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    New cyclohexene-di:carboxylic acid di:amide derivs. - used as selective herbicides, plant growth regulators, desiccants and defoliants
    21.
    发明专利
    New cyclohexene-di:carboxylic acid di:amide derivs. - used as selective herbicides, plant growth regulators, desiccants and defoliants 未知

    公开(公告)号：DE4213715A1

    公开(公告)日：1993-10-28

    申请号：DE4213715

    申请日：1992-04-25

    Applicant: BASF AG

    Inventor： KLINTZ RALF DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  PLATH PETER DR ,  KARDORFF UWE DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

    IPC: A01N37/30 ,  A01N37/32 ,  A01N37/34 ,  A01N37/46 ,  A01N43/12 ,  A01N43/16 ,  A01N43/40 ,  A01N43/74 ,  C07C233/61 ,  C07C233/63 ,  C07C255/13 ,  C07C255/46 ,  C07D209/48 ,  C07D295/185 ,  C07D307/12 ,  C07D307/90 ,  C07D309/06 ,  C07D339/08 ,  C07D401/10 ,  C07D413/10 ,  C07D417/10 ,  C07C233/57 ,  A01N37/22 ,  A01N37/24 ,  A01N43/54 ,  C07D403/10 ,  C07D405/10 ,  C07D409/10

    Abstract: N-(Substd. phenyl)-cyclohexene -1,2-dicarboxylic acid diamide derivs. of formula (I) and their salts are new. In (I), R1, R2 = (i) H; (ii) alkyl, alkenyl or alkynyl all opt. substd. (iii) 3-8C cycloalkyl; or (iv) phenyl or heterocyclyl (contg. 1-4 heteroatoms selected from 1-4N, 1 or 2 O and 1 or 2 S), both opt. C-substd. by one or more of OH, halogen, CN, NO2, CF3, halogen and alkyl; if R1 = H or alkyl, then additionally: R2 = (v) OH, alkoxy, alkenyloxy, alkynyloxy, 3-7C cycloalkoxy, 5-7C cycloalkenyloxy, haloalkoxy, haloalkenyloxy, (3-7C) cycloalkyl-alkoxy, alkoxycarbonyl, cyanoalkoxy, hydroxyalkoxy, alkoxyalkoxy, alkoxycarbonylalkoxy, alkylthioalkoxy or mono- or dialkylamino-alkoxy; (vi) phenylalkoxy, phenylalkenyloxy or phenylalkynyloxy (in which 1 or 2 CH2 gps. of the aliphatic chain are opt. replaced by O, S and/or N (alkyl) and phenyl rings are opt. substd. by 1-3 of alkyl, 2-6C alkenyl, halogen, CN, NO2, haloalkyl alkoxy and alkoxycarbonyl), or (vii) NR7R8; or NR1R2 = non-aromatic heterocycle which can contain 1-3 N and/or one O or S and 1 or 2 CO gps. and is opt. mono-, di- or tri-alkyl substd.; R7, R8 = H, alkyl, alkenyl, alkynyl, 3-6C cycloalkyl, haloalkyl, alkylcarbonyl, alkoxycarbonyl, alkoxyalkyl or phenyl, opt. substd.; or NR7R8 = 4-7 membered heterocycle opt. contg. a further N, 0 or S heteroatom; R3 = H or alkyl; R4 = H or halogen; R5 = H, halogen, NO2, CN or CF3; R6 = e.g. heterocyclyl (contg. 1-4 heteroatoms selected from 1-4N, 1-2 O and 1-2 S, opt. with 1 or 2 CH2 gps. replaced by CO), opt. C-substd. etc. or R5 + R6 = satd. or partially or completely unsatd. 3-5 membered hydrocarbon chain (opt. contg. 1 or 2 O, S or N and/or one CO or alkoxyimino as chain member; and opt. substd. by 1 or 2 of CN, NO2, NH2, halogen, alkyl, haloalkyl, 2-6C alkenyl, 2-6C alkynyl, cyanoalkyl, alkoxycarbonylalkyl, phenylalkyl and heterocyclyl-alkyl (where heterocyclyl contains 1-4 heteroatoms selected from 1-4N, 1-2 O and 1-2 S)); unless otherwise specified, all alkyl moieties contain 1-6C, and alkenyl and alkynyl moieties 3-6C; and heterocycles are satd. or partially or completely unsatd. and have 3-8 members. Also claimed are certain new 3,4,5,6-tetrahydrophthalimide, 3,4,5,6-tetrahydro-phthalisoimide and tetrahydrophthalamic acid deriv. intermediates. USE/ADVANTAGE - (I) are herbicides (claimed), plant growth regulators, defoliants (claimed) and desiccants (claimed); the new intermediates have the same activities. As herbicides, the cpds. are esp. useful for combatting dicotyledonous weeds and are useful as selective herbicides in wheat, rice, maize, soya and cotton. (I) have good herbicidal activity and higher selectivity (better culture plant compatibility) than related known cpds. The cpds. are useful as desiccants/defoliant for defoliation of cotton or desiccating the ground parts of potatoes, sunflowers, soybeans and rape to facilitate mechanical harvesting. They also promote abscission of citrus fruits, olives and other fruits. The cpds. are applied pre- or post-emergence at 0.001-3 (pref. 0.01-1) kg/ha, or to seeds.

    23.
    发明专利
    未知

    公开(公告)号：DE19530605A1

    公开(公告)日：1997-02-27

    申请号：DE19530605

    申请日：1995-08-21

    Applicant: BASF AG

    Inventor： HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  KLINTZ RALF DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR

    IPC: A01N43/56 ,  C07D213/64 ,  C07D213/73 ,  C07D213/74 ,  C07D213/77 ,  C07D401/04

    Abstract: Trifluoromethylpyridines of formula (Ia) and (Ib) are new. In cpds. (Ia), R2a = CF3, and R2b = halo; in cpds. (Ib), R2a = halo, and R2b = CF3; R1 = NH2 or NHNH2; in (Ib), R1 may also be Cl or Br; R3 = 1-6Calkyl, 1-6Calkenyl or 1-6Calkynyl (all opt. substd. by 1-6 halo), 3-6C cycloalkyl (opt. substd. by 1-3 of 1-3C alkyl), 1-6C alkyl substd. by CN, COOH, 1-6C alkoxycarbonyl, 1-4C alkoxy-2-4C alkoxycarbonyl, CONH2, CONH-1-4C alkyl, CON(1-4C alkyl)2,CONH-2-4C alkenyl, CONH-3-4C alkynyl or CON(1-4C alkyl) (3-4C alkenyl or alkynyl); 2-6C alkyl substd. by 1-4C alkoxy or 3-6C-( alpha -alkylalkylidene)iminoxy, 3-oxetanyl, cyclopropylmethyl, 1-6C alkylamino, di(1-6C alkyl)amino; 1-6C alkylideneimino or alpha -(1-4C alkyl)-2-6C alkylideneimino; and halo = F, Cl, Br or I.

    25.
    发明专利
    未知

    公开(公告)号：DE19523372A1

    公开(公告)日：1997-01-09

    申请号：DE19523372

    申请日：1995-06-29

    Applicant: BASF AG

    Inventor： MENKE OLAF DR ,  KLINTZ RALF DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  GOETZ NORBERT DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISLITZ ULF DR

    IPC: A01N43/54 ,  C07C275/24 ,  C07C281/02 ,  C07C281/06 ,  C07D239/54 ,  C07D413/12 ,  C07D419/12 ,  C07D239/545 ,  C07C271/22

    Abstract: The invention concerns 1-amino-3-benzyluracils of formula (I) and their salts. In said formula (I), R = halogen; R , R = H, CN, SCN, halogen, C1-C4-alkyl halide, C1-C4-alkoxy halide, C1-C4-alkylthio halide; R = R + C1-C4-alkyl, C1-C4-alkoxy, C1-C6-alkyl-NH-CO-; R = H, CN, NO2, OH, halogen, optionally substituted NH2, optionally substituted C1-C6-alkoxy halide, C1-C6-alkylthio halide, C1-C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C3-C6-alkenyloxy, C3-C6-alkenylthio, C3-C6-alkinyloxy, C3-C6-alkinylthio, C1-C6-alkyl-COO-, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO-, C3-C6-alkenyl-COS-, C3-C6-alkinyl-COO-, C3-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O- or C1-C6-alkyl-SO2-; R = 1) H, OH, SH, halogen, C1-C6-alkoxy halide, C1C6-alkylthio halide, C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, C1-C6-alkyliminooxy-CO-, 2) optionally substituted C1C6-alkoxy, C1-C6-alkylthio, C3-C8-cycloalkoxy, C3-C8-cycloalkylthio, C2-C6-alkenyloxy, C2-C6-alkenylthio, C2-C6-alkinyloxy, C2-C6-alkinylthio, C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-, C2-C6-alkenyl-COO-, C2-C6-alkenyl-COS-, C2-C6-alkinyl-COO-, C2-C6-alkinyl-COS-, C1-C6-alkyl-SO2-O-, C1-C6-alkyl-SO2-, 3) -CY-R {Y = -O-, -S-, optionally substituted -NH-}, -C(R )(Z R )(Z R ) {Z , Z = -O-, -S-}, -C(R )=C(R )-CN, -C(R )=C(R )-CO-R , -CH(R )-CH(R )-CO-R , -C(R )=C(R )-CH2-CO-R , -C(R )=C(R )-C(R )=C(R )-CO-R , -C(R )=C(R )-CH2-CH(R )-CO-R , -CO-OR , -CO-SR , -CO-N(R )-OR , -C=C-CO-NH-OR , -C=C-CO-N(R )-OR , -C=C-CS-NH-OR , -C=C-CS-N(R )-OR , -C(R )=C(R )-CO-NH-OR , -C(R )=C(R )-CO-N(R )-OR ,-C(R )=C(R )-CS-NH-OR , -C(R )=C(R )-CS-N(R )-OR , -C(R )=C(R )-C(R )=N-OR , -C(R )=N-OR , -C=C-C(R )=N-OR , -C(Z R )(Z R )-OR , -C(Z R )(Z R )-SR , -C(Z R )(Z R )-N(R )R , optionally substituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl, or a chain comprising (N + O or N + O + S) heterocyclyl. These compounds can be used as herbicides for desiccating/defoliating plants.

    26.
    发明专利
    未知

    公开(公告)号：DE19508590A1

    公开(公告)日：1996-09-19

    申请号：DE19508590

    申请日：1995-03-13

    Applicant: BASF AG

    Inventor： KLINTZ RALF DR ,  GOETZ NORBERT DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  BUSSCHE-HUENNEFELD CHRISTOPH D ,  HARREUS ALBRECHT DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISLITZ ULF DR

    IPC: C07D239/54 ,  A01N43/60 ,  A01N43/84 ,  C07D241/52 ,  C07D241/54 ,  C07D265/36 ,  C07D403/04 ,  C07D413/04 ,  C07D413/14 ,  C07D403/14 ,  A01N43/54 ,  A01N47/34

    Abstract: 3-Aryluracils (I) and their salts (with A = hydrogen) where: A = H, CH3, NH2; R = H, halogen; R = H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkylthio, C1-C6-alkylsulfenyl or C1-C6-alkylsulfonyl; R = H, halogen, C1-C6-alkyl; X = oxygen or -N(R )-, with R = C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkylcarbonyl or C1-C6-alkoxy-C1-C6-alkyl; Y and Y = oxygen or sulfur; Z = oxygen or -N(R )-; R , R and R = H, C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C1-C6-alkoxy-C1-C6-alkyl; or R and R together are a second chemical bond; R = H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkylcarbonyl, C3-C6-alkenyl-carbonyl, C3-C6-alkynylcarbonyl or C1-C6-alkylsulfonyl, where each of the last-mentioned 9 radicals can carry 1-3 substituents: R = H, C1-C6-alkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkoxy-C1-C6-alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, unsubst. or subst. phenyl or phenyl-C1-C6-alkyl; R = H, OH, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-alkoxy, C3-C6-alkenyloxy, C1-C6-alkoxycarbonyl-C1-C6-alkoxy; R = C1-C6alkoxy, C3-C6-alkenyloxy, C1-C6-alkoxycarbonyl-C1-C6alkoxy; R = C1-C6-alkyl, C3-C6-alkenyl, C1-C6-alkoxycarbonyl-C1-C6-alkyl. Use: as herbicides; for the desiccation/defoliation of plants.

    30.
    发明专利
    未知

    公开(公告)号：DE4419517A1

    公开(公告)日：1995-12-07

    申请号：DE4419517

    申请日：1994-06-03

    Applicant: BASF AG

    Inventor： BUSSCHE-HUENNEFELD CHRISTOPH D ,  KLINTZ RALF DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  DITRICH KLAUS DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

    IPC: C07D231/18 ,  A01N43/56 ,  A01N47/12 ,  A01N47/34 ,  A01N47/40 ,  C07D231/20 ,  C07D231/22 ,  C07D401/06 ,  C07D401/10 ,  C07D403/06 ,  C07D403/10 ,  C07D405/06 ,  C07D405/10 ,  C07D409/06 ,  C07D231/14

    Abstract: Substituted 3-phenylpyrazoles (I) in which: R represents -C(R )=C(R ,R ), (a), -C(R ,R )-C(R ,R ,R ), (b), (c), -C(R )=C(R )-phenyl or -C(R ,R )-C(R ,R )-phenyl; R represents CN, CF3, halogen; R represents H, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl; R represents C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl; R represents H, NO2, halogen, carboxylic acid/ester radical, substituted or unsubstituted aminocarbonyl; R represents H, halogen; Y represents -O-, -S-, -CH2-; Z represents 2- to 5-membered chain; R represents CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, carboxylic acid/ester radical, substituted or unsubstituted aminocarbonyl; R , R , R , R represent H, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, carboxylic acid/ester radical, substituted or unsubstituted -N(H)-CO-R , amino or aminocarbonyl: R represents CN, halogen, carboxylic acid/ester radical, substituted or unsubstituted amino or aminocarbonyl, azido, OH, (halo)alkoxy, alkenyloxy, alkylcarbonyloxy; R represents isoxazolidinylcarbonyl, carboxylic acid/ester radical, acid amide group, -CO-O-N=C(R )-(C1-C6-alkyl), -CO-O-N=C(R )-CO-O-(C1-C6-alkyl), -CO-O-N=C(R31)-(C1-C4-alkyl)-CO-O-(C1-C4-alkyl)-CO-O-CH2-R , -CO-O-C(R )-(C1-C4-alkyl), substituted or unsubstituted aminocarbonyl or aminothiocarbonyl, -CO-NH-SO2-(C1-C4-alkyl), -CO-R , -CO-O-(C1-C4-alkyl)-C(R )=N-O-(C1-C4-alkyl), substituted or unsubstituted -CO-NH-CH(R )-(COOH/ester) substituted or unsubstituted cyclopentyliminooxy- or cyclohexyliminooxycarbonyl; R represents H, C1-C4-alkyl, phenyl, benzyl; R , R represents H, C1-C6-alkyl, C1-C6-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, substituted or unsubstituted C3-C7-cycloalkyl, phenyl or phenyl-C1-C6-alkyl; R represents C1-C6-alkyl, C1-C4-haloalkyl, C1-C6-alkoxy-C1-C4-alkyl, C1-C6-alkoxycarbonyl-C1-C4-alkyl, di-[C1-C6-alkoxycarbonyl]-C1-C4-alkyl, C3-C6-cycloalkyl, C1-C6-alkoxy, C1-C6-alkoxycarbonyl, 2-furyl, substituted or unsubstituted phenyl; R represents H, halogen, C1-C4-alkyl, C2-C4-alkenyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, are used as herbicides.

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