11.
    发明专利
    未知

    公开(公告)号:DE102004051647A1

    公开(公告)日:2006-07-06

    申请号:DE102004051647

    申请日:2004-10-22

    Applicant: BASF AG

    Abstract: Copolymers prepared by a process comprising free-radical polymerizing: (a) more than 15 to 40% by weight of at least one monoethylenically unsaturated carboxylic acid; (b) 30 to less than 85% by weight of ethyl methacrylate; and (c) 0 to 50% by weight of at least one additional free-radically polymerizable monomer other than the at least one monoethylenically unsaturated carboxylic acid and ethyl methacrylate; wherein the total amount of (a), (b) and (c) equals 100% by weight; with the proviso that where the process comprises a solution polymerization, (a) consists of acrylic acid and methacrylic acid, and (c) is an ester of (meth)acrylic acid and an aliphatic C 8 -C 18 -alcohol, then the ester of (meth)acrylic acid and an aliphatic C 8 -C 18 -alcohol is not present in an amount of 5 to 40% by weight; and with the proviso that where (c) is selected from the group consisting of N-vinylpyrrolidone, N-vinylcaprolactam and mixtures thereof; then the N-vinylpyrrolidone, N-vinylcaprolactam or mixture thereof is present in an amount of less than 5% by weight.

    12.
    发明专利
    未知

    公开(公告)号:DE10224922A1

    公开(公告)日:2003-12-18

    申请号:DE10224922

    申请日:2002-06-04

    Applicant: BASF AG

    Abstract: An ethylenically unsaturated monocarboxylic acid and/or dicarboxylic acid (monomer A) (in wt.%) (50-99.5), an ethylenically unsaturated compound chosen from specific esters (0.5-50) (monomer B), and an optional monomer (monomer C) (up to 20) are polymerized in aqueous medium in the presence of foam inhibitor(s), to prepare an aqueous copolymer solution. An ethylenically unsaturated monocarboxylic acid and/or dicarboxylic acid (monomer A) (in wt.%) (50-99.5), ethylenically unsaturated compound (0.5-50) (monomer B), and an optional monomer (monomer C) (up to 20), are polymerized in an aqueous medium in the presence of at least one foam inhibitor, to prepare an aqueous copolymer solution. The monomer (B) is chosen from esters of ethylenically unsaturated monocarboxylic acids and monoesters and diesters of ethylenically unsaturated dicarboxylic acids with an amine containing at least one hydroxyl group.

    Use of water-soluble/water-dispersible polymer comprising e.g. ethylenic unsaturated compound and monoethylenic unsaturated amide group compound, for modification of rheologic aqueous and/or alcoholic composition such as hair gel

    公开(公告)号:DE102005039537A1

    公开(公告)日:2007-02-22

    申请号:DE102005039537

    申请日:2005-08-18

    Applicant: BASF AG

    Abstract: Use of water-soluble or water-dispersible polymer by polymerization of a mixture, comprising at least one alpha ,beta - ethylenic unsaturated compound, at least one of different monoethylenic unsaturated amide group containing compound, a crosslinker, at least one monoethylenic unsaturated compound containing at least one group of alkyl substituted group, alkenyl, cycloalkyl, aryl, aryl alkyl and hetaryl and/or reactive precursor, further different monoethylenic unsaturated compound and a polyether containing compound, for modification of the rheologic aqueous and/or alcoholic compositions. Use of water-soluble or water-dispersible polymer by polymerization of a mixture, comprising 99.99-10 wt.% of at least one alpha ,beta - ethylenic unsaturated compound with at least one cationogenic and/or cationic group per molecule, 0-90 wt.% of at least one of different monoethylenic unsaturated amide group containing compound, 0.01-5 wt.% of cross linker, 0-15 wt.% of at least one monoethylenic unsaturated compound containing at least one group of 5-30C alkyl substituted group, 5-30C alkenyl, 5-8C cycloalkyl, aryl, aryl alkyl and hetaryl, and/or a reactive precursor, 0-30 wt.% of further different monoethylenic unsaturated compound and 0-70 wt.% of a polyether containing compound, where the polymerization is carried out in the presence of less than 69 wt.% of cyclohexane and less than 12 wt.% of water, and the absence of carbon dioxide, for modification of the rheologic aqueous and/or alcoholic compositions. Independent claims are included for: (1) a water-soluble or water-dispersible polymer; and (2) a cosmetic or pharmaceutical agent comprising the water-soluble or water-dispersible polymer.

    16.
    发明专利
    未知

    公开(公告)号:BRPI0607038A2

    公开(公告)日:2009-12-01

    申请号:BRPI0607038

    申请日:2006-01-24

    Applicant: BASF AG

    Abstract: The present invention relates to the use of, if appropriate present in the form of an aqueous dispersion, polymers of ethylenically unsaturated anionic monomers for modifying the rheology of aqueous, alcoholic or aqueous/alcoholic cosmetic or dermatological compositions. The polymers are obtainable by free-radical emulsion copolymerization of water-soluble inorganic monomers in aqueous phase in the presence of, in each case, at least one stabilizing polymer of groups a) and b). The emulsion polymers are exceptionally suitable for thickening cosmetic or dermatological preparations based either on water or on alcohols.

    Ampholytic copolymers prepared from anionic and cationic monomers and a crosslinker optionally in presence of a silicon compound are used as a rheological modifier for hair cosmetics

    公开(公告)号:DE102005046916A1

    公开(公告)日:2007-04-05

    申请号:DE102005046916

    申请日:2005-09-30

    Applicant: BASF AG

    Abstract: Use is claimed as a rheological modifier for hair cosmetics of an ampholytic copolymer with a molar excess of anionogenic/anionic groups over cationogenic/cation groups or vice-versa, the copolymer being obtained by radical polymerization of specified unsaturated compounds optionally in presence of a silicon compound containing a polyether group and/or a radically polymerizable olefinically unsaturated double bond. Use is claimed as a rheological modifier for hair cosmetics of an ampholytic copolymer with a molar excess of anionogenic/anionic groups over cationogenic/cation groups or vice-versa, the copolymer being obtained (optionally in the presence of a silicon compound containing a polyether group and/or a radically polymerizable olefinically unsaturated double bond) by radical polymerization of (A) a compound with a radically polymerizable alpha ,beta -unsaturated double bond and an anionogenic and/or anionic group; (B) a compound like (a) but having cationgenic/cationic rather than anionogenic/anionic groups; and (C) a radically polymerizable crosslinking compound with >=2 alpha ,beta -unsaturated double bonds. Some of the copolymers are also claimed per se (see also the abstract for ).

    Use of water-soluble/water-dispersible polymer comprising e.g. ethylenic unsaturated compound, monoethylenic unsaturated amide group compound, cross linker and polyether, for modification of rheologic aqueous composition

    公开(公告)号:DE102005013037A1

    公开(公告)日:2006-09-21

    申请号:DE102005013037

    申请日:2005-03-18

    Applicant: BASF AG

    Abstract: Use of water-soluble or water-dispersible polymer by polymerization, comprising at least one alpha ,beta - ethylenic unsaturated compound, at least one of different monoethylenic unsaturated amide group containing compound, a cross linker, at least one monoethylenic unsaturated compound containing at least one group of 5-30C alkyl substituted group, 5-30C alkenyl, 5-8C cycloalkyl, aryl, aryl alkyl and hetaryl, and/or a reactive precursor, 0-30 wt.% of further different monoethylenic unsaturated compound and a polyether containing compound, for modification of the rheologic aqueous composition. Use of water-soluble or water-dispersible polymer by polymerization, comprising 99.99-10 wt.% of at least one alpha ,beta - ethylenic unsaturated compound with at least one cationogenic and/or cationic group per molecule, 0-90 wt.% of at least one of different monoethylenic unsaturated amide group containing compound, 0.01-5 wt.% of cross linker, 0-15 wt.% of at least one monoethylenic unsaturated compound containing at least one group of 5-30C alkyl substituted group, 5-30C alkenyl, 5-8C cycloalkyl, aryl, aryl alkyl and hetaryl, and/or a reactive precursor, 0-30 wt.% of further different monoethylenic unsaturated compound and 0-70 wt.% of a polyether containing compound, where the polymerization is carried out in the presence of less than 69 wt.% of cyclohexane and less than 12 wt.% of water, and the absence of carbon dioxide for modification of the rheologic aqueous composition. Independent claims are included for: (1) a water-soluble or water-dispersible polymer; and (2) a cosmetic or pharmaceutical agent comprising the water-soluble or water-dispersible polymer.

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