公开(公告)号：AU2003254335A1

公开(公告)日：2004-02-02

申请号：AU2003254335

申请日：2003-07-10

Applicant: BASF AG

Inventor： HARTH KLAUS ,  HIBST HARTMUT ,  SCHINDLER GOTZ-PETER ,  WALSDORFF CHRISTIAN

IPC: B01J23/62 ,  C07B61/00 ,  C07C5/333 ,  C07C11/167

Abstract: The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.

公开(公告)号：CA2493133A1

公开(公告)日：2004-01-22

申请号：CA2493133

申请日：2003-07-10

Applicant: BASF AG

Inventor： HARTH KLAUS ,  HIBST HARTMUT ,  WALSDORFF CHRISTIAN ,  SCHINDLER GOETZ-PETER

IPC: B01J23/62 ,  C07B61/00 ,  C07C5/333 ,  C07C11/167

Abstract: The invention relates to a method for the production of butadiene from n- butane comprising the steps: (a) preparation of a gas feedstream containing n- butane, (b) feeding the gas feedstream containing n-butane into a first dehydrogenation zone with non-oxidative catalytic dehydrogenation of n-butan e to give 1-butene, 2-butene and optionally butadiene, whereby a first gas product stream comprising n-butane, 1-butene, 2-butene, optionally butadiene and optionally by-products is obtained, (c) feeding the first gas product stream comprising n-butane, 1-butene, 2-butene, optionally butadiene and optionally by-products into a second dehydrogenation zone with oxidative dehydrogenation of 1-butene and 2- butene to give butadiene, whereby a secon d gas product stream is obtained comprising butadiene, n-butane, steam and optionally by-products and (d) recovery of butadiene from the second gas product stream.

公开(公告)号：CZ20030139A3

公开(公告)日：2003-06-18

申请号：CZ20030139

申请日：2001-07-16

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  TENTEN ANDREAS ,  HIBST HARTMUT ,  MULLER-ENGEL KLAUS JOACHIM ,  UNVERRICHT SIGNE ,  COX GERHARD

IPC: B01J23/00 ,  B01J23/28 ,  B01J27/057 ,  B01J37/02 ,  C07B61/00 ,  C07C45/33 ,  C07C45/35 ,  C07C51/215 ,  C07C57/05 ,  B01J23/883 ,  C07C57/04

CPC classification number: B01J23/002 ,  B01J23/28 ,  B01J27/0576 ,  B01J37/0232 ,  B01J2523/00 ,  C07C51/215 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  C07C57/04

公开(公告)号：CA2414989A1

公开(公告)日：2003-01-02

申请号：CA2414989

申请日：2001-07-02

Applicant: BASF AG

Inventor： SCHWAB EKKEHARD ,  STEINBRENNER ULRICH ,  LINDEN GERD ,  COX GERHARD ,  TENTEN ANDREAS ,  BOHNER GERD ,  SIGWART CHRISTOPH ,  HIBST HARTMUT ,  FISCHER ROLF-HARTMUTH ,  HESSE MICHAEL ,  HAUBNER MARTIN ,  NARBESHUBER THOMAS

IPC: C08G65/10 ,  B01J21/06 ,  B01J23/28 ,  B01J23/30 ,  B01J27/188 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C08G65/20 ,  C08G65/26 ,  B01J23/20 ,  B01J23/24

Abstract: The invention relates to a catalyst which contains a catalytically active quantity of at least one oxygen-containing molybdenum and/or wolfram compound on an oxidic support material and which has been calcinated at temperatures of 400 to 900° C. after the precursor compound of the catalytically active compounds have been applied to the support material or to a support material precursor. The transport pores for this catalyst each have a diameter of >25 nm and a volume of at least 50 mm /g. The catalyst contains x mumol (wolfram and/or molybdenum)/m molybdenum and/or wolfram, with 10.1 /g. Catalysts of this type are characterized by an acidity of at least 70 mumol/g at pKs

公开(公告)号：ES2175744T3

公开(公告)日：2002-11-16

申请号：ES98937471

申请日：1998-06-10

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  RIEBER NORBERT ,  BREUER KLAUS ,  DEMUTH DIRK ,  HIBST HARTMUT ,  ETZRODT HEINZ

IPC: B01J21/16 ,  C07B61/00 ,  C07C41/08 ,  C07C41/28 ,  C07C43/15 ,  C07C43/16

Abstract: Enol ethers of the formula Iwhere R1 is an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical which may carry further substituents which do not react with acetylenes or allenes, and the radicals R, independently of one another, are hydrogen or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radicals, which may be bonded to one another to form a ring, and m is 0 or 1, are prepared by reacting an acetal or ketal of the formula IIwith an acetylene or allene of the formula III or IVwhere R and R1 have the abovementioned meanings, in the gas phase at elevated temperatures in the presence of a zinc- or cadmium- and silicon- and oxygen-containing heterogeneous catalyst.

公开(公告)号：DE59803528D1

公开(公告)日：2002-05-02

申请号：DE59803528

申请日：1998-06-10

Applicant: BASF AG

Inventor： TELES HENRIQUE ,  RIEBER NORBERT ,  BREUER KLAUS ,  DEMUTH DIRK ,  HIBST HARTMUT ,  ETZRODT HEINZ ,  RHEUDE UDO

IPC: B01J21/16 ,  C07B61/00 ,  C07C41/08 ,  C07C41/28 ,  C07C43/15 ,  C07C43/16

Abstract: Enol ethers of the formula Iwhere R1 is an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical which may carry further substituents which do not react with acetylenes or allenes, and the radicals R, independently of one another, are hydrogen or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radicals, which may be bonded to one another to form a ring, and m is 0 or 1, are prepared by reacting an acetal or ketal of the formula IIwith an acetylene or allene of the formula III or IVwhere R and R1 have the abovementioned meanings, in the gas phase at elevated temperatures in the presence of a zinc- or cadmium- and silicon- and oxygen-containing heterogeneous catalyst.

公开(公告)号：HU0104939A2

公开(公告)日：2002-04-29

申请号：HU0104939

申请日：1999-11-10

Applicant: BASF AG

Inventor： BAUER STEFAN ,  DIETRICH ULF ,  HEIDEMANN THOMAS ,  HIBST HARTMUT

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31

Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

公开(公告)号：AU8193701A

公开(公告)日：2002-01-14

申请号：AU8193701

申请日：2001-07-02

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  NARBESHUBER THOMAS ,  HAUBNER MARTIN ,  SIGWART CHRISTOPH ,  LINDEN GERD ,  COX GERHARD ,  FISCHER ROLF-HARTMUTH ,  HESSE MICHAEL ,  BOHNER GERD ,  HIBST HARTMUT ,  SCHWAB EKKEHARD ,  TENTEN ANDREAS

IPC: C08G65/10 ,  B01J21/06 ,  B01J23/28 ,  B01J23/30 ,  B01J27/188 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C08G65/20 ,  C08G65/26 ,  B01J23/20 ,  B01J23/24

Abstract: The invention relates to a catalyst which contains a catalytically active quantity of at least one oxygen-containing molybdenum and/or wolfram compound on an oxidic support material and which has been calcinated at temperatures of 400 to 900° C. after the precursor compound of the catalytically active compounds have been applied to the support material or to a support material precursor. The transport pores for this catalyst each have a diameter of >25 nm and a volume of at least 50 mm /g. The catalyst contains x mumol (wolfram and/or molybdenum)/m molybdenum and/or wolfram, with 10.1 /g. Catalysts of this type are characterized by an acidity of at least 70 mumol/g at pKs

公开(公告)号：AU7410501A

公开(公告)日：2002-01-02

申请号：AU7410501

申请日：2001-06-15

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  TENTEN ANDREAS ,  HIBST HARTMUT ,  MULLER-ENGEL KLAUS JOACHIM

IPC: C07C45/33 ,  C07C45/35 ,  C07C57/05 ,  C07C51/215 ,  B01J23/28

公开(公告)号：SK5822001A3

公开(公告)日：2001-10-08

申请号：SK5822001

申请日：1999-11-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31

Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.