公开(公告)号：DE10156685A1

公开(公告)日：2003-05-28

申请号：DE10156685

申请日：2001-11-17

Applicant: BASF AG

Inventor： FUNKE FRANK ,  STEINBRENNER ULRICH ,  BOEHLING RALF ,  RUDOLF PETER ,  BREUER KLAUS ,  HIBST HARTMUT

IPC: C07C209/54 ,  C07C209/60 ,  C07C209/64 ,  C07C211/06

Abstract: The invention relates to a method for producing monoisopropylamine (MIPA). According to the inventive method, propine and/or propadiene are reacted with MIPA under hydroamination conditions. The hydroamination product(s) obtained are then reacted with ammonia under transalkylation and hydrogenation conditions.

公开(公告)号：DE10155524A1

公开(公告)日：2003-05-22

申请号：DE10155524

申请日：2001-11-12

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  FUNKE FRANK ,  BOEHLING RALF

IPC: C07C209/62 ,  C07B61/00 ,  C07C209/60 ,  C07C209/86 ,  C07C211/03 ,  C07C211/04 ,  C07C211/05 ,  C07C211/07 ,  C07C211/08 ,  B01J31/00 ,  C07C209/54

Abstract: The invention concerns a method for producing ethylamines and butylamines and ethylamine and butylamine mixtures. Said method comprises the following steps: (i) hydroamination of butadiene and ethylene with a monoalkylamine and/or dialkylamine, alkyl may be substituted by ethyl and/or butyl, in the presence of an alkali metal amide as catalyst; (ii) isomerization of the amine obtained during hydroamination (i), optionally after (iia) separating into specific fractions and/or (iib) in hydrogenation conditions and/or (iic) in the presence of ammonia; (iii) separating the product mixture obtained, isolating the desired amine produced and recycling to step (i) the appropriate amine as educt.

公开(公告)号：DE10207747A1

公开(公告)日：2002-09-05

申请号：DE10207747

申请日：2002-02-22

Applicant: BASF AG

Inventor： FUNKE FRANK ,  BREUER KLAUS ,  KRATZ DETLEF ,  BOEHLING RALF ,  HORN HELMUT

IPC: C07C67/44 ,  C07C67/00 ,  C07C69/28

Abstract: Production of 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate or a 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate-containing mixture comprises heating isobutyraldehyde in the presence of a basic catalyst to 60-130 deg C, followed by heating the mixture to 140-250 deg C and optionally isolating the 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate from the mixture.

公开(公告)号：CA2288520A1

公开(公告)日：2000-05-11

申请号：CA2288520

申请日：1999-11-05

Applicant: BASF AG

Inventor： ZEHNER PETER ,  BOEHLING RALF ,  ARON MAIK

IPC: C07C31/12 ,  C07C41/06 ,  C07C43/15 ,  C07C45/51 ,  C07C47/02 ,  C07C43/166 ,  C07C43/215

Abstract: Described is a process for preparing substituted butenes of the formula I and/or II, (see formula I and/or II) where the radical R is unsubstituted or mono- or di-C1-C10-alkoxy-substituted or mono- or dihydroxy-substituted C2-C20-alkyl or alkenyl or is C6-C10-aryl, C7-C11-aralkyl or methyl by reacting 1,3-butadiene with an alcohol of the formula ROH in which R is as defined in the presence of an acidic particulate catalyst insoluble in the reaction medium, which involves contacting the butadiene, the alcohol and the catalyst in a fluidized bed reactor which is flow-approached from below and is operated at above the loosening paint.

公开(公告)号：DE50308660D1

公开(公告)日：2008-01-03

申请号：DE50308660

申请日：2003-07-30

Applicant: BASF AG

Inventor： ADAMI CHRISTOPH ,  KARL JOERN ,  HAUK ALEXANDER ,  BOEHLING RALF ,  PASTRE JOERG ,  LENZ ROBERT

IPC: A23K1/16 ,  C07C51/09 ,  A01N1/00 ,  A01N3/00 ,  A61K31/19 ,  A61P3/00 ,  B01D9/02 ,  C07C51/41 ,  C07C53/02 ,  C07C53/06

Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.

公开(公告)号：DE102005051974A1

公开(公告)日：2007-05-03

申请号：DE102005051974

申请日：2005-10-31

Applicant: BASF AG

Inventor： LANG NEVEN ,  BOEHLING RALF ,  STAMMER ACHIM ,  OLDENBURG JAN ,  SIEGERT MARKUS ,  STROEFER ECKHARD

IPC: C07D323/06 ,  C07D317/12

Abstract: Preparation of trioxane and at least a comonomer for the preparation of (co)polymer on trioxane basis, comprises (a) converting formaldehyde and at least a co-monomer educt to trioxane and co-monomer in an aqueous solution to obtain a reaction mixture; (b) distilling the reaction mixture in a first distillation step at a first pressure to obtain stream (B1) and a stream (B2); and (c) distilling the stream (B1) in a second distillation step to obtain stream (C1) containing trioxane, co-monomer and water, and a product stream (C2) containing co-monomer and trioxane. Preparation of trioxane and at least a co-monomer for the preparation of (co)polymer on trioxane basis, comprises: (a) converting formaldehyde and at least a co-monomer educt to trioxane and co-monomer in an aqueous solution to obtain a reaction mixture containing trioxane, co-monomer, formaldehyde, water and optionally co-monomer educt, by synthesis step; (b) distilling the reaction mixture in a first distillation step at a first pressure to obtain stream (B1) enriched with trioxane and comonomer, and a stream (B2) containing water, formaldehyde and optionally comonomer-educt; and (c) distilling the stream (B1) in a second distillation step at a pressure above the pressure of the first distillation step to obtain stream (C1) containing trioxane, co-monomer and water, and a product stream (C2) containing co-monomer and trioxane.

公开(公告)号：AT346034T

公开(公告)日：2006-12-15

申请号：AT02798307

申请日：2002-11-08

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  BOEHLING RALF ,  FUNKE FRANK ,  HARDER WOLFGANG

IPC: B01J31/26 ,  B01J31/02 ,  C07B61/00 ,  C07C209/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/35 ,  C07C211/65 ,  C07F1/00 ,  C07F1/02 ,  C07F1/04 ,  C07F1/06

Abstract: A process for preparing dialkylamides of the alkali metals by reacting the corresponding dialkylamine with the corresponding alkali metal in the presence of an electron-donating substance selected from the group consisting of 1,3-butadiene, isoprene, naphthalene and styrene with formation of small amounts of butenyldialkylamine comprises suspending the corresponding alkali metal in a solvent and subsequently adding dialkylamine and electron-donating substance in such a way that the dialkylamine is present in an amount of up to 45% by weight, preferably up to 25% by, weight, in particular up to 15% by weight, and the butadiene is present in an amount of up to 5% by weight, preferably up to 3% by weight, in particular up to 1.5% by weight.

公开(公告)号：PL375582A1

公开(公告)日：2005-11-28

申请号：PL37558203

申请日：2003-07-30

Applicant: BASF AG

Inventor： ADAMI CHRISTOPH ,  KARL JOERN ,  HAUK ALEXANDER ,  BOEHLING RALF ,  PASTRE JOERG ,  LENZ ROBERT

IPC: A23K1/16 ,  A01N1/00 ,  A01N3/00 ,  A61K31/19 ,  A61P3/00 ,  B01D9/02 ,  C07C51/09 ,  C07C51/41 ,  C07C53/06 ,  C07C53/02

Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.

公开(公告)号：ZA200407045B

公开(公告)日：2005-09-12

申请号：ZA200407045

申请日：2004-09-03

Applicant: BASF AG

Inventor： FUNKE FRANK ,  BOEHLING RALF ,  STEINBRENNER ULRICH ,  MUELLER GUENTER ,  BENISCH CHRISTOPH ,  GAUS GUENTER

IPC: C07B61/00 ,  C07C209/60 ,  C07C211/05 ,  C07C211/08 ,  C07C

Abstract: The present invention describes a process for the preparation of ethyldimethylamine and triethylamine with the following steps: (i) reaction of a mixture of diethylamine and dimethylamine with ethylene in the presence of a catalyst from the group of alkali metal dimethylamides, alkali metal diethylamides and alkali metal hydrides (ii) removal of the catalyst (iii) distillation separation of the resulting mixture in triethylamine and ethyldimethylamine and optionally diethylamine and dimethylamine (iv) optional return of the catalyst and of the starting amines to the reaction. The process according to the invention permits the coproduction of ethyldimethylamine and diethylamine in a simple process.

公开(公告)号：DE10335967A1

公开(公告)日：2005-02-24

申请号：DE10335967

申请日：2003-08-06

Applicant: BASF AG

Inventor： BOEHLING RALF ,  CRONE SVEN ,  FUNKE FRANK ,  OLBERT GERHARD

IPC: B01J8/02 ,  B01J8/06 ,  B01J19/24 ,  C07C45/35 ,  C07C51/25 ,  B01J8/00

Abstract: A gas phase oxidation reactor has one or more endothermic or exothermic stages that take place in the presence of a heterogenic particle catalyst. The catalyst comprises one or more stacked perforated panel(s) (1) with a coefficient of heat conductivity of greater than 30 W/m/K. The perforations extend in-line through the stacked sheet metal plates and hold the catalyst particles. The stacked plates are surrounded around the edges by a sleeve separating the gas inlet zone (4) from the gas outlet zone (5). The gas inlet zone (4) from the gas outlet zone (5) are linked only via the perforations (1) in the panels. The panels are sheet metal (e.g. aluminum, copper, silver or their alloys), ceramic or graphite. The perforation diameter is less than 6 mm.