公开(公告)号：DE50002226D1

公开(公告)日：2003-06-18

申请号：DE50002226

申请日：2000-12-22

Applicant: BASF AG

Inventor： WULFF CHRISTIAN ,  ORSTEN STEFAN ,  OFTRING ALFRED

IPC: C07F9/38 ,  C07F9/40

Abstract: The present invention relates to a process for the preparation of N-phosphonomethylglycine by reacting a hexahydrotriazine derivative with a triacyl phosphite. The process gives N-phosphonomethylglycine in high yield and in a simple and inexpensive manner.

公开(公告)号：DE59808082D1

公开(公告)日：2003-05-28

申请号：DE59808082

申请日：1998-08-17

Applicant: BASF AG

Inventor： RAHM RAINER ,  GREINDL THOMAS ,  OFTRING ALFRED ,  OETTER GUENTER ,  DETERING JUERGEN ,  BRAUN GEROLD

IPC: C07C229/08 ,  C07C229/16 ,  C07C253/00 ,  C07C255/25 ,  C07D233/72 ,  C07D233/74

Abstract: A process for preparing compounds of the formula IIb where R is C6-C30-alkyl or C6-C30-alkenyl, which may additionally have upto 5 hydroxyl groups, formyl groups, C1-C4-alkoxy groups, phenoxy groups or C1-C4-alkoxycarbonyl groups as substituents and may be interrupted by upto 5 nonadjacent oxygen atoms, or alkoxylate groups of the formula -(CH2)k-O-(A1O)m-(A2O)n-Y where A1 and A2 are, independently of one another, 1,2-alkylene groups having 2 to 4 carbon atoms, Y is hydrogen, C1-C12-alkyl, phenyl or C1-C4-alkoxycarbonyl, and k is 1, 2 or 3, and m and n are each numbers from 0 to 50, and the total of m+n must be at least 4,by reacting iminodiacetonitrile with aldehydes of the formula R-CHO and HCN or alkali metal cyanides, the process being carried outa) in the absence of an organic solvent and in the presence of a Lewis or Brönsted acid, orb) in the presence or absence of an organic solvent and in the presence of an emulsifier, orc) in the presence or absence of an organic solvent and under a pressure in the range from 1 to 40 bar.

公开(公告)号：AT240337T

公开(公告)日：2003-05-15

申请号：AT00993613

申请日：2000-12-22

Applicant: BASF AG

Inventor： WULFF CHRISTIAN ,  ORSTEN STEFAN ,  OFTRING ALFRED

IPC: C07F9/38 ,  C07F9/40

Abstract: The present invention relates to a process for the preparation of N-phosphonomethylglycine by reacting a hexahydrotriazine derivative with a triacyl phosphite. The process gives N-phosphonomethylglycine in high yield and in a simple and inexpensive manner.

公开(公告)号：DE10130134A1

公开(公告)日：2003-01-02

申请号：DE10130134

申请日：2001-06-22

Applicant: BASF AG

Inventor： WULFF CHRISTIAN ,  ORSTEN STEFAN ,  OFTRING ALFRED

IPC: C07F9/38 ,  C07F9/40

Abstract: The invention relates to a method for producing alpha -aminophosphonic acids, by reacting a hexahydro triazine derivative with a triorganyl phosphate. The inventive method includes a phosphono compound as an intermediate step, said phosphono compound being hydrolysed into alpha -aminophosphonic acid. The invention also relates to said phosphono compound and the method for the production thereof. The inventive method enables alpha -aminophosphonic acids to be produced in a simple and economical manner as well as ensuring a high yield and purity.

公开(公告)号：MXPA02006081A

公开(公告)日：2002-12-09

申请号：MXPA02006081

申请日：2000-12-22

Applicant: BASF AG

Inventor： WULFF CHRISTIAN ,  ORSTEN STEFAN ,  OFTRING ALFRED

IPC: C07F9/38 ,  C07F9/40

Abstract: La invencion se refiere a un metodo para la produccion de N-fosfonometilglicina, mediante la reaccion de un derivado de hexahidrotrizina con un triacilfosfito. El metodo produce N- fosfonometilglicina en un modo sencillo y eficaz en costo y con un alto rendimiento.

公开(公告)号：AT226624T

公开(公告)日：2002-11-15

申请号：AT97914305

申请日：1997-03-25

Applicant: BASF AG

Inventor： WEHLAGE THOMAS ,  BOECKH DIETER ,  BERTLEFF WERNER ,  OFTRING ALFRED

IPC: C11D3/30 ,  C11D3/39 ,  C11D3/395

公开(公告)号：ES2151551T3

公开(公告)日：2001-01-01

申请号：ES94920434

申请日：1994-06-07

Applicant: BASF AG

Inventor： SCHNEIDER JUERGEN ,  POITHOFF-KARL BIRGIT ,  KUD ALEXANDER ,  BAUR RICHARD ,  OFTRING ALFRED ,  GREINDL THOMAS

IPC: C07D307/54 ,  A23C7/02 ,  A61K8/44 ,  A61Q11/00 ,  C07B61/00 ,  C07C227/00 ,  C07C227/02 ,  C07C227/18 ,  C07C227/26 ,  C07C229/16 ,  C07C229/26 ,  C07C229/30 ,  C07C229/34 ,  C07C229/36 ,  C07C255/24 ,  C07C255/25 ,  C07D207/337 ,  C07D211/74 ,  C07D213/55 ,  C07D263/32 ,  C07D277/30 ,  C07D307/24 ,  C07D333/24 ,  C11D3/33 ,  C11D11/00 ,  C11D17/06 ,  D06L1/14 ,  D06L3/02 ,  D06L4/12 ,  D06L4/30 ,  D06M11/40 ,  D21C9/10 ,  D21C9/16 ,  G03C5/305 ,  G03C5/38 ,  G03C5/44 ,  G03C7/42

Abstract: Use of glycine-N,N-diacetic acid derivs. of formula (I) is claimed as complex formers for alkaline earth or heavy metals. R = 1-20C alkyl, 2-20C alkenyl or -A.CH(COOM).N(CH2COOM)2; A = 1-12C alkylene or a chemical bond; M = H, alkali metal or opt. substd. ammonium. The use of ~a-alanine-N,N-diacetic acids as builders in textile-washing powders or as Ca sequestrants in oral hygiene compsns. is specifically excluded. Also claimed are 2-alkylglycine-N,N-diacetonitriles or 2-alkylglycinenitrile -N,N-diacetonitriles (where alkyl = 1-20C alkyl or 2-20 C alkenyl); and cpds. of formula (II). X = carboxylic acid or nitrile function. Cpds. of formula (I) are new except when R = 1-3C alkyl and A = chemical bond.

公开(公告)号：ES2124037T3

公开(公告)日：1999-01-16

申请号：ES95943187

申请日：1995-12-22

Applicant: BASF AG

Inventor： WEHLAGE THOMAS ,  SCHROEDER ULRICH ,  OFTRING ALFRED

IPC: C07C45/46 ,  C07C45/64 ,  C07C45/72 ,  C07C47/57 ,  C07C49/217 ,  C07C49/248 ,  C07C49/255 ,  C07C49/82 ,  C07C49/83 ,  C07C49/84 ,  C07C69/738 ,  C07C235/78 ,  C07C235/80 ,  C07C255/25 ,  C07C255/36 ,  C07C255/41 ,  C07D311/08 ,  C07D311/16 ,  C25D3/02 ,  C25D3/22 ,  C25D3/32 ,  C25D3/56

Abstract: PCT No. PCT/EP95/05090 Sec. 371 Date Oct. 6, 1997 Sec. 102(e) Date Oct. 6, 1997 PCT Filed Dec. 22, 1995 PCT Pub. No. WO96/20152 PCT Pub. Date Jul. 4, 1996Salts of aromatic hydroxy compounds are used as brighteners in acidic electroplating baths. Furthermore, acidic electroplating baths for the electrolytic deposition of metallic layers onto shaped articles comprise, as brighteners, at least one novel salt of an aromatic hydroxy compound. Finally, shaped articles are electroplated by a process using the novel acidic electroplating baths.

公开(公告)号：DE59304432D1

公开(公告)日：1996-12-12

申请号：DE59304432

申请日：1993-04-01

Applicant: BASF AG

Inventor： WOLF GERHARD ,  OFTRING ALFRED ,  SCHUH GEORG ,  WOLF HELMUT ,  ALT RUDOLF ,  BECHTOLSHEIMER HANS-HEINRICH ,  HERTEL DIETER

IPC: C07H15/04

Abstract: PCT No. PCT/EP93/00791 Sec. 371 Date Sep. 15, 1994 Sec. 102(e) Date Sep. 15, 1994 PCT Filed Apr. 1, 1993 PCT Pub. No. WO93/21196 PCT Pub. Date Oct. 28, 1993The preparation of alkyl glycosides by reaction of aqueous glycoses having a water content of 10-80% by weight with aliphatic primary alcohols having from 5 to 30 C atoms is described, in which (a) the alcohols and the glycoses are employed in a molar ratio of 2:1 to 10:1, (b) 0.1-5% by weight, based on the amount of the glycoses employed, of the acidic form of an anionic surfactant is used as the acidic catalyst having emulsifying properties, (c) 1-30% by weight, based on the amount of the glycoses employed, of alkyl glycosides is used as a further emulsifier, (d) the aqueous glycose is preheated to 50 DEG -90 DEG C. and the preheated aqueous solution of the glycose is metered with effective mixing into the reaction mixture of alcohol, acidic catalyst and emulsifier in such a manner that an emulsion is formed, (e) the reaction is carried out at from 100 DEG to 150 DEG C. and from 10 to 100 mbar, the water introduced into the reaction mixture and the water formed by the reaction being continuously removed by distillation, (f) after the reaction has ended, the acidic catalyst is neutralized by addition of a base such that the resulting mixture has a pH of 8-10, then (g) the excess alcohol is removed by distillation at from 0.01 to 10 mbar down to a residual content of less than 5% by weight, based on the amount of alkyl glycoside present, and (h) the reaction mixture is bleached at pH 8-10 after conversion into an aqueous paste having a content of from 30 to 70% by weight of alkyl glycoside using a compound eliminating active oxygen.

公开(公告)号：ES2085774T3

公开(公告)日：1996-06-01

申请号：ES93909543

申请日：1993-05-05

Applicant: BASF AG

Inventor： BURKHART BERND ,  OFTRING ALFRED ,  WIDDER RUDI ,  SCHROEDER ULRICH

IPC: C07D215/10 ,  C07D213/20 ,  C07D217/10 ,  C23C18/00 ,  C25D3/12

Abstract: PCT No. PCT/EP93/01090 Sec. 371 Date Oct. 19, 1994 Sec. 102(e) Date Oct. 19, 1994 PCT Filed May 5, 1993 PCT Pub. No. WO93/23377 PCT Pub. Date Nov. 25, 1993A process for the preparation of N-allyl compounds of the general formula I I in which denotes a nitrogen-containing heterocyclic compound, R1, R3, and R4 independently denote hydrogen or C1-C4 alkyl, R2 denotes hydrogen or methyl, n is equal to 1, 2, 3, or 4, and X denotes a water-solubilizing anion, wherein a compound of formula II II is caused to react, in aqueous medium, with a compound of formula III III in which A denotes a radical which can be eliminated as an anion. The compounds produced by the process of the invention are very well suited for use as brighteners in nickel electroplating.