PROCESS FOR PREPARING HALOGENATED METHYL BENZOYL CYANIDES

    公开(公告)号:BG62806B1

    公开(公告)日:2000-08-31

    申请号:BG10148397

    申请日:1997-05-14

    Applicant: BASF AG

    Abstract: The halogenated methyl benzoyl cyanides are of formula (I) Ph-CO-CN , in which Ph stands for a phenyl rest substituted by chloromethyl or bromethyl that optionally carry 1-4 other rests, from halogenated methyl benzoyl chlorides having the formula (II) Ph-CO-CL. The compound having the formula (II) is reacted with a cyanide-releasing compound in the presence of a Lewis acid, optionally in an inert organic solvent, and the product obtained by this process is then isolated. The halogenated methyl benzoyl cyanides having the formula (I) are important intermediate products for the synthesys of plant protective agents. 3 claims

    Process for preparing halogenated methyl benzoyl cyanides

    公开(公告)号:AU694590B2

    公开(公告)日:1998-07-23

    申请号:AU4116596

    申请日:1995-11-14

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

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