公开(公告)号：IN123CH2000A

公开(公告)日：2005-07-22

申请号：IN123CH2000

申请日：2000-06-16

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  BOTTCHER ARND ,  BREITSCHEIDEL BORIS ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  THIL LUCIEN ,  PINKOS ROLF

IPC: B01J23/46 ,  C07B61/00 ,  C07C51/36 ,  C07C61/08 ,  C07C61/09 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12

Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.

公开(公告)号：CA2260810C

公开(公告)日：2005-05-10

申请号：CA2260810

申请日：1997-09-23

Applicant: BASF AG

Inventor： KAIBEL GERD ,  PINKOS ROLF ,  WULFF-DORING JOACHIM ,  BROCKER FRANZ JOSEF ,  BECKER RAINER

IPC: B01J25/02 ,  B01J8/02 ,  B01J8/06 ,  B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  B01J19/26 ,  C07B61/00 ,  C07C29/17 ,  C07C31/20

Abstract: The invention concerns a process for preparing 1,4-butanediol by continuous catalytic hydrogenation of 1,4-butinediol in that 1,4-butinediol is reacted with hydrogen in the liquid continuous phase in th e presence of a heterogeneous hydrogenation catalyst at temperatures of between 20 and 300 .degree.C, a pressure of between 1 and 20 0 bar and values of the liquid-side mass transfer coefficients k L a, relative to the volume, of between 0.1 s-1 and 1s-1, a) with a catalyst suspended in the reaction medium, wherein, when a packed bubble column is used, it is operated in the upwards mode and at a ratio of the amount of gas leaving the reaction vessel to the amount fed thereto of between 0.99:1 and 0.4:1, or b) is guided upwards in parallel flow throug h a fixed bed reactor operated in the circulating gas mode, the ratio between the amount of gas fed to the reaction vessel and the amount of gas leaving the latter being maintained between 0.99:1 and 0.4:1.

公开(公告)号：DE50008528D1

公开(公告)日：2004-12-09

申请号：DE50008528

申请日：2000-08-23

Applicant: BASF AG

Inventor： FISCHER ROLF ,  PINKOS ROLF

IPC: C07D307/33

Abstract: In a process for preparing GBL by reaction of 1,4 butanediol over a copper catalyst, use is made of a 1,4 butanediol-containing reaction mixture which comprises further alcohols other than 1,4-butanediol and water.

公开(公告)号：AT281444T

公开(公告)日：2004-11-15

申请号：AT00964033

申请日：2000-08-23

Applicant: BASF AG

Inventor： FISCHER ROLF ,  PINKOS ROLF

IPC: C07D307/33

Abstract: In a process for preparing GBL by reaction of 1,4 butanediol over a copper catalyst, use is made of a 1,4 butanediol-containing reaction mixture which comprises further alcohols other than 1,4-butanediol and water.

公开(公告)号：DE59711833D1

公开(公告)日：2004-09-09

申请号：DE59711833

申请日：1997-05-28

Applicant: BASF AG

Inventor： FISCHER ROLF ,  PINKOS ROLF ,  SCHAEFER MARTIN ,  HOEHN ARTHUR ,  SCHWAB PETER

IPC: B01J23/36 ,  B01J23/72 ,  B01J31/24 ,  C07B61/00 ,  C07C41/01 ,  C07C41/26 ,  C07C41/30 ,  C07C43/13 ,  C07C43/15 ,  C07C43/178 ,  C07D307/08

Abstract: A process for preparing tetrahydrofuran, which comprises reacting 1,4-butenediol diethers of the formulae I and/or IIwhere the R radicals can be identical or different and are C1-C15-alkyl or cycloalkyl radicals, C6-C12-aryl radicals or C7-C15-aralkyl radicals, with water and hydrogen at from 20 to 300° C. under from 1 to 300 bar in the presence of catalysts or catalyst combinations which comprise components which are both capable of hydrogenation and have acidic or basic centers and a novel process for preparing 1,4-butanediol diethers of the formula I by metathesis are described.

公开(公告)号：DE10238953A1

公开(公告)日：2004-03-04

申请号：DE10238953

申请日：2002-08-24

Applicant: BASF AG

Inventor： PINKOS ROLF ,  HESSE MICHAEL ,  HAUBNER MARTIN ,  SCHLITTER STEPHAN

IPC: B01J23/80 ,  B01J37/18 ,  C08G65/322 ,  C08G65/331 ,  C08G65/10 ,  C08G65/20

公开(公告)号：ES2200506T3

公开(公告)日：2004-03-01

申请号：ES99910290

申请日：1999-02-26

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF ,  LIANG SHELUE

IPC: C07C29/149 ,  C07C29/80 ,  C07C31/20 ,  C07C45/82 ,  C07C47/19 ,  C07D307/20

Abstract: A process for the separation by distillation of a mixture of 1,4-butanediol and at least one 4-hydroxybutyraldehyde, its cyclic hemiacetal and its cyclic full acetals with at least one further alcohol by carrying out the distillation in the presence of an alkaline compound. The mixture to be separated preferably contains a cyclic full acetal of 4-hydroxybutyraldehyde with a further alcohol which has a lower boiling point than butanediol and also the further alcohol in free form. The process is particularly suitable for the separation by distillation of mixtures formed in the hydrogenation of maleic acid derivatives.

公开(公告)号：MX218972B

公开(公告)日：2004-02-04

申请号：MXPA00005882

申请日：2000-06-15

Applicant: BASF AG

Inventor： PINKOS ROLF ,  THIL LUCIEN ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  BREITSCHEIDEL BORIS ,  BOTTCHER ARND ,  BRUNNER MELANIE

IPC: B01J23/46 ,  C07B61/00 ,  C07C51/36 ,  C07C61/08 ,  C07C61/09 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12

公开(公告)号：AU2003222308A1

公开(公告)日：2003-11-17

申请号：AU2003222308

申请日：2003-04-25

Applicant: BASF AG

Inventor： BOTTKE NILS ,  SCHLITTER STEPHAN ,  HESSE MICHAEL ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR ,  PINKOS ROLF ,  FISCHER ROLF-HARTMUTH ,  ROSCH MARKUS

IPC: C07D307/33 ,  B01J21/08 ,  B01J23/72 ,  C07B61/00 ,  C07D307/20

Abstract: The present invention relates to a process for preparing unsubstituted or C 1 -C 4 -alkyl-substituted gamma-butyrolactone by catalytic hydrogenation of maleic acid and/or its derivatives in the presence of chromium-free catalyst comprising from 10 to 80% by weight of copper oxide and from 10 to 90% by weight of at least one catalyst support selected from the group consisting of silicon dioxide, titanium dioxide, hafnium dioxide, magnesium silicate, activated carbon, silicon carbide, zirconium dioxide and alpha-aluminum oxide.

公开(公告)号：MY115224A

公开(公告)日：2003-04-30

申请号：MYPI9604987

申请日：1996-11-28

Applicant: BASF AG

Inventor： BROCKER FRANZ JOSEF ,  KAIBEL GERD ,  FISCHER ROLF ,  PINKOS ROLF

IPC: C07D307/08 ,  B01J37/02 ,  C23C14/16

Abstract: IN A PROCESS FOR THE CATALYTIC HYDROGENATION OF 2, 5- AND 2, 3-DIHYDROFURAN WITH HYDROGEN TO GIVE TETRAHYDROFURAN, USE IN MADE OF A CATALYST IN WHICH A METAL OR A PLURALITY OF METALS HAVE BEEN DEPOSITED BY VAPOR DEPOSITION OR SPUTTERING ON A METAL WIRE MESH OR A METAL FOIL AS SUPPORT.