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公开(公告)号:DE102004051647A1
公开(公告)日:2006-07-06
申请号:DE102004051647
申请日:2004-10-22
Applicant: BASF AG
Inventor: MUELLER GABI , LAUBENDER MATTHIAS , WOOD CLAUDIA
IPC: A61K8/02 , A61K8/81 , A61Q5/06 , C08F220/00 , C08F222/00 , C08F226/06 , C09D5/04 , C09D133/08 , C14C3/18 , D21H19/58 , F17D1/17
Abstract: Copolymers prepared by a process comprising free-radical polymerizing: (a) more than 15 to 40% by weight of at least one monoethylenically unsaturated carboxylic acid; (b) 30 to less than 85% by weight of ethyl methacrylate; and (c) 0 to 50% by weight of at least one additional free-radically polymerizable monomer other than the at least one monoethylenically unsaturated carboxylic acid and ethyl methacrylate; wherein the total amount of (a), (b) and (c) equals 100% by weight; with the proviso that where the process comprises a solution polymerization, (a) consists of acrylic acid and methacrylic acid, and (c) is an ester of (meth)acrylic acid and an aliphatic C 8 -C 18 -alcohol, then the ester of (meth)acrylic acid and an aliphatic C 8 -C 18 -alcohol is not present in an amount of 5 to 40% by weight; and with the proviso that where (c) is selected from the group consisting of N-vinylpyrrolidone, N-vinylcaprolactam and mixtures thereof; then the N-vinylpyrrolidone, N-vinylcaprolactam or mixture thereof is present in an amount of less than 5% by weight.
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公开(公告)号:DE10224922A1
公开(公告)日:2003-12-18
申请号:DE10224922
申请日:2002-06-04
Applicant: BASF AG
Inventor: MICHL KATHRIN , GERST MATTHIAS , LAUBENDER MATTHIAS , FAUL DIETER , RAUBENHEIMER HANS-JUERGEN
IPC: C08F2/16 , C08F2/10 , C08F2/44 , C08F220/02 , C08F220/04 , C08F220/34 , C08F222/02 , C08F222/22 , C08F246/00
Abstract: An ethylenically unsaturated monocarboxylic acid and/or dicarboxylic acid (monomer A) (in wt.%) (50-99.5), an ethylenically unsaturated compound chosen from specific esters (0.5-50) (monomer B), and an optional monomer (monomer C) (up to 20) are polymerized in aqueous medium in the presence of foam inhibitor(s), to prepare an aqueous copolymer solution. An ethylenically unsaturated monocarboxylic acid and/or dicarboxylic acid (monomer A) (in wt.%) (50-99.5), ethylenically unsaturated compound (0.5-50) (monomer B), and an optional monomer (monomer C) (up to 20), are polymerized in an aqueous medium in the presence of at least one foam inhibitor, to prepare an aqueous copolymer solution. The monomer (B) is chosen from esters of ethylenically unsaturated monocarboxylic acids and monoesters and diesters of ethylenically unsaturated dicarboxylic acids with an amine containing at least one hydroxyl group.
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公开(公告)号:DE10113227A1
公开(公告)日:2002-09-26
申请号:DE10113227
申请日:2001-03-19
Applicant: BASF AG
Inventor: ROECKEL HARALD , ZHAO CHENG-LE , LAUBENDER MATTHIAS
IPC: C08F265/04 , C08F291/00 , C08L51/00 , C09D151/00 , C09D5/02 , C09D123/00 , C09D129/00
Abstract: Aqueous coating composition (A) contains (i), dispersed in the aqueous phase, at least one polymer (I) made from at least one ethylenically unsaturated monomer (II) and (ii) at least one alkoxylate (III) of a linear or branched aliphatic alcohol with 5-100 alkylene oxide units.
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公开(公告)号:DE102005039537A1
公开(公告)日:2007-02-22
申请号:DE102005039537
申请日:2005-08-18
Applicant: BASF AG
Inventor: HOESSEL PETER , MATHAUER KLEMENS , WOOD CLAUDIA , LAUBENDER MATTHIAS , JAHNEL WOLFGANG , GARCIA CASTRO IVETTE , WENDEL VOLKER , KOLTER KARL
Abstract: Use of water-soluble or water-dispersible polymer by polymerization of a mixture, comprising at least one alpha ,beta - ethylenic unsaturated compound, at least one of different monoethylenic unsaturated amide group containing compound, a crosslinker, at least one monoethylenic unsaturated compound containing at least one group of alkyl substituted group, alkenyl, cycloalkyl, aryl, aryl alkyl and hetaryl and/or reactive precursor, further different monoethylenic unsaturated compound and a polyether containing compound, for modification of the rheologic aqueous and/or alcoholic compositions. Use of water-soluble or water-dispersible polymer by polymerization of a mixture, comprising 99.99-10 wt.% of at least one alpha ,beta - ethylenic unsaturated compound with at least one cationogenic and/or cationic group per molecule, 0-90 wt.% of at least one of different monoethylenic unsaturated amide group containing compound, 0.01-5 wt.% of cross linker, 0-15 wt.% of at least one monoethylenic unsaturated compound containing at least one group of 5-30C alkyl substituted group, 5-30C alkenyl, 5-8C cycloalkyl, aryl, aryl alkyl and hetaryl, and/or a reactive precursor, 0-30 wt.% of further different monoethylenic unsaturated compound and 0-70 wt.% of a polyether containing compound, where the polymerization is carried out in the presence of less than 69 wt.% of cyclohexane and less than 12 wt.% of water, and the absence of carbon dioxide, for modification of the rheologic aqueous and/or alcoholic compositions. Independent claims are included for: (1) a water-soluble or water-dispersible polymer; and (2) a cosmetic or pharmaceutical agent comprising the water-soluble or water-dispersible polymer.
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公开(公告)号:DE10322786A1
公开(公告)日:2004-12-09
申请号:DE10322786
申请日:2003-05-19
Applicant: BASF AG
Inventor: KOPPERS MARKUS , PAKUSCH JOACHIM , SACK HEINRICH , KRONER MATTHIAS , KLUEGLEIN MATTHIAS , LAUBENDER MATTHIAS
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公开(公告)号:BRPI0607038A2
公开(公告)日:2009-12-01
申请号:BRPI0607038
申请日:2006-01-24
Applicant: BASF AG
Inventor: MATHAUER KLEMES , WOOD CLAUDIA , LAUBENDER MATTHIAS , CASTRO IVETTE GARCIA , WENDEL VOLKER , VILLMAR HELMUTH , RENONCOURT AUDREY , MUKHERJEE PULAKESH
Abstract: The present invention relates to the use of, if appropriate present in the form of an aqueous dispersion, polymers of ethylenically unsaturated anionic monomers for modifying the rheology of aqueous, alcoholic or aqueous/alcoholic cosmetic or dermatological compositions. The polymers are obtainable by free-radical emulsion copolymerization of water-soluble inorganic monomers in aqueous phase in the presence of, in each case, at least one stabilizing polymer of groups a) and b). The emulsion polymers are exceptionally suitable for thickening cosmetic or dermatological preparations based either on water or on alcohols.
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公开(公告)号:CA2643608A1
公开(公告)日:2007-10-11
申请号:CA2643608
申请日:2007-03-23
Applicant: BASF AG
Inventor: LAUBENDER MATTHIAS , NGUYEN KIM SON , WINTER GABI , PIEROBON MARIANNA
IPC: C08F2/04 , A61K8/00 , C08F220/10 , C08F220/54
Abstract: The present invention relates to a method of producing polymers by free-radical polymerization in solution, wherein the polymerization initiator used is an ethanol-soluble initiator, and the solution polymerization is carried out in an alcoholic solvent which comprises 5 to 50% by weight of water.
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公开(公告)号:DE102005046916A1
公开(公告)日:2007-04-05
申请号:DE102005046916
申请日:2005-09-30
Applicant: BASF AG
Inventor: NGUYEN KIM SON , LAUBENDER MATTHIAS , HOESSEL PETER
IPC: A61K8/90 , A61Q5/00 , A61Q5/06 , C08F220/06 , C08F220/10 , C08F220/52 , C08F226/06 , C08F283/06
Abstract: Use is claimed as a rheological modifier for hair cosmetics of an ampholytic copolymer with a molar excess of anionogenic/anionic groups over cationogenic/cation groups or vice-versa, the copolymer being obtained by radical polymerization of specified unsaturated compounds optionally in presence of a silicon compound containing a polyether group and/or a radically polymerizable olefinically unsaturated double bond. Use is claimed as a rheological modifier for hair cosmetics of an ampholytic copolymer with a molar excess of anionogenic/anionic groups over cationogenic/cation groups or vice-versa, the copolymer being obtained (optionally in the presence of a silicon compound containing a polyether group and/or a radically polymerizable olefinically unsaturated double bond) by radical polymerization of (A) a compound with a radically polymerizable alpha ,beta -unsaturated double bond and an anionogenic and/or anionic group; (B) a compound like (a) but having cationgenic/cationic rather than anionogenic/anionic groups; and (C) a radically polymerizable crosslinking compound with >=2 alpha ,beta -unsaturated double bonds. Some of the copolymers are also claimed per se (see also the abstract for ).
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公开(公告)号:ES2265061T3
公开(公告)日:2007-02-01
申请号:ES02790296
申请日:2002-10-18
Applicant: BASF AG
Inventor: GERST MATTHIAS , LAUBENDER MATTHIAS , RECK BERND
IPC: C08L101/00 , C09D151/00 , C08F257/02 , C08F265/04 , C08F291/00 , C08G59/42 , C08K5/15 , C08K5/1515 , C08K5/17 , C08L33/02 , C08L35/00 , C08L51/00 , C08L63/00 , D04H1/64 , D06M13/11 , D06M15/263
Abstract: Agentes aglutinantes termoendurecibles, a base de una dispersión polímera acuosa, que contiene - un polímero en emulsión (en abreviatura EP), - un polímero, que está constituido al menos por un 5% en peso de un ácido carboxílico, un ácido dicarboxílico o un anhídrido de ácido dicarboxílico monoetilénicamente insaturado (en abreviatura polímero ácido - compuestos epóxido monofuncionales o multifuncionales como endurecedores y, como endurecedores, además, un poliol o una alcanolamina con al menos dos grupos hidroxilo.
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公开(公告)号:DE102005013037A1
公开(公告)日:2006-09-21
申请号:DE102005013037
申请日:2005-03-18
Applicant: BASF AG
Inventor: HOESSEL PETER , MATHAUER KLEMENS , WOOD CLAUDIA , LAUBENDER MATTHIAS , JAHNEL WOLFGANG , GARCIA CASTRO IVETTE , WENDEL VOLKER , KOLTER KARL
IPC: C08F283/06 , A61K8/81 , A61K8/86 , A61Q5/06 , C08F2/44 , C08F8/00 , C08F220/00 , C08F226/00
Abstract: Use of water-soluble or water-dispersible polymer by polymerization, comprising at least one alpha ,beta - ethylenic unsaturated compound, at least one of different monoethylenic unsaturated amide group containing compound, a cross linker, at least one monoethylenic unsaturated compound containing at least one group of 5-30C alkyl substituted group, 5-30C alkenyl, 5-8C cycloalkyl, aryl, aryl alkyl and hetaryl, and/or a reactive precursor, 0-30 wt.% of further different monoethylenic unsaturated compound and a polyether containing compound, for modification of the rheologic aqueous composition. Use of water-soluble or water-dispersible polymer by polymerization, comprising 99.99-10 wt.% of at least one alpha ,beta - ethylenic unsaturated compound with at least one cationogenic and/or cationic group per molecule, 0-90 wt.% of at least one of different monoethylenic unsaturated amide group containing compound, 0.01-5 wt.% of cross linker, 0-15 wt.% of at least one monoethylenic unsaturated compound containing at least one group of 5-30C alkyl substituted group, 5-30C alkenyl, 5-8C cycloalkyl, aryl, aryl alkyl and hetaryl, and/or a reactive precursor, 0-30 wt.% of further different monoethylenic unsaturated compound and 0-70 wt.% of a polyether containing compound, where the polymerization is carried out in the presence of less than 69 wt.% of cyclohexane and less than 12 wt.% of water, and the absence of carbon dioxide for modification of the rheologic aqueous composition. Independent claims are included for: (1) a water-soluble or water-dispersible polymer; and (2) a cosmetic or pharmaceutical agent comprising the water-soluble or water-dispersible polymer.
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