of (I) by reaction of BMIEB with compound(s) containing EO units, so that the ratio of NCO groups to NCO-reactive groups is at least 2:1, followed by catalytic cleavage of CO2; (c) carbodi-imides (I) obtained by these processes; (d) mixtures of (I) with compounds containing ester units or with polyurethanes containing ester groups, polycondensation products such as thermoplastic polyesters (e.g. polyethylene and polybutylene terephthalate), polyether-esters, polyester-esters, polyester-amides, polycaprolactones, unsaturated polyester resins or polyamides; (e) a process for the production of polyurethanes by reacting isocyanates with isocyanate-reactive compounds, blowing agents and optionally catalysts and additives etc. in presence of (I); (f) polyurethanes obtained by process (d).
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公开(公告)号:DE19809634A1
公开(公告)日:1999-09-09
申请号:DE19809634
申请日:1998-03-06
Applicant: BASF AG
Inventor: KOKEL NICOLAS , HAEBERLE KARL , KRAUS RUPERT
IPC: C07C267/00 , C07C271/10 , C07C271/20 , C07C275/00 , C07C275/04 , C07C271/06 , C07C275/24 , C07C269/02 , C07C273/18 , C08K5/205 , C08K5/21 , C08K5/29 , C08G18/78 , C08G18/32 , C09K15/16
Abstract: Carbodiimides which are solid at 25 degrees C, containing carbodiimide structures which are attached to non-aromatic carbon atoms, together with urethane and/or urea structures. Independent claims are also included for: (a) a process for the production of these solid carbodiimides from di-isocyanates in which the isocyanate (NCO) groups are not attached to aromatic carbon, by reaction in presence of catalysts to form the carbodiimide with cleavage of carbon dioxide, followed by reaction with compounds containing at least two NCO-reactive groups; (b) another process in which the above stages are reversed and the ratio of NCO groups to NCO-reactive groups used in the first stage is at least 2:1; (c) solid carbodiimides obtained by these processes; (d) mixtures containing compounds with ester units together with these carbodiimides; and (e) mixtures containing these carbodiimides and at least one of the following: polyurethanes with ester units and/or polycondensation products such as polyesters, e.g. polyethylene- or polybutylene- terephthalate, polyether-esters, polyester-esters, polyester-amides, polycaprolactones, unsaturated polyester resins and polyamides.
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公开(公告)号:CA2262843A1
公开(公告)日:1999-09-06
申请号:CA2262843
申请日:1999-03-05
Applicant: BASF AG
Inventor: KRAUS RUPERT , HAEBERLE KARL , KOKEL NICOLAS
IPC: C07C267/00 , C07C271/10 , C07C271/20 , C07C275/00 , C07C275/04 , C07C275/24 , C07C275/26 , C08K5/29
Abstract: In carbodiimides which contain carbodiimide structures and also urethane and/or urea structures and are solid at 25.degree.C, the carbodiimide structures are bound to non-aromatic carbon atoms.
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公开(公告)号:CA2298476A1
公开(公告)日:1999-02-11
申请号:CA2298476
申请日:1998-07-20
Applicant: BASF AG
Inventor: MOSSBACH RALF , KAEHS HELMUT , KOKEL NICOLAS , TREIBER REINHARD , LICHT ULRIKE , GOETZ THOMAS , BEUTLER KUNO , HAEBERLE KARL , HUMMERICH RAINER
IPC: C08G18/00 , C08G18/08 , C08G18/10 , C08G18/70 , C08G18/79 , C09D175/04 , C09D175/06 , C09J175/04 , C14C11/00 , D06M15/564 , D06M15/572 , D06N3/14 , E04D5/02
Abstract: The invention concerns aqueous dispersions containing a polyurethane (1) containing carbodiimide building blocks of formula (I): -N=C=N-.
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公开(公告)号:CA2222922A1
公开(公告)日:1998-06-19
申请号:CA2222922
申请日:1997-12-18
Applicant: BASF AG
Inventor: KOKEL NICOLAS , BECK ERICH , REICH WOLFGANG , VOIT GUIDO , LARBIG HARALD , MENZEL KLAUS
IPC: C08G18/00 , C08G18/08 , C08G18/16 , C08G18/28 , C08G18/30 , C08G18/32 , C08G18/67 , C09D5/00 , C09D175/08 , C09D175/04 , C08L75/04 , B05D3/06 , C09D175/14 , C08L75/14 , C08G18/65
Abstract: A polyurethane which is substantially self-dispersible in water and is obtainable by reacting a) at least one polyisocyanate with b) at least one polyol and c) at least one photoinitiator of the general formula I (see fig. I) where R is a radical of the formula II (see fig. II) or is -CR7R8R9, P(=O)(R10)2 or SO2R11, the number-average molecular weight Mn of the polyurethane being greater than 2700, and its use. The invention also relates to aqueous polyurethane resin dispersions and coating compositions comprising the novel polyurethanes, and to their use.
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