-
公开(公告)号：DE10130958A1
公开(公告)日：2003-01-16
申请号：DE10130958
申请日：2001-06-27
Applicant: BASF AG
Inventor： ROEPER MICHAEL , STEPHAN JUERGEN
Abstract: Production of propene (Pr) from a mixture (M1) that comprises: (1) ethylene (E); (2) hexenes (H); (3) other olefins (K1a); and (4) optionally other inert hydrocarbons (K1b). The mixture is contacted with a metathesis catalyst (MC) at 20-350 deg C. Production of propene from a mixture (M1) that comprises: (1) ethylene (E); (2) hexenes (H); (3) other olefins (K1a); and (4) optionally other inert hydrocarbons (K1b). The mixture is contacted with a metathesis catalyst (MC) at 20-350 deg C. The mixture (M1) has: (i) a molar proportion of the sum of 2-hexene (H2) and 3-hexene (H3) in (H) of 4-99:1; (ii) a molar ratio of (E) to the sum of (H) and (K1a) of 1-100:1; and (iii) a ratio of (H2) to (H3) of at least 2:1, as long as (H3) is not simultaneously isomerized to increase the (H2) proportion correspondingly.
-
公开(公告)号：CA2434579A1
公开(公告)日：2002-08-29
申请号：CA2434579
申请日：2002-01-23
Applicant: BASF AG
Inventor： MAAS HEIKO , WIEBELHAUS DAG , STEPHAN JUERGEN , PACIELLO ROCCO
Abstract: The invention relates to a method for selective production of linear .alpha. - olefins having a carbon number ranging from 6 20, comprising the following steps: a) reaction of a linear, internal olefin or a mixture of linear, internal olefins having a carbon number of (n/2) + 1, wherein n is the carbo n number of the desired linear .alpha.-olefin, in a transalkylation with a trialkyl aluminium compound in isomerizing conditions, wherein an olefin corresponding to the alkyl radical is released and the linear olefin thus added becomes attached to the aluminium during isomerization and the formati on of a corresponding linear alkyl aluminium compound; b) reaction of the forme d linear alkyl aluminium compound with an olefin upon release of the corresponding linear .alpha. olefin having a carbon number of (n/2) + 1 and formation of a trialkyl aluminium compound, c) introduction of the formed linear .alpha.-olefin into a self methathesis reaction, wherein a linear internal olefin having the desired carbon number n is formed, d) reaction of the formed olefin having a carbon number n with a trialkyl aluminium compoun d in isomerizing conditions, wherein an olefin corresponding to the alkyl radical is released and the linear, internal olefin becomes attached to the aluminium upon isomerization and formation of a corresponding linear alkyl aluminium compound e) reaction of the formed linear alkyl aluminium compound with an olefin upon release of the linear .alpha.-olefin having the desired carbon number n and formation of a triialkylaluminium compound; f) isolation of the desired linear .alpha.-olefin having a carbon number n.
-
公开(公告)号：ZA200603279B
公开(公告)日：2007-09-26
申请号：ZA200603279
申请日：2006-04-25
Applicant: BASF AG
Inventor： NILS BOTTKE , REGINA BENFER , THOMAS NARBESHUBER , ULRICH STEINBRENNER , MARCO BOSCH , STEPHAN JUERGEN
IPC: C07C20090101 , C07C2/66 , C11D20090101 , C11D1/22
Abstract: In a process for preparing alkylaryl compounds by reacting a C10-14-monoolefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds and if appropriate subsequently sulfonating and neutralizing the resulting alkylaryl compounds, in the C10-14-monoolefins, on average, more than 0% and up to 100% of methyl branches are present in the longest carbon chain and fewer than 50% of the methyl branches are in the 2-, 3- and 4-position, calculated starting from the chain ends of the longest carbon chain.
-
公开(公告)号：DE102005009596A1
公开(公告)日：2006-08-31
申请号：DE102005009596
申请日：2005-02-28
Applicant: BASF AG
Inventor： SCHUBERT MARKUS , STEPHAN JUERGEN , POPLOW FRANK , HEIDEMANN THOMAS , DIEHLMANN UWE , MALTRY MICHAELA
Abstract: Preparation of non-aromatic carbon-carbon double/triple bond compound (A) or its mixtures from another non-aromatic carbon-carbon double/triple bond compound (B), comprises reacting pure (B) with an adsorption agent comprising an aluminum oxide (3 wt.%) and activating at 450-1000[deg]C; and contacting the pure compound (B) with a metathesis catalyst.
-
公开(公告)号：DE102004009805A1
公开(公告)日：2005-09-15
申请号：DE102004009805
申请日：2004-02-28
Applicant: BASF AG
Inventor： SCHUBERT MARKUS , STEPHAN JUERGEN , BOEHM VOLKER , BRODHAGEN ANDREAS , POPLOW FRANK , WEICHERT CHRISTIAN , BORCHERT HOLGER
Abstract: Supported catalyst comprising a support (S) in which Al 2 O 3 is present in a proportion of at least 75% by weight and rhenium compounds as active component (A), wherein the maximum of the distribution function of the pore diameters in the mesopore range is at from 0.008 to 0.050 mum.
-
Patent Agency Ranking
公开(公告)号：DE10350333A1
公开(公告)日：2005-05-25
申请号：DE10350333
申请日：2003-10-29
Applicant: BASF AG
Inventor： BOTTKE NILS , BENFER REGINA , BOSCH MARCO , NARBESHUBER THOMAS , STEINBRENNER ULRICH , STEPHAN JUERGEN
IPC: C07C2/66 , C11D1/22 , C07C15/107 , C07C2/00
Abstract: In a process for preparing alkylaryl compounds by reacting a C10-14-monoolefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds and if appropriate subsequently sulfonating and neutralizing the resulting alkylaryl compounds, in the C10-14-monoolefins, on average, more than 0% and up to 100% of methyl branches are present in the longest carbon chain and fewer than 50% of the methyl branches are in the 2-, 3- and 4-position, calculated starting from the chain ends of the longest carbon chain.
-
公开(公告)号：DE10213492A1
公开(公告)日：2003-10-09
申请号：DE10213492
申请日：2002-03-26
Applicant: BASF AG
Inventor： STEINBRENNER ULRICH , HEIDEMANN THOMAS , SCHINDLER GOETZ-PETER , STEPHAN JUERGEN , MAAS HEIKO
IPC: C07C15/00 , C07C309/31 , C11D1/22 , C07C2/66 , C07C2/08 , C07C5/22 , C07C5/327 , C07C6/04 , C07C15/02 , C07C303/02 , C07C309/28
Abstract: Preparation of alkylaryl compounds comprises production of a 12C-olefin mixture and reaction of the 12C-olefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkylaromatic compounds whereby additional linear olefins are added before the reaction. A process for the preparation of alkylaryl compounds (I) comprises: (A) production of a 12C-olefin mixture by trimerization of butenes or dehydrogenation of 12C-alkanes, with optionally pre- or post isomerization, or by the production of a 12C-olefin mixture by oligomerization of ethene, followed by isomerization; and (B) reaction of the 12C-olefin mixture from (A) with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkylaromatic compounds whereby additional linear olefins are added before the reaction. Independent claims are included for: (1) a process for the production of alkylarylsulfonates (II) by sulfonation and neutralization of alkylaryl compounds (I); (2) the alkylaryl compounds (I); (3) the alkylarylsulfonates (II); and (4) washing- or cleaning agents containing the alkylarylsulfonates (II).
-
公开(公告)号：DE502005002594D1
公开(公告)日：2008-03-06
申请号：DE502005002594
申请日：2005-08-06
Applicant: BASF AG
Inventor： SIGL MARCUS , SCHUBERT MARKUS , STEPHAN JUERGEN , PAPP RAINER , POPLOW FRANK
Abstract: Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.
-
公开(公告)号：BRPI0415901A
公开(公告)日：2007-01-16
申请号：BRPI0415901
申请日：2004-10-29
Applicant: BASF AG
Inventor： BOTTKE NILS , BENFER REGINA , BOSCH MARCO , NARBESHUBER THOMAS , STEINBRENNER ULRICH , STEPHAN JUERGEN
Abstract: In a process for preparing alkylaryl compounds by reacting a C10-14-monoolefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds and if appropriate subsequently sulfonating and neutralizing the resulting alkylaryl compounds, in the C10-14-monoolefins, on average, more than 0% and up to 100% of methyl branches are present in the longest carbon chain and fewer than 50% of the methyl branches are in the 2-, 3- and 4-position, calculated starting from the chain ends of the longest carbon chain.
-
公开(公告)号：DE102005016152A1
公开(公告)日：2006-10-12
申请号：DE102005016152
申请日：2005-04-07
Applicant: BASF AG
Inventor： STEPHAN JUERGEN , ROEPER MICHAEL , HEIDEMANN THOMAS , TRILLER MICHAEL , TROPSCH JUERGEN
Abstract: The present invention relates to a process for preparing polyol alkyl ethers by reacting compounds comprising at least three hydroxyl functionalities with olefins in the presence of acidic catalysts at temperatures of from 20 to 250° C. and pressures of from 0.5 to 10 bar, wherein the olefins correspond to the general formula (I) in which R1 is hydrogen and R2 is a linear or branched carbon radical having from 7 to 28 carbon atoms, or R1 and R2 are each linear or branched carbon radicals having from 1 to 27 carbon atoms, the sum of the carbon number of R1 and R2 being at most 28, to polyol alkyl ethers derived from compounds having at least three hydroxyl functionalities, not more than all but one hydroxyl functionality being replaced by a moiety of the general formula (VIII) to the use of these polyol alkyl ethers as surfactants and to laundry detergents and cleaning compositions comprising these polyol alkyl ethers.
-
-
-
-
-
-
-
-
-
Search Results
51
records
(took 0.023 seconds)
