公开(公告)号：DE3643010A1

公开(公告)日：1988-06-30

申请号：DE3643010

申请日：1986-12-17

Applicant: BASF AG

Inventor： MERGER FRANZ ,  PRIESTER CLAUS-ULRICH ,  FISCHER ROLF ,  SAUERWALD MANFRED

IPC: C07D201/08 ,  C07D223/10

Abstract: Caprolactam is prepared by heating a 6-aminocaproic ester at 100 DEG -320 DEG C. in the presence of a reaction medium comprising an aromatic hydrocarbon which is liquid under reaction conditions and has a boiling point from 80 DEG to 240 DEG C., and isolating caprolactam from the reaction medium.

公开(公告)号：BR8503464A

公开(公告)日：1986-04-15

申请号：BR8503464

申请日：1985-07-22

Applicant: BASF AG

Inventor： SAUERWALD MANFRED ,  DOCKNER TONI ,  ROHR WOLFGANG ,  REISSENWEBER GERNOT

IPC: A01N43/18 ,  C07D335/02 ,  C07D333/22

Abstract: 5,6-Dihydro-2H-thiopyran-3-carboxaldehydes of the formula where R denotes hydrogen or methyl, are prepared by a method in which acrolein or crotonaldehyde is reacted with hydrogen sulfide in a mineral oil whose boiling point is higher than those of the starting materials and of the end product, and the 5,6-dihydro-2H-thiopyran-3-carboxaldehyde is obtained by distillation. These aldehydes are important intermediates for the preparation of some crop protection agents.

公开(公告)号：CA2322744C

公开(公告)日：2009-05-12

申请号：CA2322744

申请日：1999-03-05

Applicant: BASF AG

Inventor： WALTER MARC ,  KRATZ DETLEF ,  SCHULZ GERHARD ,  SAUERWALD MANFRED ,  HESSE MICHAEL

IPC: B01J23/72 ,  C07B61/00 ,  C07C29/141 ,  C07C31/20 ,  C07C31/22

Abstract: The invention relates to a method for the catalytic hydrogenation of a carbonyl compound or of a mixture comprised of two or more carbonyl compounds in the presence of a catalyst. Said catalyst comprises an inorganic supporting material containing TiO2, and, as an active component, copper or a mixture of copper with at least one of the metals selected from the group zinc, aluminum, cerium, a precious metal and a metal of subgroup VIII. The invention is characterized in that t he copper surface amounts to a maximum of 10 m2/g.

公开(公告)号：DE59807079D1

公开(公告)日：2003-03-06

申请号：DE59807079

申请日：1998-07-15

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS ,  WALTER MARC ,  KRATZ DETLEF ,  SCHULZ GERHARD ,  SAUERWALD MANFRED

IPC: B01J25/00 ,  C07B31/00 ,  C07B61/00 ,  C07C29/141 ,  C07C31/12 ,  C07C31/22

Abstract: A carbonyl compound or a mixture of two or more carbonyl compounds is catalytically hydrogenated in the presence of a Raney copper catalyst in the form of nuggets.

公开(公告)号：DE59510029D1

公开(公告)日：2002-03-14

申请号：DE59510029

申请日：1995-05-19

Applicant: BASF AG

Inventor： BRUDERMUELLER MARTIN ,  IRGANG MATTHIAS ,  SCHMIDT-RADDE MARTIN ,  MERGER FRANZ ,  WITZEL TOM ,  KRATZ DETLEF ,  DANZ ECKEHARD ,  WITTWER ARNOLD ,  HESSE MICHAEL ,  SAUERWALD MANFRED ,  FREIRE ERDBRUEGGER CRISTINA

IPC: B01J23/78 ,  B01J21/08 ,  B01J23/72 ,  B01J23/80 ,  B01J23/85 ,  B01J23/86 ,  C07B61/00 ,  C07C29/141 ,  C07C29/145 ,  C07C31/12 ,  C07C31/125 ,  C07C31/20 ,  C07C31/27

Abstract: Alcohols are prepared by the catalytic hydrogenation of the corresponding carbonyl compounds at elevated temperatures and at superatmospheric pressure in the liquid phase by a process in which the catalyst used contains copper on an SiO2-containing carrier in the presence or absence of one or more of the elements magnesium, barium, zinc and chromium.

公开(公告)号：ES2023175B3

公开(公告)日：1992-01-01

申请号：ES87118199

申请日：1987-12-09

Applicant: BASF AG

Inventor： MERGER FRANZ ,  PRIESTER CLAUS-ULRICH ,  FISCHER ROLF ,  SAUERWALD MANFRED

IPC: C07D201/08

Abstract: PROCEDIMIENTO PARA LA OBTENCION DE CAPROLACTAMA POR CALENTAMIENTO DE ESTERES 6-AMINOCAPROICOS EN PRESENCIA DE UN MEDIO ORGANICO INERTE, LIQUIDO EN LAS CONDICIONES DE LA REACCION, CON UN PUNTO DE EBULLICION INFERIOR AL DE LA CAPROLACTAMA. EL PROCEDIMIENTO SE CARACTERIZA PORQUE SE EMPLEAN COMO MEDIO DE REACCION HIDROCARBUROS AROMATICOS CON UN PUNTO DE EBULLICION DE 80 A 240 GRADOS C, SE MANTIENE UNA TEMPERATURA ENTRE 100 Y 320 GRADOS C, Y SE OBTIENE CAPROLACTAMA A PARTIR DEL MEDIO DE REACCION.

公开(公告)号：HUT50096A

公开(公告)日：1989-12-28

申请号：HU206589

申请日：1989-05-02

Applicant: BASF AG

Inventor： DECKER MARTIN ,  FRANZISCHKA WOLFGANG ,  IRNICH RUDOLF ,  SAUERWALD MANFRED

IPC: B01J31/04 ,  C07B61/00 ,  C07C51/00 ,  C07C51/60 ,  C07C53/38 ,  C07C53/42 ,  C07C67/00

Abstract: Acid chlorides are prepared by reaction of carboxylic acids or anhydrides thereof with phosgene in the presence of a carboxamide of the formula I in which R denotes a radical of the formulae R denotes an alkyl radical having 2 to 9 carbon atoms, R denotes an alkyl radical having 1 to 9 carbon atoms, R and R denote hydrogen atoms or alkyl radicals having 1 to 9 carbon atoms, the two radicals R and R can also represent a hydrocarbon radical which completes the molecule portion to give a heterocycle, it being possible for the alkyl and hydrocarbon radicals mentioned additionally to contain substituents which are inert under the reaction conditions.

公开(公告)号：CA2458696A1

公开(公告)日：2003-03-13

申请号：CA2458696

申请日：2002-08-10

Applicant: BASF AG

Inventor： GRIMMER JOHANNES ,  MERK CLAUDIA ,  ERNST HANSGEORG ,  SAUERWALD MANFRED ,  BOTZEM JOERG ,  MUELLER THOMAS

IPC: C25B3/25 ,  C07C45/62 ,  C25B3/04 ,  C25B9/06 ,  C25B9/20

Abstract: The invention relates to a method for producing compounds of general formula (I), wherein Rl represents an oxocyclohexyl radical which is optionally substituted by a hydroxyl radical, an alkoxy radical, and/or alkyl radicals, or an oxocyclohexenyl radical which is optionally substituted by a hydroxyl radical, an alkoxy radical, and/or alkyl radicals, the oxo groups being in t he form of an acetal, a ketone, or an enol ether, and R2 represents a hydroxy group or a protective group which can be transformed into a hydroxy group by means of hydrolysis. A compound of general formula (II) is cathodically reduced in a divided or partially divided electrolysis cell at a pH value of between 2 and 9.

公开(公告)号：DE3768784D1

公开(公告)日：1991-04-25

申请号：DE3768784

申请日：1987-12-09

Applicant: BASF AG

Inventor： MERGER FRANZ ,  PRIESTER CLAUS-ULRICH ,  FISCHER ROLF ,  SAUERWALD MANFRED

IPC: C07D201/08

Abstract: Caprolactam is prepared by heating a 6-aminocaproic ester at 100 DEG -320 DEG C. in the presence of a reaction medium comprising an aromatic hydrocarbon which is liquid under reaction conditions and has a boiling point from 80 DEG to 240 DEG C., and isolating caprolactam from the reaction medium.

公开(公告)号：HUT54607A

公开(公告)日：1991-03-28

申请号：HU504790

申请日：1990-08-16

Applicant: BASF AG

Inventor： FRANZISCHKA WOLFGANG ,  HUPPER LEOPOLD ,  HENKELMANN JOCHEM ,  KAHL THOMAS-MICHAEL ,  SAUERWALD MANFRED

IPC: B01J31/02 ,  A01N37/02 ,  C07B61/00 ,  C07C51/58 ,  C07C51/60 ,  C07C53/50