公开(公告)号：CA2553249A1

公开(公告)日：2005-08-25

申请号：CA2553249

申请日：2005-02-08

Applicant: BASF AG

Inventor： URTEL HEIKO ,  HAUNERT ANDREA ,  ROESCH MARKUS ,  SCHUBERT MARKUS

IPC: C07C29/149 ,  C07B41/02 ,  C07B53/00 ,  C07C31/22 ,  C07C213/00 ,  C07C215/08 ,  C07C215/10 ,  C07C215/18 ,  C07C215/28 ,  C07D307/33

Abstract: The invention concerns a method for producing optically active hydroxy-, alkoxy-, amino-, alkyl-, aryl- or chlorine-substituted alcohols or hydroxycarboxylic acids having 3 to 25 carbon atoms or their acid derivative s or cyclization products by hydrogenating the correspondingly substituted optically active monocarboxylic acids or dicarboxylic acids or their acid derivatives in the presence of a catalyst whose active constituent consists of rhenium or contains rhenium and at least one additional element of atomic numbers 22 to 83, with the provisions that: a) the at least one additional element of atomic numbers 22 to 83 is not rhenium, and; b) when producing optically active 2-amino-, 2-chloro-, 2-hydroxy- and 2-alkoxy-1-alkanols by the catalytic hydrogenation of correspondingly optically active 2-amino-, 2- chloro-, 2-hydroxy- and 2-alkoxy carboxylic acids or their acid derivatives, the at least one additional element of atomic numbers 22 to 83 is not palladium nor platinum.

公开(公告)号：AU2003302024A1

公开(公告)日：2004-06-15

申请号：AU2003302024

申请日：2003-11-11

Applicant: BASF AG

Inventor： SIRCH TILMAN ,  HAUNERT ANDREA ,  FISCHER ROLF-HARTMUTH ,  KRUG THOMAS

IPC: C07C41/28 ,  C07C67/317

公开(公告)号：NO20076505A

公开(公告)日：2008-01-28

申请号：NO20076505

申请日：2007-12-19

Applicant: BASF AG

Inventor： STROFER ECKHARD ,  KARL JORN ,  TEBBEN GERD-DIETER ,  SCHELLING HEINER ,  PINKOS ROLF ,  HAUNERT ANDREA ,  EIERMANN MATTHIAS

IPC: C10L1/02 ,  C10L1/14 ,  C10L1/185 ,  C10L1/198 ,  C10L10/02 ,  C10L10/12

CPC classification number: C10L1/14 ,  C10G2300/1011 ,  C10G2300/307 ,  C10G2300/80 ,  C10L1/026 ,  C10L1/1616 ,  C10L1/1852 ,  C10L1/19 ,  C10L1/1985 ,  C10L10/02 ,  C10L10/12 ,  Y02E50/13 ,  Y02P30/20

公开(公告)号：DE502005001845D1

公开(公告)日：2007-12-13

申请号：DE502005001845

申请日：2005-07-07

Applicant: BASF AG

Inventor： HAUNERT ANDREA ,  PINKOS ROLF ,  KRUG THOMAS ,  SIRCH TILMAN ,  KOCH MICHAEL ,  TEBBEN GERD-DIETER

IPC: C07C29/145 ,  C07C29/149 ,  C07C31/20

Abstract: The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).

公开(公告)号：CA2581502A1

公开(公告)日：2006-05-04

申请号：CA2581502

申请日：2005-10-19

Applicant: BASF AG

Inventor： STROEFER ECKHARD ,  SCHELLING HEINER ,  HASSE HANS ,  BLAGOV SERGEJ ,  PINKOS ROLF ,  HAUNERT ANDREA ,  TEBBEN GERD-DIETER

IPC: C07C41/56 ,  C07C43/30 ,  C07C43/303 ,  C08G2/08

Abstract: A process for preparing polyoxymethylene dimethyl ether of the formula H 3 CO(CH 2 O) n CH 3 where n=2-10, in which methylal and trioxane are fed into a reactor and reacted in the presence of an acidic catalyst, wherein the amount of water introduced into the reaction mixture by methylal, trioxane and/or the catalyst is 4 are recycled into the reaction.

公开(公告)号：AU2003299298A1

公开(公告)日：2004-07-09

申请号：AU2003299298

申请日：2003-12-03

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  HAUNERT ANDREA ,  ROPER MICHAEL ,  SIRCH TILMAN ,  STUER WOLFRAM

IPC: C07C29/17 ,  C07C69/593 ,  C07C29/149 ,  C07C31/20 ,  C07C67/347

Abstract: Production of 1,6-hexanediol of purity at least 99.5 % comprises: (1) catalytically dimerizing a 1-8C acrylic acid ester in presence of rhodium compounds to a mixture mainly of 2- and 3-hexenedioic acid diesters; (2) hydrogenating the ester mixture in chromium-free mainly copper-containing catalysts; and (3) purifying the resulting diol mixture by fractional distillation.

公开(公告)号：AU2003283386A1

公开(公告)日：2004-06-15

申请号：AU2003283386

申请日：2003-11-11

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  SIRCH TILMAN ,  HAUNERT ANDREA

IPC: C07C29/149 ,  C07C31/20

公开(公告)号：NZ564408A

公开(公告)日：2009-12-24

申请号：NZ56440806

申请日：2006-06-26

Applicant: BASF AG

Inventor： TEBBEN GERD-DIETER ,  SCHELLING HEINER ,  STROFER ECKHARD ,  PINKOS ROLF ,  HAUNERT ANDREA ,  EIERMANN MATTHIAS ,  KARL JORN

IPC: C10L1/02 ,  C10L1/14 ,  C10L1/185 ,  C10L1/198 ,  C10L10/02 ,  C10L10/12

Abstract: Disclosed is a biodiesel fuel mixture having a cetane number of> 40, comprising a) from 5 to 90% by weight of biodiesel, b) from 0 to 94% by weight of diesel oil of fossil origin, c) from 1 to 20% by weight of a polyoxyalkylene dialkyl ether of the formula RO(CH2O)nR, in which R is an alkyl group having from 1 to 10 carbon atoms and n is from 2 to 10, and d) from 0 to 5% by weight of further additives. Also disclosed is the use of polyoxymethylene dialkyl ethers as defined above as an additive in biodiesel fuel mixtures with at least 1% by weight of biodiesel for increasing the cetane number.

公开(公告)号：MX2007015974A

公开(公告)日：2008-03-06

申请号：MX2007015974

申请日：2006-06-26

Applicant: BASF AG

Inventor： PINKOS ROLF ,  SCHELLING HEINER ,  STROFER ECKHARD ,  KARL JORN ,  HAUNERT ANDREA ,  TEBBEN GERD-DIETER ,  EIERMANN MATTHIAS

IPC: C10L1/02 ,  C10L1/14 ,  C10L1/185 ,  C10L1/198 ,  C10L10/02 ,  C10L10/12

Abstract: La invencion se refiere a una mezcla de combustibles biodiesel que tiene un indice de cetano de >40 y contiene: a) 1 a 100% en peso de biodiesel, b) 0 a 98.9% en peso de gasoil de origen fosil, c) 0.1 a 20% en peso de polioxialquileno dialquil eter de formula RO(CH2O)nR, en donde R es un grupo alquilo con 1 a 10 atomos de carbono y n = 2 a 10, y d) 0 a 5% en peso de aditivos adicionales.

公开(公告)号：AT376987T

公开(公告)日：2007-11-15

申请号：AT05759413

申请日：2005-07-07

Applicant: BASF AG

Inventor： HAUNERT ANDREA ,  PINKOS ROLF ,  KRUG THOMAS ,  SIRCH TILMAN ,  KOCH MICHAEL ,  TEBBEN GERD-DIETER

IPC: C07C29/145 ,  C07C29/149 ,  C07C31/20

Abstract: The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).