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公开(公告)号:BR0311489A
公开(公告)日:2005-03-15
申请号:BR0311489
申请日:2003-06-06
Applicant: BASF AG
Inventor: POPP ANDREAS , DANIEL THOMAS , SCHROEDER JUERGEN , JAWOREK THOMAS , FUNK RUEDIGER , SCHWALM REINHOLD , WEISMANTEL MATTHIAS , RIEGEL ULRICH
IPC: C08G65/332 , A61L15/60 , C07B61/00 , C07C67/08 , C07C69/54 , C08F290/06 , C08G65/26 , C08G65/28
Abstract: The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O-CH2-CH2- PO is independently at each instance O-CH2-CH(CH3)- or O-CH(CH3)-CH2- BO is independently at each instance O-CH2-CH(CH2-CH3)- or O-CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
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公开(公告)号:AU2003242636A1
公开(公告)日:2003-12-22
申请号:AU2003242636
申请日:2003-06-06
Applicant: BASF AG
Inventor: JAWOREK THOMAS , DANIEL THOMAS , WOLF LOTHAR , KONIGER RAINER , SCHWALM REINHOLD , HARTMANN GABRIELE , WICKEL STEFAN
IPC: C08G63/78 , A61L15/60 , C07C67/08 , C08G65/332 , C07C69/54
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公开(公告)号:CA2487031A1
公开(公告)日:2003-12-18
申请号:CA2487031
申请日:2003-06-10
Applicant: BASF AG
Inventor: SCHROEDER JUERGEN , JAWOREK THOMAS , FUNK RUEDIGER , POPP ANDREAS , DANIEL THOMAS , SCHWALM REINHOLD , WEISMANTEL MATTHIAS , RIEGEL ULRICH
IPC: A61L15/60 , C07C67/08 , C08F290/06 , C08G65/26 , C08G65/28 , C08G65/332 , C07C69/54
Abstract: The invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of formula (I), wherein EO represents O-CH2-CH2-,PO represents independently from each other O-CH2-CH(CH3)- or O-CH(CH3)-CH2-,n1 , n2, n3 represent independently from each other 4,5 or 6, n1 + n2 + n3 is 14, 15 or 16,m1, m2, m3 represent independently from each other 1,2 or 3, m1 + m 2 + m3 is 4, 5 or 6, R1, R2, R3 represent independently from each other H or CH3. The invention also relates to a simplified method for producing said esters and the use of the thus obtained reaction mixture.
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公开(公告)号:BR0013519A
公开(公告)日:2002-05-07
申请号:BR0013519
申请日:2000-08-24
Applicant: BASF AG
Inventor: JAWOREK THOMAS , SCHWALM REINHOLD
IPC: B05D3/04 , B05D3/06 , C08F2/46 , C08F2/48 , C09D4/00 , C09D4/06 , C09D175/16 , C08F290/06
Abstract: A process for producing scratch-resistant coatings comprises applying at least one UV-curable coating composition comprising as its photochemically crosslinkable constituentat least one aliphatic urethane (meth)acrylate prepolymer PU having at least two double bonds per molecule, ora mixture of at least one urethane (meth)acrylate prepolymer PU and at least one reactive diluent,to the target substrate and curing the resulting wet coating by exposure to ultraviolet radiation under an inert gas atmosphere.
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公开(公告)号:BR9916088A
公开(公告)日:2001-09-04
申请号:BR9916088
申请日:1999-12-07
Applicant: BASF AG
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公开(公告)号:DE10002089A1
公开(公告)日:2001-07-26
申请号:DE10002089
申请日:2000-01-19
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , VOELLINGER FRANK , MENZEL KLAUS , REICH WOLFGANG , BECK ERICH , JAWOREK THOMAS
Abstract: A water dispersible, radiation curable polyurethane comprises organic aliphatic or alicyclic polyisocyanates, cycloaliphatic diols and/or cycloaliphatic diamines, compounds having at least one isocyanate reactive group and at least one radically polymerizable unsaturated group and compounds having at least one isocyanate reactive group and at least one dispersion aiding group. A water dispersible, radiation curable polyurethane (I) comprises: (A) organic aliphatic or alicyclic polyisocyanates; (B) cycloaliphatic diols and/or cycloaliphatic diamines; (C) compounds having at least one isocyanate reactive group and at least one radically polymerizable unsaturated group; (D) compounds having at least one isocyanate reactive group and at least one dispersion aiding group; (E) optionally compounds having at least two isocyanate reactive groups having a mol. wt. of less than 1000 g/mol; (F) optionally compounds having at least one isocyanate reactive group that are different to (A)-(D). Independent claims are included for: (i) a polyurethane dispersion (II) comprising the polyurethane (I) and optionally 0-10 wt.% of a photochemical and/or thermal initiator and 0-10 wt.% of a UV absorber and a HALS compound; (ii) a process for the coating of substrates by application of the polyurethane dispersion (II), optionally containing conventional paint additives, onto a substrate and curing by means of electron irradiation or UV light under oxygen, or preferably under inert gas; (iii) the resulting coated substrate.
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公开(公告)号:DE19940313A1
公开(公告)日:2001-03-01
申请号:DE19940313
申请日:1999-08-25
Applicant: BASF AG
Inventor: JAWOREK THOMAS , SCHWALM REINHOLD
IPC: B05D3/04 , B05D3/06 , C08F2/46 , C08F2/48 , C09D4/00 , C09D4/06 , C09D175/16 , B05D7/26 , B05D7/16 , B05D5/00
Abstract: The invention relates to a method for producing scratch resistant coatings. A UV hardenable coating agent contains at least one aliphatic urethane(meth)acrylate prepolymer PU with at least two double bonds per molecule or a mixture of at least one urethane(meth)acrylate prepolymer PU and at least one reactive diluent, said contents being the photochemically cross-linkable component. At least one of said coating agents is applied to the substrate to be coated. The humid coating thus obtained is hardened in an inert gas atmosphere under the influence of ultraviolet radiation.
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公开(公告)号:ES2263988T3
公开(公告)日:2006-12-16
申请号:ES03740207
申请日:2003-06-10
Applicant: BASF AG
Inventor: POPP ANDREAS , DANIEL THOMAS , SCHRODER JURGEN , JAWOREK THOMAS , FUNK RUDIGER , SCHWALM REINHOLD
Abstract: Ésteres F de la fórmula Ia en la que AO significa, independientemente entre sí, para cada AO, EO o PO, significando EO O-CH2-CH2-, PO significa, independientemente entre sí, O-CH2- CH(CH3)- o O-CH(CH3)-CH2- siendo p1 + p2 + p3 3, 4 o 5, R1, R2, R3 significan, independientemente entre sí, H o CH3, donde al menos un AO significa PO y, al menos, otro AO significa EO.
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公开(公告)号:DE50012234D1
公开(公告)日:2006-04-20
申请号:DE50012234
申请日:2000-08-24
Applicant: BASF AG
Inventor: JAWOREK THOMAS , SCHWALM REINHOLD , KOENIGER RAINER , KRANWETVOGEL REINER
IPC: C09D175/16 , B05D3/04 , B05D3/06 , C08F2/46
Abstract: A process for producing scratch-resistant coatings, encompassing the following steps:applying at least one UV-curable coating composition to at least one surface of an article to be coated, said coating composition comprising at least one polymer and/or oligomer P1 containing on average at least one ethylenically unsaturated double bond per molecule, andcuring the coating composition by exposure to UV radiation,which comprises conducting the curing of the coating composition under an oxygen-containing protective gas which has an oxygen partial pressure in the range from 0.2 to 18 kPa.
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公开(公告)号:PL374428A1
公开(公告)日:2005-10-17
申请号:PL37442803
申请日:2003-06-10
Applicant: BASF AG
Inventor: POPP ANDREAS , DANIEL THOMAS , SCHROEDER JUERGEN , JAWOREK THOMAS , FUNK RUEDIGER , SCHWALM REINHOLD , WEISMANTEL MATTHIAS , RIEGEL ULRICH
IPC: A61L15/60 , C07C67/08 , C08F290/06 , C08G65/26 , C08G65/28 , C08G65/332
Abstract: The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where EO is O-CH2-CH2- PO is independently at each instance O-CH2-CH(CH3)- or O-CH(CH3)-CH2- n1, n2 and n3 are independently 4, 5 or 6, n1+n2+n3 is 14, 15 or 16, m1, m2 and m3 are independently 1, 2 or 3, m1+m2+m3 is 4, 5 or 6, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
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