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公开(公告)号:DK44588D0
公开(公告)日:1988-01-29
申请号:DK44588
申请日:1988-01-29
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN , REICHEL FRITZ , RIEBELING ULRICH , HOEHR LOTHAR
IPC: C08F2/22 , C08F2/44 , C08F4/28 , C08F20/52 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/42 , C08F220/56 , C08F251/00 , D21H17/28 , D21H17/37 , D21H19/20 , D21H19/24 , D21H21/16 , D21H3/46
Abstract: Sizing agents for paper are based on finely divided aqueous dispersions of copolymers obtainable by copolymerizing from 40 to 140 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers, the weight percentages (a), (b) and (c) always adding up to 100, in the manner of an emulsion polymerization in 100 parts by weight of an aqueous solution containing in solution from 2.7 to 15% by weight of a degraded starch having a viscosity ni from 0.04 to less than 0.12 dl/g at from 40 DEG to 100 DEG C. in the presence of a peroxide initiator.
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公开(公告)号:ES2089839T3
公开(公告)日:1996-10-01
申请号:ES93919142
申请日:1993-08-23
Applicant: BASF AG
Inventor: DE CLERCQ ARNOLD , ETTL ROLAND , GONCALVES CARLOS ALBERTO , HOEHR LOTHAR , HOHMANN ANDREAS , RIEBELING ULRICH
Abstract: PCT No. PCT/EP93/02259 Sec. 371 Date Mar. 1, 1995 Sec. 102(e) Date Mar. 1, 1995 PCT Filed Aug. 23, 1993 PCT Pub. No. WO94/05855 PCT Pub. Date Mar. 17, 1994.Paper size mixtures which are prepared by mixing an aqueous suspension of a digested cationic starch with a finely divided, aqueous polymer dispersion which is the paper size and emulsifying the C14-C22-alkyldiketene in this mixture at not less than 70 DEG C. are used for engine and surface sizing of the paper.
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公开(公告)号:DE59303206D1
公开(公告)日:1996-08-14
申请号:DE59303206
申请日:1993-08-23
Applicant: BASF AG
Inventor: DE CLERCQ ARNOLD , ETTL ROLAND , GONCALVES CARLOS ALBERTO , HOEHR LOTHAR , HOHMANN ANDREAS , RIEBELING ULRICH
Abstract: PCT No. PCT/EP93/02259 Sec. 371 Date Mar. 1, 1995 Sec. 102(e) Date Mar. 1, 1995 PCT Filed Aug. 23, 1993 PCT Pub. No. WO94/05855 PCT Pub. Date Mar. 17, 1994.Paper size mixtures which are prepared by mixing an aqueous suspension of a digested cationic starch with a finely divided, aqueous polymer dispersion which is the paper size and emulsifying the C14-C22-alkyldiketene in this mixture at not less than 70 DEG C. are used for engine and surface sizing of the paper.
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公开(公告)号:ES2018508T5
公开(公告)日:1995-08-01
申请号:ES87111490
申请日:1987-08-08
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN DR , REICHEL FRITZ DR , RIEBELING ULRICH , HOEHR LOTHAR DR
IPC: C08F220/12 , C08F2/22 , C08F2/24 , C08F220/10 , C08F220/18 , C08F220/42 , C08F251/00 , C08F290/00 , D21H17/28 , D21H17/37 , D21H17/55 , D21H21/16
Abstract: Sizes for paper are based on finely divided aqueous dispersions of copolymers which are obtainable by copolymerization of from 10 to 56 parts by weight of a monomer mixture of (a) from 20 to 65% by weight of (meth)acrylonitrile, (b) from 35 to 80% by weight of one or more acrylates of monohydric, saturated C3-C8-alcohols and (c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers by an emulsion polymerization method in 100 parts by weight of an aqueous solution of from 1.7 to 25% by weight of a degraded starch having a viscosity eta i of from 0.12 to 0.50 dl/g, at from 40 DEG to 100 DEG C. in the presence of a peroxide-containing initiator.
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公开(公告)号:FI92213C
公开(公告)日:1994-10-10
申请号:FI880037
申请日:1988-01-06
Applicant: BASF AG
Inventor: DEGEN HANS-JUERGEN , REICHEL FRITZ , RIEBELING ULRICH , HOEHR LOTHAR
IPC: C08F2/22 , C08F2/44 , C08F4/28 , C08F20/52 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/42 , C08F220/56 , C08F251/00 , D21H17/28 , D21H17/37 , D21H19/20 , D21H19/24 , D21H21/16 , C08F220/44 , C08L3/04 , C08L33/20 , C08L33/08
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公开(公告)号:AU4951693A
公开(公告)日:1994-03-29
申请号:AU4951693
申请日:1993-08-23
Applicant: BASF AG
Inventor: CLERCQ ARNOLD DE , ETTL ROLAND , ALVES CARLOS ALBERTO GON , HOEHR LOTHAR , HOHMANN ANDREAS , RIEBELING ULRICH
Abstract: PCT No. PCT/EP93/02259 Sec. 371 Date Mar. 1, 1995 Sec. 102(e) Date Mar. 1, 1995 PCT Filed Aug. 23, 1993 PCT Pub. No. WO94/05855 PCT Pub. Date Mar. 17, 1994.Paper size mixtures which are prepared by mixing an aqueous suspension of a digested cationic starch with a finely divided, aqueous polymer dispersion which is the paper size and emulsifying the C14-C22-alkyldiketene in this mixture at not less than 70 DEG C. are used for engine and surface sizing of the paper.
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公开(公告)号:FI933829A
公开(公告)日:1994-03-02
申请号:FI933829
申请日:1993-09-01
Applicant: BASF AG
Inventor: DE CLERCQ ARNOLD , ETTL ROLAND , GONCALVES CARLOS ALBERTO , HOEHR LOTHAR , HOHMANN ANDREAS , RIEBELING ULRICH
Abstract: PCT No. PCT/EP93/02259 Sec. 371 Date Mar. 1, 1995 Sec. 102(e) Date Mar. 1, 1995 PCT Filed Aug. 23, 1993 PCT Pub. No. WO94/05855 PCT Pub. Date Mar. 17, 1994.Paper size mixtures which are prepared by mixing an aqueous suspension of a digested cationic starch with a finely divided, aqueous polymer dispersion which is the paper size and emulsifying the C14-C22-alkyldiketene in this mixture at not less than 70 DEG C. are used for engine and surface sizing of the paper.
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公开(公告)号:DK0437764T3
公开(公告)日:1993-08-30
申请号:DK90124486
申请日:1990-12-18
Applicant: BASF AG
Inventor: HOHMANN ANDREAS DR , KSOLL PETER DR , HAHN ERWIN DR , WITTMER PETER , DE CLERQ ARNOLD DR , RIEBELING ULRICH
IPC: B01J13/00 , C07C45/90 , C07C49/88 , C09K23/00 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:DE4032660A1
公开(公告)日:1992-04-16
申请号:DE4032660
申请日:1990-10-15
Applicant: BASF AG
Inventor: KROENER MICHAEL DR , NILZ CLAUDIA DR , SENDHOFF NORBERT DR , STANGE ANDREAS DR , CLERCQ ARNOLD DE DR , RIEBELING ULRICH
Abstract: According to a paper, paperboard and cardboard internal sizing process, resin size is used, as well as cationic polymers containing polymerized vinylamine units as fixing agents for the resin size.
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公开(公告)号:AU6940491A
公开(公告)日:1991-07-25
申请号:AU6940491
申请日:1991-01-17
Applicant: BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , CLERCQ ARNOLD DE , RIEBELING ULRICH
IPC: C09K23/00 , B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , B01F17/00
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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