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    35.
    发明专利
    未知

    公开(公告)号：DE3635710A1

    公开(公告)日：1988-04-28

    申请号：DE3635710

    申请日：1986-10-21

    Applicant: BASF AG

    Inventor： KONRAD RAINER DR ,  FUNK GUIDO DR ,  SCHMIDT-THUEMMES JUERGEN DR ,  MUELLER-MALL RUDOLF DR ,  SCHWEIER GUENTHER DR

    IPC: C08F4/02 ,  C08F4/24 ,  C08F4/48 ,  C08F4/62 ,  C08F10/00 ,  C08F10/02 ,  C08F4/52 ,  C08F4/78

    Abstract: Ethene polymerization by Phillips catalysis is carried out using (1) a supported catalyst, which is laden with chromium, phosphorus and aluminum, and (2) a cocatalyst, (1) being obtained by a method in which (1.1) a catalyst intermediate laden with chromium, phosphorus and aluminum is prepared from a silicate carrier, a selected chromium compound, a selected phosphorus compound and a selected aluminum compound, and then (1.2) the catalyst intermediate is heated in an oxygen-containing gas stream. In this process, the component (1) used is one which is obtained by a method in which, in each case in a specific manner, (1.1) in a first stage, (1.1.1) first a suspension is prepared from (1.1.1.1) a finely divided silicate carrier and (1.1.1.2) an inert organic solvent, (1.1.2) then, (1.1.2.1) in an inert organic solvent, (1.1.2.2) an organic chromium compound is combined with (1.1.2.3) an aluminum trialkyl, (1.1.3) then (1.1.3.1) the suspension resulting from (1.1.1) is combined with (1.1.3.2) a phosphoric acid or phosphite and (1.1.3.3) the product obtained from (1.1.2), (1.1.4) finally, the suspension obtained in (1.1.3) is evaporated to dryness, and then (1.2) in a second stage, first (1.2.1) the intermediate obtained from (1.1) is treated with a stream of nitrogen, then (1.2.2) the intermediate obtained from (1.2.1) is heated in an oxygen-containing gas stream, and finally (1.2.3) the intermediate obtained from (1.2.2) is treated with a stream of nitrogen, and both a lithiumalkyl and a boronalkyl are used as (2).

    Process for the preparation of a titanium-containing catalyst component for Ziegler catalyst systems
    37.
    发明专利
    Process for the preparation of a titanium-containing catalyst component for Ziegler catalyst systems 未知

    公开(公告)号：DE3433468A1

    公开(公告)日：1986-03-20

    申请号：DE3433468

    申请日：1984-09-12

    Applicant: BASF AG

    Inventor： VOGT HEINZ DR ,  BACHL ROBERT DR ,  WARZELHAN VOLKER DR ,  STAIGER GERHARD DR ,  FUNK GUIDO DR

    IPC: C08F4/64 ,  C08F4/65 ,  C08F10/00 ,  C08F4/52

    Abstract: The invention relates to the preparation of a titanium-containing catalyst component (1) for Ziegler catalyst systems, in which (1.1) first (1.1.1) an inorganic oxidic support material (I) and (1.1.2) a solution (II) of (IIa) a lower alcohol, (IIb) a titanium trichloride and (IIc) magnesium chloride are combined, forming a dispersion (III), which is evaporated to form an intermediate (IV), and (1.2) then (1.2.1) the product (IV) from (1.1) and (1.2.2) an aluminium component (V) are combined, the resultant product (VI) being the catalyst component (1), characterised in that the aluminium component (V) employed in (1.2) comprises (1.2.2.1) a complex compound of a certain oxacycloalkane carrying no substituents and a certain aluminium compound, and (1.2.2.2) optionally a certain free aluminium compound.

    38.
    发明专利
    未知

    公开(公告)号：DE3426193A1

    公开(公告)日：1986-01-23

    申请号：DE3426193

    申请日：1984-07-17

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER DR ,  KARER RAINER ,  BACHL ROBERT DR ,  FUNK GUIDO DR

    IPC: C08F4/02 ,  C08F4/62 ,  C08F4/64 ,  C08F4/68 ,  C08F10/00 ,  C08F4/52

    Abstract: A transition metal catalyst component (1) for Ziegler catalyst systems is prepared by (1.1) first combining (1.1.1) an inorganic oxidic substance (I), as the carrier, with (1.1.2) a solution (II) consisting of (IIa) an organic solvent and (IIb) a transition metal composition to form a suspension (III), evaporating down this suspension to form a solid-phase intermediate (IV) and (1.2) then combining (1.2.1) the solid-phase intermediate (IV) obtained from (1.1) with (1.2.2) a solution of an organoaluminum compound (V) to form a suspension, the resulting suspended solid-phase products (VI) being the transition metal catalyst component (1). The characteristic feature is that the solution (II) employed in stage (1.1) consists of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex, (IIb2) a titanium trihalide and (IIb3) a zirconium tetrahalide.

    39.
    发明专利
    未知

    公开(公告)号：DE3404668A1

    公开(公告)日：1985-08-14

    申请号：DE3404668

    申请日：1984-02-10

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER DR ,  BACHL ROBERT DR ,  BALL WOLFGANG DR ,  FUNK GUIDO DR ,  LAUN MARTIN DR

    IPC: C08F4/00 ,  C08F4/14 ,  C08F4/16 ,  C08F4/20 ,  C08F4/60 ,  C08F4/622 ,  C08F4/64 ,  C08F4/658 ,  C08F4/68 ,  C08F10/00 ,  C08F10/04 ,  C08F10/02 ,  C08F10/14 ,  C08F10/08 ,  C08F4/52

    Abstract: alpha -Monoolefins are polymerized using a Ziegler catalyst system comprising (1) a transition metal catalyst component and (2) an organoaluminum catalyst component, in which (1) is a solid-phase product (VI) obtained by (1.1) first combining (1.1.1) an inorganic oxidic substance (I), as the carrier, with (1.1.2) a solution (II) consisting of (IIa) an organic solvent and (IIb) a transition metal composition to form a suspension (III), evaporating down this suspension to form a solid-phase intermediate (IV), and (1.2) then (1.2.1) combining the solid-phase intermediate (IV), obtained from (1.1), with (1.2.2) a solution of an organoaluminum compound (V) to form a suspension, the resulting suspended solid-phase product (VI) being the transition metal catalyst component (1). The characteristic feature is that (1) is a solid-phase product (VI) obtained using a solution (II) consisting of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex, (IIb2) a titanium trihalide and (IIb3) a zirconium tetrahalide.

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