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    HETEROPHASIC PROPYLENE COPOLYMERS
    21.
    发明申请
    HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开

    公开(公告)号：WO2018104092A1

    公开(公告)日：2018-06-14

    申请号：PCT/EP2017/080509

    申请日：2017-11-27

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： CATHELIN, Caroline ,  MASSARI, Paola ,  CAVALIERI, Claudio ,  CIARAFONI, Marco ,  PANTALEONI, Roberto

    IPC: C08L23/12

    Abstract: A film comprising a polypropylene composition comprising: A) from 50 wt% to 90 wt%; of a propylene homopolymer; B) from 10 wt% to 50wt%; of a copolymer of propylene with from 30.0 wt% to 70.0wt%, of ethylene derived units; the sum of the amount of component A) and B) being 100; the composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 2.2 and 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) from 0.5 to 50 g/10 min; iii) a xylene soluble fraction ranging from 20 wt% to 50 wt%; the polypropylene composition being obtained by a two steps polymerization process wherein the catalyst system contains bismuth.

    COMPOSITION COMPRISING PROPYLENE-ETHYLENE-1-BUTENE TERPOLYMERS
    23.
    发明申请
    COMPOSITION COMPRISING PROPYLENE-ETHYLENE-1-BUTENE TERPOLYMERS 审中-公开
    包含丙烯 - 乙烯-1-丁烯共聚物的组合物

    公开(公告)号：WO2017021138A1

    公开(公告)日：2017-02-09

    申请号：PCT/EP2016/067144

    申请日：2016-07-19

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： FELISATI, Andrea ,  FERRARO, Angelo ,  MASSARI, Paola ,  CIARAFONI, Marco ,  CAVALIERI, Claudio ,  PANTALEONI, Roberto

    IPC: B32B27/32 ,  C08J5/18 ,  C08L23/14

    CPC classification number: C08L23/14 ,  B32B7/04 ,  B32B27/08 ,  B32B27/16 ,  B32B27/32 ,  B32B2307/514 ,  B32B2307/518 ,  B32B2307/542 ,  B32B2307/548 ,  C08L23/142 ,  C08L2203/162 ,  C08L2205/025 ,  C08L2308/00 ,  C08F210/06 ,  C08F4/6492 ,  C08F2/001

    Abstract: A polyolefin composition comprising: A) from 19 wt% to 50 wt% of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt% to 6.0 wt%; B) from 50 wt% to 81 wt% of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt% and 6.0 wt% and 1-butene derived units content of between 4.8 wt% and 12.4 wt%; the sum of the amount of component A) and B) being 100; the composition being characterized by the following features: - the ratio C2wt%/C4wt% is comprised between 0.22 and 3.0, where C2wt% is the weight per cent of ethylene derived units and C4wt% is the weight per cent of 1-butene derived units; - the content of xylene soluble fraction at 25°C is comprised between 2 and 15 wt%; - molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; recoverable compliance at 200°C having a maximum value between 800 and 1200 seconds lower than 65x10 -5 Pa -1 .

    Abstract translation: 一种聚烯烃组合物，其包含：A）19重量％至50重量％的乙烯衍生单元含量为1.5重量％至6.0重量％的丙烯乙烯共聚物; B）50重量％至81重量％的乙烯衍生单元含量为1.5重量％至6.0重量％，1-丁烯衍生单元含量为4.8重量％至12.4重量％的丙烯乙烯1-丁烯三元共聚物; 组分A）和B）的量的总和为100; 该组合物的特征在于以下特征： - C2wt％/ C4wt％的比例在0.22和3.0之间，其中C2wt％是乙烯衍生单元的重量百分比，C4wt％是1-丁烯衍生单元的重量百分比 ; - 二甲苯可溶成分在25℃下的含量为2至15重量％; - 分子量分布（MWD），以Mw / Mn表示，大于4.0; 在200℃的可恢复顺应性，其最大值低于65×10 -5 Pa -1 -100秒。

    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS
    24.
    发明申请
    PROCESS FOR THE PREPARATION OF POROUS PROPYLENE POLYMERS 审中-公开
    制备多孔丙烯聚合物的方法

    公开(公告)号：WO2015059117A1

    公开(公告)日：2015-04-30

    申请号：PCT/EP2014/072501

    申请日：2014-10-21

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： GADDI, Benedetta ,  BOCCHINO, Marco ,  COLLINA, Gianni ,  FUSCO, Ofelia ,  GUIDOTTI, Simona ,  MAZZUCCO, Antonio ,  PANTALEONI, Roberto ,  PIEMONTESI, Fabrizio

    IPC: C08F10/06 ,  C08F210/06

    CPC classification number: C08F210/02 ,  C08F10/06 ,  C08J9/0052 ,  C08J9/0066 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6545

    Abstract: Process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55°C; optionally, ii) pre-polymerizing with one or more olefins of formula CH 2 =CHR, where R is H or a C 1 -C 10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C 4 -C 10 alpha olefins producing said porous propylene (co)polymer.

    Abstract translation: 在催化剂体系存在下进行的多孔丙烯的制备方法，该催化剂体系包含（a）含有至少两种电子给体化合物的齐格勒 - 纳塔催化剂，其中一种催化剂体系以50至90摩尔％的量存在， 相对于供体的总量，选自琥珀酸盐，另一种选自1,3-二醚，（b）烷基铝，包括以下步骤：i）使催化剂组分（a）和（b）接触一段时间 时间为1至60分钟，温度范围为35至55℃; 任选地，ii）使用一种或多种式CH 2 = CHR的烯烃进行预聚合，其中R是H或C1-C10烃基，直至每克固体催化剂组分约0.1至约1000g的聚合物的形成量 （一个）; 和iii）在少量乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯，生产所述多孔丙烯（共）聚合物。

    PROCESS FOR GAS-PHASE POLYMERIZATION OF OLEFINS
    27.
    发明申请
    PROCESS FOR GAS-PHASE POLYMERIZATION OF OLEFINS 审中-公开

    公开(公告)号：WO2019057595A1

    公开(公告)日：2019-03-28

    申请号：PCT/EP2018/074705

    申请日：2018-09-13

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MAZZUCCO, Antonio ,  BALESTRA, Enrico ,  PANTALEONI, Roberto ,  TARTARI, Davide ,  RINALDI, Riccardo

    IPC: C08F2/34 ,  C08F2/00 ,  C08F10/06 ,  C08F4/651 ,  C08F4/654

    Abstract: A process is disclosed for the polymerization of olefins in gas phase carried out in a reactor having two interconnected polymerization zones, a first zone (riser) and a second zone (downcomer), wherein the growing polymer particles: a) flow through the riser under fast fluidization conditions established by feeding a mixture of gas and liquid; b) leave the riser and enter the downcomer, through which they flow downward in a densified form; c) leave the downcomer and are reintroduced into the riser, thus establishing a circulation of polymer between the riser and the downcomer; and wherein the reactor is operated at a temperature which is between 0° C and 5° C above the dew point of the riser gas at the operating pressure, so that in the riser, besides the growing polymer particles and gas flow, an amount of liquid is also present.

    NUCLEATED PROPYLENE POLYMER COMPOSITION
    28.
    发明申请
    NUCLEATED PROPYLENE POLYMER COMPOSITION 审中-公开
    成核丙烯聚合物组合物

    公开(公告)号：WO2018069127A1

    公开(公告)日：2018-04-19

    申请号：PCT/EP2017/075288

    申请日：2017-10-05

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MASSARI, Paola ,  FELISATI, Andrea ,  IZZI, Marco ,  CAVALIERI, Claudio ,  CIARAFONI, Marco ,  GUERRA, Silvia ,  PANTALEONI, Roberto ,  MALIZIA, Federica

    IPC: C08L23/12

    Abstract: A nucleated propylene polymer composition comprising: A) from 77 wt% to 91 wt%, of a propylene homopolymer having a fraction insoluble in xylene at 25 °C higher than 95 %; B) from 9 wt % to 23 wt%, of a copolymer of propylene with from 28.0 wt% to 42.0 wt% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 1.0 dl/g and 1.9 dl/g, a fraction soluble in xylene at 25 °C comprised between 9.0 wt% and 21.0 wt%, a total melt flow rate (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) comprised between 1.5 and 5 g/10 min and the value of the relation (I): 22.5+0.2*MFR-1.2*Xs+0.2*IV is higher than 5.9; wherein MFR is the melt flow rate of the nucleated composition (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load); IV is the intrinsic viscosity of the fraction soluble in xylene at 25 °C; and Xs is the fraction soluble in xylene at 25°C; wherein the amount of A+B is equal to 100 wt% and wherein the nucleated agent is selected from the group consisting of aromatic or aliphatic carboxylic acids, aromatic metal phosphates, sorbitol derivatives and talc.

    Abstract translation: 1.一种成核丙烯聚合物组合物，其包含：A）77重量％至91重量％的丙烯均聚物，其在25℃下具有不溶于二甲苯的部分，其含量高于95％; B）9重量％至23重量％的丙烯与28.0重量％至42.0重量％的乙烯衍生的单元的共聚物; 所述组合物在25℃下的可溶于二甲苯的部分的特性粘度为1.0dl / g至1.9dl / g，在25℃下可溶于二甲苯的部分为9.0wt％至21.0wt％， 总熔体流动速率（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg载荷）为1.5至5g / 10min，并且关系式（I）的值为：22.5±0.2 * MFR- 1.2 * Xs + 0.2 * IV高于5.9; 其中MFR是成核组合物的熔体流动速率（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg载荷）; IV是在25℃可溶于二甲苯的部分的特性粘度; Xs是在25℃可溶于二甲苯的部分; 其中A + B的量等于100wt％，并且其中成核剂选自芳族或脂族羧酸，芳族金属磷酸盐，山梨糖醇衍生物和滑石。

    HETEROPHASIC PROPYLENE COPOLYMERS
    29.
    发明申请
    HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开
    杂原子丙烯共聚物

    公开(公告)号：WO2017076701A1

    公开(公告)日：2017-05-11

    申请号：PCT/EP2016/075684

    申请日：2016-10-25

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MASSARI, Paola ,  CATHELIN, Caroline ,  MORINI, Giampiero ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni ,  CIARAFONI, Marco ,  CAVALIERI, Claudio ,  PANTALEONI, Roberto ,  GRAZZI, Michele

    IPC: C08L23/12 ,  C08L23/08

    CPC classification number: C08L23/12 ,  C08F210/06 ,  C08L2207/02 ,  C08L2308/00 ,  C08L23/16 ,  C08F10/06 ,  C08F2/001 ,  C08F4/6492 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F4/6574

    Abstract: A polypropylene composition comprising: A) from 50 wt% to 90 wt%; of a propylene homopolymer; B) from 10 wt% to 50wt%; of a copolymer of propylene with from 30.0 wt% to 70.0wt%, of ethylene derived units; the sum of the amount of component A) and B) being 100; the composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 2.2 and 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 20 wt% to 50 wt%; the polypropylene composition being obtained by a two steps polymerization process wherein the catalyst system contains bismuth.

    Abstract translation: 1.一种聚丙烯组合物，其包含：A）50重量％至90重量％; 的丙烯均聚物; B）10重量％至50重量％; 的丙烯与30.0重量％至70.0重量％的乙烯衍生的单元的共聚物; 组分A）和B）的量的总和为100; 该组合物具有：i）在25℃下可溶于二甲苯的部分的特性粘度为2.2至4.0dl / g; ii）0.5至100g / 10min的MFR L（根据ISO 1133的熔体流动速率，条件L，即230℃和2.16kg载荷）; iii）20wt％至50wt％的二甲苯可溶部分; 该聚丙烯组合物通过其中催化剂体系含有铋的两步聚合方法获得。

    LLDPE-CONTAINING IMPACT MODIFIER POLYOLEFIN COMPOSITION
    30.
    发明申请
    LLDPE-CONTAINING IMPACT MODIFIER POLYOLEFIN COMPOSITION 审中-公开
    含LLDPE的冲击改性剂聚烯烃组合物

    公开(公告)号：WO2016207236A1

    公开(公告)日：2016-12-29

    申请号：PCT/EP2016/064453

    申请日：2016-06-22

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： CAVALIERI, Claudio ,  GRAZZI, Michele ,  PANTALEONI, Roberto

    IPC: C08L23/16

    CPC classification number: C08L23/20 ,  C08F210/16 ,  C08L23/16 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2308/00 ,  C08L2310/00 ,  C08L2314/02 ,  C08L23/0815 ,  C08L23/12 ,  C08F210/06 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2/001 ,  C08F110/06 ,  C08F4/6492

    Abstract: Polyolefin compositions comprising: (A) 5-35% by weight of a propylene-based polymer containing 90% by weight or more of propylene units and containing 10% by weight or less of a fraction soluble in xylene at 25 °C (XS A ), both the amount of propylene units and of the fraction XS A being referred to the weight of (A); (B) 25-50% by weight, of a copolymer of ethylene and a C 3 -C 8 alpha-olefin containing from 0.1% to 15% by weight of alpha-olefin units and containing 75% by weight or less of a fraction soluble in xylene at 25 °C (XS B ), both the amount of ethylene units and of the fraction XS B being referred to the weight of (B); and (C) 30-60% by weight, of a copolymer of ethylene and propylene containing from 45% to 75% by weight of ethylene units and containing from 55% to 95% by weight, of a fraction soluble in xylene at 25 °C (XS c ), both the amount of ethylene units and of the fraction XS c being referred to the weight of (C).

    Abstract translation: 聚烯烃组合物，其包含：（A）5-35重量％的含有90重量％以上丙烯单元且含有10重量％以下的在25℃下可溶于二甲苯的馏分（XSA）的丙烯类聚合物， ，丙烯单元的量和馏分XSA的量均称为（A）的重量; （B）25-50重量％的乙烯与含有0.1重量％至15重量％的α-烯烃单元并含有75重量％以下的可溶于乙烯的馏分的C 3 -C 8α-烯烃的共聚物 25℃下的二甲苯（XSB），乙烯单元的量和XSB的分数与（B）的重量相同; 和（C）30-60重量％的乙烯和丙烯的共聚物，其含有45重量％至75重量％的乙烯单元，并且含有55重量％至95重量％的在25℃下可溶于二甲苯的馏分 C（XSc），乙烯单元的量和XSc的分数称为（C）的重量。

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