BIOLOGICALLY DEGRADABLE POLYMERS, PROCESSES OF THEIR PREPARATION AS WELL AS THEIR USE FOR PRODUCING BIOLOGICALLY DEGRADABLE SHAPED ARTICLES

    公开(公告)号:CZ146597A3

    公开(公告)日:1997-10-15

    申请号:CZ146597

    申请日:1995-06-27

    Applicant: BASF AG

    Abstract: Biodegradable polyether esters P1 obtainable by reacting a mixture essentially comprising(a1) a mixture essentially comprising20-95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol % of a compound containing sulfonate groups,where the total of the individual mole percentages is 100 mol %, and(a2) a mixture of dihydroxy compounds essentially comprising(a21) from 15 to 99.8 mol % of a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols,(a22) from 85 to 0.2 mol % of a dihydroxy compound containing ether functionalities of the formula Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, or mixtures thereof,where the molar ratio of (a1) to (a2) is chosen in the range from 0.4:1 to 1.5:1, with the proviso that the polyether ester P1 has a molecular weight (Mn) in the range from 5000 to 80,000 g/mol, a viscosity number in the range from 30 to 450 g/ml (measured in o-dichlorobenzene/phenol (50/50 ratio by weight) at a concentration of 0.5% by weight of polyether ester P1 at 25° C.) and a melting point in the range from 50 to 200° C., and with the further proviso that from 0.01 to 5 mol %, based on the molar quantity of component (a1) employed, of a compound D with at least three groups capable of ester formation are employed to prepare the polyether ester P1,and further biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives, biodegradable moldings, films and blends with starch obtainable from the polymers and molding compositions according to the invention.

    33.
    发明专利
    未知

    公开(公告)号:DE19519338A1

    公开(公告)日:1996-11-28

    申请号:DE19519338

    申请日:1995-05-26

    Applicant: BASF AG

    Abstract: The invention concerns polymer and surfactant mixtures containing in suspended form in at least one surfactant between 1 and 50 wt.% of a polymer comprising: a) between 10 and 100 wt.% of at least one vinylimidazole or a derivative thereof, an open-chain or cyclic N-vinylamide, N-vinyloxazolidone, N-vinyltriazole or mixtures of said monomers; b) between 0 and 90 wt.% of other copolymerizable monoethylenically unsaturated monomers; and c) between 0 and 30 wt.% of at least one monomer with at least two ethylenically unsaturated, non-conjugated double bonds. The invention further concerns a process for preparing these mixtures by polymerization of said monomers in a surfactant, and the use of the mixtures as additives for washing agents.

    34.
    发明专利
    未知

    公开(公告)号:DE19515730A1

    公开(公告)日:1996-11-07

    申请号:DE19515730

    申请日:1995-05-03

    Applicant: BASF AG

    Abstract: N-benzyliminium salts have formula (I), in which R and R represent independently from each other hydrogen or optionally substituted alkyl, alkenyl, cycloalkyl, aralkyl, heteroaralkyl, aryl or heteroaryl, provided that at least one of the rests R or R has at least 5 C atoms, if it is an aliphatic rest, or at least 7 C atoms, if it is a cyclic rest; R stands for an organic or inorganic substituent; m equals 1, 2 or 3; and X stands for an oxidation-resistant anion, while n indicates the valence of anion X. These N-benzyliminium salts are used as bleach catalysts, in particular in textile washing and bleaching systems.

    35.
    发明专利
    未知

    公开(公告)号:DE4444975A1

    公开(公告)日:1996-06-20

    申请号:DE4444975

    申请日:1994-12-16

    Applicant: BASF AG

    Abstract: Disclosed are powdered complexes of condensation polymers that contain aspartimide units and of hydrogen peroxide, with a mean paricle diameter of 10 mu m to 5 mm and a hydrogen peroxide content of 1 to 45 wt.%; a method for producing the powdered complexes by reacting hydrogen peroxide with powdered condensation polymers containing aspartimide units with a mean particle diameter of 10 mu m to 5 mm and drying the mixture, as well as use of the polyaspartimide-hydrogen peroxide complexes as admixture to detergents and cleaners, as preservative and disinfectant, as bleach in hair-care products and as polymerization initiator.

    39.
    发明专利
    未知

    公开(公告)号:DE4142131A1

    公开(公告)日:1993-06-24

    申请号:DE4142131

    申请日:1991-12-20

    Applicant: BASF AG

    Abstract: Described are polycondensation products obtained by condensing (a) butane-1,2,3,4-tetracarboxylic acid, optionally mixed with hydroxycarboxylic acids or other carboxylic acids, with (b) polyhydroxy compounds selected from the group comprising mono-, oligo- and polysaccharides, reduced mono- and oligosaccharides and their amino derivatives, oxidized mono-, oligo- and polysaccharides, alkyl polyglycosides, polyvinyl alcohols and oligoglycerins with more than 2 glycerin units, or mixtures thereof, plus, optionally, (c) up to 20 mole %, relative to component a, of alkylene glycols, polyalkylene glycols or monohydric C4-C20 alcohols, in the ratio, by weight, of a:b from 50:1 to 0.5:1, the condensation products produced having a K-value of 8 to 100 (determined by the H. Fikent method in a 2 % by wt. aqueous solution at 25 DEG C and pH 7 on the Na salts of the condensation products). The invention also concerns the use of the polycondensation products as additives to low-phosphate or phosphate-free washing or cleaning agents in amounts ranging from 0.1 to 30 % by wt. relative to the agent.

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