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公开(公告)号:DE2824975A1
公开(公告)日:1979-12-20
申请号:DE2824975
申请日:1978-06-07
Applicant: BASF AG
Inventor: GLASER KLAUS ING GRAD , STREIT WERNER DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , GOTSMANN GUENTHER DIPL CHEM DR
IPC: C23F1/44 , C23F3/00 , C23G1/00 , C09K13/00 , C23F1/00 , C23F11/14 , C25F1/00 , C25F3/00 , C25F5/00
Abstract: Water-sol., cross-linked, nitrogenous condensation prods. (I), the viscosity of which in aq. soln. increases with increase in temp. and falls again with decrease in temp., are prepd. by reacting (a) 0.8-30 pts. of a block copolymer of formula R-O-(CH2CH2O)x-(CH2CH(CH3)O)y-(CH2CH2O)x-R (II), in which R is H(OCH2C(CH2Cl)H-)n, with n = 0.75-3, -COCl or -CH2CH2Cl, x = 50-250, y = 20-100, and x:y = 6.5:1-1:15, with (b) 1 pt. of a cpd. with is not 4 basic NH gps. Reaction is in a polar solvent at 20 180 degrees C. (I) are used as additives in etching, polishing and de-metallisation baths. The surface of the treated metal is improved. Etching baths contg. H2SO4-H2O2 are more easily handled. In electrochemical polishing and burr-removal, (I) may (partly) replace H3PO4; disposal of waste water is then easier. The polishing and smoothing effect can be controlled by varying the temp. In de-metallisation, e.g. in removal of Cu, Ni, Cr, Zn, noble metals and alloys from substrates such as steel, brass, Zn castings or Al, addn. of (I) protects the substrate and regulates the attack by the soln. on increase in temp.
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公开(公告)号:DE2821626A1
公开(公告)日:1979-11-29
申请号:DE2821626
申请日:1978-05-18
Applicant: BASF AG
IPC: C07D487/04 , C11D3/00 , C11D3/28 , C07D487/02
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公开(公告)号:DE2719978A1
公开(公告)日:1978-11-16
申请号:DE2719978
申请日:1977-05-04
Applicant: BASF AG
Inventor: OPPENLAENDER KNUT DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , BUETTNER EGON , SLOTMAN WILHELMUS , SCHWARTZ ERICH DIPL CHEM DR , MOHR RUDOLF DIPL CHEM DR
Abstract: Petroleum demulsifiers which contain, as the active ingredients, oxyalkylated isoalkylphenol-formaldehyde resins and oxyalkylated polyalkylenepolyamines.
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公开(公告)号:DE2521859A1
公开(公告)日:1976-12-02
申请号:DE2521859
申请日:1975-05-16
Applicant: BASF AG
Inventor: DOCKNER TONI DIPL CHEM DR , WALLIS ALBRECHT H DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , THOMAS RAINER DIPL CHEM DR , HERZOG REINHARD DIPL CHEM DR
IPC: C07D203/10 , C07D203/08 , C14C9/00 , D06M13/48
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公开(公告)号:DE2421405A1
公开(公告)日:1975-11-13
申请号:DE2421405
申请日:1974-05-03
Applicant: BASF AG
IPC: D06M13/148 , D06M13/388 , D06M23/10 , D06M13/40 , D06M13/16 , D06M13/18
Abstract: Mixt. of useful in textile reviving compsns. consists of (a) 1 part amine oxide of formula R'CONH-(CH2)n-NR2R3 right arrow O (1) (where R1 is satd. or ethylenically unsatd. opt. OH-substd. 15-17C aliphatic gP. R2 and R3 are 1-3C aliphatic gps. and n is integer 2 to 5) and (b) 1-2 parts solvent of formula R4O(CHR5CHR6O)mH (II) where R4 is H or 1-4C alkyl, and R5 and R6 are H or Me, provided at least one is H, and m is 1 or 2). Mixt. is pref. used as an aq. soln. pref. contg. 15-25 wt. % (I) and 20-40 wt. % (II). Used for softening and anti-electrostatic finishing of textile fibres and fabrics, esp. acrylonitrile polymers but also polyesters and cotton. (I) and (II) are miscible with water in all proportions, conc. solns. are stable to storage and only need diluting with cold water, both anti-electrostatic and reviving effects are excellent.
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公开(公告)号:DE2316725A1
公开(公告)日:1974-11-07
申请号:DE2316725
申请日:1973-04-04
Applicant: BASF AG
Inventor: FUERST ERNST DR , GERENDAS JOZSEF DIPL CHEM DR , ROKOHL RUDOLF DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , HELFERT HERBERT DIPL CHEM DR
Abstract: Title cpds. of formula (I): (where R1 is opt. branched 1-6C alkyl opt. substd. by OH gps, or two R1 gps. together with the N atom form a 4-7C heterocycle; R2-R4 are each a cyclic, linear or branched, satd. or contg. an olefinic link 1-30C alkyl, opt. substd. by OH gps. and opt. interrupted by ether bridges, or a phenyl or benzyl gp. opt. substd. by Cl or 1-12C alkyl; R3 and R4 may also represent H or a pair of free electrons; R5 is H or 1-4C alkyl; Z is 2-6C alkylene, opt. substd. esp. by OH gps. or interrupted by either or ester gps; X- is an (in)organice anion; and these various anions may be the same or different; n is a whole no. 1-3), are prepd. by quaternising the corresp. unguaternised cpd. They are effective in amts. of 0.003-1.5 wt. % w.r.t. anionic polyacrylonitrile fibres.
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公开(公告)号:DE2916356A1
公开(公告)日:1980-11-13
申请号:DE2916356
申请日:1979-04-23
Applicant: BASF AG
Inventor: STREIT WERNER DIPL CHEM DR , FIKENTSCHER ROLF DIPL CHEM DR , MELZER JAROSLAV DIPL ING , SCHARF EMIL DIPL CHEM DR , KOLHAUPT REINHOLD DIPL CHEM DR
Abstract: Polyetheramine are prepd. by condensing di- or polyamines (I) contg. 2-10 N atoms wich chlorohydrin ethers (II) prepd. from 1 mol divalent 2-5C alcohol, the ethoxylated adduct contg. up to 18 ethylene oxide units, glycerol or polyglycerol contg. up to 15 glycerol units and 2-8 mol epichlorohydrin at 110-200 degrees C in polar, water miscile solvents in the absence or extensive exclusion of water, adding an alkali(ne earth) metal base to neutralise >=20% of the HCl formed by the condensn. and post-condensing (I) is used in an amt. of 0.6-2.5 mol per mol. chlorohydrin gp. in (II). The aids are prepd. withou the necessity of having to graft components used during the condensn. with ethylene imine.
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公开(公告)号:DE2831899A1
公开(公告)日:1980-02-07
申请号:DE2831899
申请日:1978-07-20
Applicant: BASF AG
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公开(公告)号:DE2658934A1
公开(公告)日:1978-07-06
申请号:DE2658934
申请日:1976-12-24
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF DIPL CHEM DR , GLASER KLAUS ING GRAD , GOTSMANN GUENTHER DIPL CHEM DR , STREIT WERNER DIPL CHEM DR
IPC: C25D3/22
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