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    33.
    发明专利
    未知

    公开(公告)号：DE4306608A1

    公开(公告)日：1994-11-24

    申请号：DE4306608

    申请日：1993-03-03

    Applicant: BASF AG

    Inventor： LINHART FRIEDRICH DR ,  MOENCH DIETMAR DR ,  SCHERR GUENTER DR ,  REUTHER WOLFGANG DR ,  LORENCAK PRIMOZ DR

    IPC: C08F2/44 ,  C08G18/58 ,  C08G59/18 ,  C08G59/40 ,  C08G73/00 ,  C09D17/00 ,  C09D133/02 ,  C09D133/04 ,  C09D171/00 ,  C09D171/02 ,  C09D175/00 ,  C09D175/04 ,  C09D177/00 ,  C09D179/00 ,  C09K23/52 ,  D21H17/54 ,  D21H17/55 ,  D21H17/56 ,  D21H17/57 ,  B01F17/52 ,  D21H17/74

    Abstract: PCT No. PCT/EP94/00480 Sec. 371 Date Aug. 23, 1995 Sec. 102(e) Date Aug. 23, 1995 PCT Filed Feb. 19, 1994 PCT Pub. No. WO94/20681 PCT Pub. Date Sep. 15, 1994Aqueous pigment slurries which contain up to 80% by weight of a finely divided pigment in dispersed form and from 0.1 to 5% by weight of dispersants which are obtainable by reacting (a) polyalkylenepolyamines, polyamidoamines, polyamidoamines grafted with ethyleneimine, polyetheramines and mixtures of the stated compounds and (b) monoethylenically unsaturated carboxylic acids, salts, esters, amides or nitriles of monoethylenically unsaturated carboxylic acids, chlorocarboxylic acids and/or glycidyl compounds and, if required, (c) bifunctional or polyfunctional crosslinking agents which have a halohydrin, glycidyl, aziridine or isocyanate unit or a halogen atom as a functional group, to give water-soluble condensates which, in 20% strength by weight aqueous solution at 20 DEG C., have a viscosity of at least 100 mPa.s are prepared by milling or dispersing pigments in the presence of the dispersants and water and are used as additives to paper stock in the production of filler-containing paper.

    34.
    发明专利
    未知

    公开(公告)号：DE59808038D1

    公开(公告)日：2003-05-28

    申请号：DE59808038

    申请日：1998-10-14

    Applicant: BASF AG

    Inventor： GREINDL THOMAS DR ,  SCHERR GUENTER DR ,  SCHNEIDER ROLF DR ,  MUNDINGER KLAUS DR

    IPC: C07C277/02 ,  C07C273/18 ,  C07C275/70 ,  C07C277/08 ,  C07C279/04 ,  C07C279/14 ,  C07C303/22 ,  C07C303/30 ,  C07C309/15 ,  C07C309/69 ,  C07C311/47 ,  C08G65/333 ,  C08G73/02

    Abstract: Preparation of guanidine derivatives comprises reacting calcium cyanamide with an alcohol to form an isourea derivative and reacting the isourea derivative with an amine. Preparation of guanidine derivatives of formula H2N-C(=NH)-N(R )(R ) (I) comprises (a) reacting calcium cyanamide with an alcohol of formula R OH to form an isourea derivative of formula H2N-C(=NH)-OR (II), and (b) reacting (II) with an amine of formula HN(R )(R ) (III), where R = H, 1-20C alkyl, 2-10C alkenyl or 3-8C cycloalkyl; R = 1-20C alkyl, 2-10C alkenyl, 3-8C cycloalkyl, ACOOR , ACONR R , ACN, ASO2R or Ä(CH2)mXÜpÄ(CH2)nYÜqÄ(CH2)oÜrZ; A = 1-20C alkylene; m, n and o = 0-10; p, q and r = 0-50000; X = O or NH; Y = NÄ(CH2)mXÜpÄ(CH2)nYÜqÄ(CH2)oÜrZ; Z = OH or NH2; R = H, 1-20C alkyl, 2-10C alkenyl, 3-8C cycloalkyl, 6-18C aryl, Na, K, Li, Ca, Mg or N(R )4; R , R = H, 1-20C alkyl, 2-10C alkenyl, 3-8C cycloalkyl or 6-18C aryl; R = OR or N(R )2; R = H or 1-20C alkyl; R = H, 1-20C alkyl, 2-10C alkenyl, 3-8C cycloalkyl, 6-18C aryl, Na, K, Li, Ca, Mg or N(R )4; R = H, 1-20C alkyl, 2-10C alkenyl, 3-8C cycloalkyl or 6-18C aryl; and R = 1-20C alkyl.

    38.
    发明专利
    未知

    公开(公告)号：DE19748696A1

    公开(公告)日：1999-05-06

    申请号：DE19748696

    申请日：1997-11-04

    Applicant: BASF AG

    Inventor： GREINDL THOMAS DR ,  SCHERR GUENTER DR ,  SCHNEIDER ROLF DR ,  MUNDINGER KLAUS DR

    IPC: C07C277/00 ,  C07C277/08 ,  C07C279/04 ,  C07C279/08 ,  C07C279/12 ,  C07C279/14 ,  C07C279/16 ,  C07C303/30 ,  C07C303/40 ,  C07C309/76 ,  C07C311/05 ,  C08G65/333 ,  C08G73/02 ,  C07B43/00 ,  C08G65/26

    Abstract: Preparation of substituted guanidine derivatives (I) involves alkylating urea and reacting the obtained alkylated isourea (II) with a primary or secondary amine (III). Preparation of a substituted guanidine derivative of formula (I) involves: (a) converting urea into an alkylated isourea of formula (II); and (b) reacting (II) with an amine of formula (III). (a) R1 = H, alkyl, alkenyl or cycloalkyl; R2 = alkyl, alkenyl, cycloalkyl, -Q-COOR3, -Q-CONR4R5, -Q-CN, -Q-SO2R6 or -((CH2)mX)p-((CH2)nY)q-((CH2)o)r-Z; m,n,o = 0-10; p,q,r = 0-5000; X = O or NH; Y = N-((CH2)mX)p-((CH2)nY)q-((CH2)o)r-Z; Z = OH or NH2; R3 = H, alkyl, alkenyl, cycloalkyl, aryl, Na, K, Li, Ca, Mg or N(R7)4; R4,R5 = H, alkyl, alkenyl, cycloalkyl or aryl; R6 = OR8 or N(R9)2; R7 = H or alkyl; R8 = as R3; R9 = as R4; R10 = alkyl; alkyl = 1-20C, alkenyl 2-10C, cycloalkyl 3-8C and aryl 6-18C.

    39.
    发明专利
    未知

    公开(公告)号：DE19544739A1

    公开(公告)日：1997-06-05

    申请号：DE19544739

    申请日：1995-12-01

    Applicant: BASF AG

    Inventor： MOHR JUERGEN DR ,  MAHR NORBERT DR ,  FUNHOFF ANGELIKA DR ,  LEININGER HARTMUT DR ,  MALLM HEIKE ,  MEIXNER HUBERT DR ,  OPPENLAENDER KNUT DR ,  SCHERR GUENTER DR ,  WEISER JUERGEN DR

    IPC: C08G73/02 ,  C08G73/04 ,  C08G65/26

    Abstract: The invention relates to a process for the preparation of hydroxyalkylated polyethyleneimines by hydroxyalkylation of polyethyleneimines in one or two procedural stages to form reaction products which contain 1 to 200 mol alkylene oxide groups per NH group in the polyethyleneimine. In the one-stage process, there are anhydrous polyethyleneimines and 1 to 20 mol %, in relation to the polyethyleneimines, of at least one anhydrous base, or aqueous solutions of said substances are dehydrated and after removing all the water are reacted at temperatures above 135-150 DEG C with at least one alkylene oxide. Alternatively, in the two-stage process, in the first stage polyethyleneimine is reacted at temperatures of from 80 to 100 DEG C with 0.7 to 0.9 mol, in relation to a mol NH group in the polymerisate, of at least one alkylene oxide in an aqueous solution, and in the second stage the reaction product obtained in the first step is reacted in the presence of 1 to 20 mol %, in relation to polyethyleneimine, of an alkaline catalyst in the absence of water at temperatures of from 120 to 150 DEG C with at least one alkylene oxide to form hydroxyalkylated polyethyleneimines which contain 1 to 200 mol of alkylene oxide groups per NH group in the polyethyleneimine. The consequent alkoxylated products are only slightly coloured.

    Fire resistant plastic materials for film for high elongation
    40.
    发明专利
    Fire resistant plastic materials for film for high elongation 未知

    公开(公告)号：DE4444711A1

    公开(公告)日：1996-06-20

    申请号：DE4444711

    申请日：1994-12-15

    Applicant: BASF AG

    Inventor： MARCZINKE BERND LOTHAR DR ,  MUELLER PATRIK DR ,  KOESSLER LUDWIG ,  SCHERR GUENTER DR ,  BROSIUS SIBYLLE DR ,  GUENTHER ERHARD DR ,  HOFMANN JUERGEN

    IPC: C08K5/3492 ,  C08L23/10 ,  C08L51/06 ,  D01F6/46

    Abstract: Plastic materials with a melt flow index 230/2.16 of 0.1-100 g/10 minutes contain: (a1) propylene homopolymer with a melt flow index 230/2.16 of 0.1-100 g/10 minutes, or(a2) statistical copolymer of propylene and 2-10C alkene-1 with a comonomer content of less than 15 wt.%, or (a3) a mixt. of 25-97 wt.% of a copolymer of propylene and 0.1-15 wt.% 2-10C alkene-1 and 3-75 wt.% of another propylene copolymer contg. 15-80 wt.% 2-10C alkene-1 units, or(a4) a mixt. of 25-97 wt.% propylene homopolymer and 3-75 wt.% propylene/2-10C alkene-1 copolymer, with a comonomer content of 15-80 wt.% w.r.t. the second polymer, (b) a propylene or ethylene polymer grafted with 0.1-5 wt.% alpha , beta -unsatd. carboxylic acid or acid deriv., with a melt flow index 230/2.16 of 0.01-400 g/10 minutes, and (c) a nitrogen cpd. of formula (I): R =H, 1-30C alkyl, 2-30C alkyl or alk-1-enyl substd. with O atom(s) and/or amino gps., or a gp. of formula (II):HO-(CHR -CHR )m- (II)R =H, 1-4C alkyl or amino; andm=1-100. Also claimed are: (i) a process for the prodn. of the materials, by reacting components (a)-(c) together at 180-280 deg C and 1-100 bar for a mean residence time of 0.2-10 minutes; and(ii) film, fibres and mouldings made from the materials.

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