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公开(公告)号：JP2007176923A
公开(公告)日：2007-07-12
申请号：JP2006216963
申请日：2006-08-09
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , NAGAI MINORU , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic repairing or suppressing the structural change at the inside of hairs and also capable of imparting a good flexibility.
SOLUTION: This hair cosmetic comprises the components (A), (B), (C) and water. (A) a tertiary amine expressed by formula (1) [wherein, R
1 is a 6-24C alkyl or an alkenyl; R
2 , R
3 are each a 1-6C alkyl or -(AO)
m H (wherein, A is a 2-4C alkylene; and (m) is 1-6 number)] or its salt, (B) an aromatic alcohol including benzyl alcohol, benzyloxyethanol, etc., and (C) a branched fatty acid including 18-methyleicosanoic acid, 16-methylheptadecanoic acid, 16-methyloctadecanoic acid, etc.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题：提供修护或抑制毛发内部的结构变化的毛发化妆品，并且还能够赋予良好的柔韧性。 本发明的化妆品包括组分（A），（B），（C）和水。 （A）由式（1）表示的叔胺[其中R 1是6-24C烷基或链烯基; R（SP）2，R SP 3，各自为1-6C烷基或 - （AO）H（其中，A为2-4C亚烷基 ;（m）为1-6数）]或其盐，（B）包括苄醇，苄氧基乙醇等的芳族醇，（C）包含18-甲基十一烷酸，16-甲基十五烷酸， 16-甲基十八烷酸等。版权所有（C）2007，JPO＆INPIT
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公开(公告)号：JP2007176922A
公开(公告)日：2007-07-12
申请号：JP2006216962
申请日：2006-08-09
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , NAGAI MINORU , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair wash excellent in foaming/foam quality and touch feeling on rinsing and finishing, and also capable of repairing or suppressing the hair damage/fatigue destruction.
SOLUTION: This hair wash comprises the following components (A) to (C). (A) a sulfuric acid salt type surfactant expressed by formula: R
1 -O-(C
2 H
4 O)
m -SO
3 M [wherein, R
1 is an 8-18C alkyl or an alkenyl; (m) is 0 or a positive integer; and M is an alkali metal, an alkaline earth metal or ammonium], having that m=0 is 30-45%, m=1 is 18-27%, m=2 is 10-20%, and rest of m=3 in the total sulfuric salts, and also having the total of m=0 to 2 as ≥70%, (B) an amphoteric surfactant and (C) a branched fatty acid expressed by general formula (2) [R
2 is methyl or ethyl; and (n) is 3 to 36] or its salt.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题：提供发泡/泡沫质量优异的洗发和漂洗和整理的触感，并且还能够修复或抑制头发损伤/疲劳破坏。 该洗发剂包含以下成分（A）〜（C）。 （A）由下式表示的硫酸盐型表面活性剂：R
-O-（C 2 H 4 O） 3其中R 1是8-18C烷基或链烯基; （m）为0或正整数; 并且M为碱金属，碱土金属或铵]，其中m = 0为30-45％，m = 1为18-27％，m = 2为10-20％，m = 3的其余部分 在总硫酸盐中，m = 0〜2的总和≥70％，（B）两性表面活性剂和（C）由通式（2）表示的支链脂肪酸[R 2＆ / SP>是甲基或乙基; 和（n）为3〜36]或其盐。 版权所有（C）2007，JPO＆INPIT -
公开(公告)号：JPH08109166A
公开(公告)日：1996-04-30
申请号：JP24745094
申请日：1994-10-13
Applicant: KAO CORP
Inventor： NAGAI MINORU , KAWADA YUZO , TSUCHIYA MAYUMI , YAMAZAKI SEIJI , YAMAMURO AKIRA
Abstract: PURPOSE: To provide the subject new compound having humectant action, cuticle emollient action, etc., and useful as a compounding component for skin cosmetic and hair cosmetic and a production intermediate for agrochemicals, pharmaceuticals, etc. CONSTITUTION: A guanidine derivative of formula I (one of R to R is hydroxyl and the others are H) or its salt, e.g. N-(aminoiminomethyl)-trans-4-hydroxy-L- proline. The compound of formula I can be produced e.g. by reacting a proline compound of formula II with a guanidylating agent (e.g. cyanamide or S- alkylisothiourea). The guanidylation reaction is preferably carried out at 0-200 deg.C for 1-72hr under stirring when cyanamide is used as the guanidylating agent or at 25-200 deg.C for 1-72hr under stirring in the presence of a base such as barium hydroxide or pyridine when the agent is other than cyanamide.
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公开(公告)号：JPH08109120A
公开(公告)日：1996-04-30
申请号：JP24745194
申请日：1994-10-13
Applicant: KAO CORP
Inventor： YAMAZAKI SEIJI , KAWADA YUZO , TSUCHIYA MAYUMI , NAGAI MINORU , YAMAMURO AKIRA
IPC: C07D211/62 , A61K8/00 , A61K8/30 , A61K8/36 , A61K8/362 , A61K8/37 , A61K8/49 , A61K31/35 , A61K31/40 , A61K31/401 , A61P17/00 , A61Q19/00 , C07D207/08 , C07D207/12 , C07D207/16 , A61K7/48 , A61K7/00
Abstract: PURPOSE: To obtain a skin cosmetic capable of sustainedly manifesting excellent softness imparting effects on a horny layer without deteriorating the normal skin physiology for a long period and further imparting a good feeling of use to the skin without stickiness. CONSTITUTION: This skin cosmetic contains 0.001-50wt.%, especially 0.01-20wt.% guanidine derivative of formula I (formula II is a heterocyclic group selected from azetidine, pyrrolidine, piperidine, piperazine and morpholine; R and R are each H, an alkyl, a hydroxyalkyl, carboxyl, a carboxyalkyl or amidino) or its salt, e.g. N-amidino-L-proline. When an organic or an inorganic acid, preferably a dicarboxylic acid, especially succinic acid is blended in the cosmetic, softening effects can be enhanced. The amount thereof blended is within the range of 0.001-30wt.%. The compound of formula I is obtained by reacting a cyclic amine derivative of formula III with a guanylating reagent.
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公开(公告)号：JPH0892054A
公开(公告)日：1996-04-09
申请号：JP22802394
申请日：1994-09-22
Applicant: KAO CORP
Inventor： YAMAZAKI SEIJI , KAWADA YUZO , TSUCHIYA MAYUMI , NAGAI MINORU , YAMAMURO AKIRA
IPC: A61K8/30 , A61K8/00 , A61K8/36 , A61K8/362 , A61K8/37 , A61K8/43 , A61K8/55 , A61K8/58 , A61Q19/00 , A61K7/48 , A61K7/00
Abstract: PURPOSE: To obtain a skin cosmetic containing a guanidine derivative (salt) having a specific structure, capable of exhibiting excellent softening property- imparting effect to corneal layer for a long time, free from stickiness and capable of providing good feeling of use. CONSTITUTION: This cosmetic contains preferably 0.01-20wt.% of a guanidine derivative of formula I or II [A and B are each a 2-8C alkylene; D is a direct bond, CO, etc.; E is H, a lower alkyl; (m) is 1-6; (n) is 0-6; R is H, a lower alkyl, etc.; (l) is 1-10; G is H, phosphate group, etc.) or its salt (preferably guanidinoethoxyethanol, guanidinopropanoic acid, etc.) as an active ingredient. The compound of formula I or II is obtained by reacting, e.g. an amine derivative such as 2-(2-aminoethoxy)ethanol with a guanidylation reagent such as cyanamide. Furthermore, the effect can moreover be enhanced by further blending the cosmetic with 0.01-10wt.% of succinic acid.
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Patent Agency Ranking
公开(公告)号：JP2007176924A
公开(公告)日：2007-07-12
申请号：JP2006216964
申请日：2006-08-09
Inventor： USUNAMI FUMIKO , TANAMACHI HIROTO , NAGAI MINORU , ISHITA MIO
Abstract: PROBLEM TO BE SOLVED: To provide a hair cosmetic capable of repairing or suppressing the structural change at the inside of the hairs formed by a chemical treatment, drying by a dryer and daily hair care actions and also imparting a good suppleness and pliable feeling from moistened time to even after drying.
SOLUTION: This hair cosmetic comprises (A) an amideamine compound (1) [wherein, R
1 is am 11-23C aliphatic hydrocarbon group; R
2 is H or a 1-4C alkyl; and (m) is 2-4] or its salt, (B) an aromatic alcohol (2) [wherein, R
4 is H, methyl or methoxy; Y is a single bond or a 1-3C alkylene or an alkenylene; Z is H or OH; and (p), (q) are each 0-5 number], (C) a branched fatty acid (3) [wherein, R
5 is methyl or ethyl; and (n) is 3-36] or its salt, and water.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题：提供一种能够修复或抑制通过化学处理形成的毛发内部的结构变化，通过干燥器干燥和每日头发护理动作并且还赋予良好的柔软性和柔韧性的头发化妆品 从潮湿的时间到干燥后的感觉。 解决方案：该毛发化妆品包含（A）酰胺胺化合物（1）[其中，R SP 1为11-23个脂肪族烃基; R
2 是H或1-4C烷基; 和（m）为2-4]或其盐，（B）芳族醇（2）[其中，R 4为H，甲基或甲氧基; Y是单键或1-3C亚烷基或亚烯基; Z是H或OH; 和（p），（q）各自为0-5数]，（C）支链脂肪酸（3）[其中，R 5为甲基或乙基; 和（n）为3-36]或其盐和水。 版权所有（C）2007，JPO＆INPIT -
公开(公告)号：JPH11302246A
公开(公告)日：1999-11-02
申请号：JP11671098
申请日：1998-04-27
Applicant: KAO CORP
Inventor： HASHIZUME KOJIRO , NAGAI MINORU , OISHI SUSUMU , YAMAMURO AKIRA , FUJIKURA YOSHIAKI
Abstract: PROBLEM TO BE SOLVED: To obtain a new compound capable of imparting excellent softness as well as good feeling to hair without tackiness and useful as a cosmetic. SOLUTION: This compound is represented by formula I [R is a 4-30C hydrocarbon; R to R are each H or CH2 CHOH)CH2 OR ] Furthermore, the compound is preferably obtained by reacting a guanidine of formula II with a glycidyl ether of formula III in the presence of a base such as potassium hydroxide in a solvent such as isobutanol at 0-100 deg.C and when the compound is used as a hair cosmetic, the compound is preferably formulated in an amount of about 0.001-50 wt.% based on total composition.
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公开(公告)号：JPH1135424A
公开(公告)日：1999-02-09
申请号：JP19549397
申请日：1997-07-22
Applicant: KAO CORP
Inventor： NAGAI MINORU , OISHI SUSUMU , ONO TOSHIYA , YAMAMURO AKIRA , FUJIKURA YOSHIAKI
Abstract: PROBLEM TO BE SOLVED: To obtain a hair cosmetic good in feeling when applied and capable of imparting the hair after dried with excellent wiriness esp. even in neutral region, by including a specific guanidine derivative. SOLUTION: This hair cosmetic is obtained by formulating 0.001-50 wt.% of a guanidine derivative of formula I [formula II represents a heterocyclic group selected from azetidine, pyrrolidine, piperidine, piperazine, and morpholine; R and R are each H, (hydroxy or carboxy)alkyl, hydroxyl, carboxyl or amidino; Z and Z are each H, a (substituted) alkyl or alkenyl] [e.g. 1- amidinopyrrolidine (1-pyrrolidinecarboxyamidine)] or an acid addition salt thereof, singly or a combination of two or more kinds thereof, and pref. furthermore, a surfactant, aromatic alcohol(s) and/or glycolic acid.
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公开(公告)号：JPH09263511A
公开(公告)日：1997-10-07
申请号：JP26626796
申请日：1996-10-07
Applicant: KAO CORP
Inventor： FUJIMURA TSUTOMU , ITO NORIKO , TAKEMA YOSHINORI , YAMAZAKI SEIJI , KAWADA YUZO , YAMAMURO AKIRA , NAGAI MINORU , ONO TOSHIYA
IPC: C07H5/04 , A61K8/00 , A61K8/30 , A61K8/36 , A61K8/362 , A61K8/37 , A61K8/41 , A61K8/42 , A61K8/43 , A61K8/49 , A61K8/60 , A61K8/68 , A61Q19/00 , A61Q19/08 , A61K7/00 , A61K7/48
Abstract: PROBLEM TO BE SOLVED: To obtain the subject preparation capable of persisting an excellent flexibility-imparting effect to horny layers and an excellent skin wrinkle- improving effect for a long time and useful for skin-softening cosmetics, antiaging cosmetics, etc. SOLUTION: This preparation for external uses for skins contains a guanidine derivative of formula I (R is a hydrocarbon group, an aromatic ring group, an aralkyl group, etc.; R is H, a hydrocarbon group) or its acid adduct, a synthetic sphingosine derivative of formula II (R is a 4-40C hydrocarbon group; R , R , R , R , R are each H, a 1-10C hydrocarbon; X, Y are each H, a 1-6C alkyl which may have an oxygen atom), and an organic acid such as a dicarboxylic acid or its ester. The guanidine derivative, the synthetic sphingosine derivative, and the organic acid or its ester are preferably compounded in amounts of 0.001-50wt.%, 0.0001-10wt.% and 0.001-30wt.%, respectively, in the preparation.
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公开(公告)号：JPH09202710A
公开(公告)日：1997-08-05
申请号：JP27462896
申请日：1996-10-17
Applicant: KAO CORP
Inventor： FUJIMURA TSUTOMU , OGAWA AYUMI , TSUKAHARA KAZUE , TAKEMA YOSHINORI , NAGAI MINORU , ONO TOSHIYA
IPC: A61K8/30 , A61K8/00 , A61K8/36 , A61K8/362 , A61K8/37 , A61K8/43 , A61K8/46 , A61Q19/00 , A61Q19/08 , C07C279/08 , C07C279/14 , C07C309/15 , C07F9/09 , A61K7/00 , A61K7/48
Abstract: PROBLEM TO BE SOLVED: To obtain a wrinkles improver containing a guanidine derivative having a specific structure or its acid addition salt as an active ingredient, capable of suppressing occurrence of wrinkles without impairing normal skin physiology and excellent in effect for eliminating wrinkles and having good feeling to users. SOLUTION: This wrinkles improver is obtained by using a guanidine derivative of formula I [A and B are each a 2-8C alkylene; D is a direct bond or a 1-6C alkylene; E is H, an alkyl, an aralkyl or an aryl; (m) is 1-6; (n) is 0-6; R is H, an alkyl or (AO)m (BO)n -D-E] or formula II [(k) is 1-10; G is H, OH, COOH, sulfonic acid or phosphoric acid] or its acid addition salt. The wrinkles improver is useful as a cosmetic for preventing aging. The content of the active ingredient is preferably 0.001-50wt.%. An organic acid or its ester in an amount of 0.001-30wt.% is preferably further added to the system. A dicarboxylic acid is preferably used as the organic acid. The compound of formula I is obtained by reacting, e.g. a compound of formula III with a guanidination reagent.
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