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    52.
    发明专利
    未知

    公开(公告)号：AT153347T

    公开(公告)日：1997-06-15

    申请号：AT94909115

    申请日：1994-03-05

    Applicant: BASF AG

    Inventor： KRONER MATTHIAS ,  SCHORNICK GUNNAR ,  DENZINGER WALTER ,  BAUR RICHARD ,  KUD ALEXANDER ,  POTTHOFF-KARL BIRGIT ,  SCHWENDEMANN VOLKER

    IPC: C08F8/14 ,  C08F8/30 ,  C08F8/44 ,  C08F8/48 ,  C08G69/10 ,  C08G73/06 ,  C08G73/10 ,  C09K23/00 ,  C09K23/52 ,  C11D3/37

    Abstract: PCT No. PCT/EP94/00660 Sec. 371 Date Sep. 13, 1995 Sec. 102(e) Date Sep. 13, 1995 PCT Filed Mar. 5, 1994 PCT Pub. No. WO94/21695 PCT Pub. Date Sep. 29, 1994Polycocondensates based on aspartic acid which are obtainable by condensing aspartic acid in the presence of polymers containing carboxyl groups, which contain at least 10 mol % of a monoethylenically unsaturated carboxylic acid in copolymerized form and have a molecular weight of at least 300, in the weight ratio from 1,000:1 to 2:1, processes for preparing the polycocondensates and use of the polycocondensates in the form of the free acid groups or in a form neutralized with ammonia, amines, alkali metal or alkaline earth metal bases as an additive to detergents and cleaners, as scale inhibitors or as dispersants for finely divided solids are described.

    54.
    发明专利
    未知

    公开(公告)号：DE59305089D1

    公开(公告)日：1997-02-20

    申请号：DE59305089

    申请日：1993-08-16

    Applicant: BASF AG

    Inventor： FUNHOFF ANGELIKA ,  MC KEE GRAHAM ,  HARTMANN HEINRICH ,  BAUR RICHARD ,  KUD ALEXANDER ,  SCHWENDEMANN VOLKER

    IPC: C08G2/12 ,  C08G2/18 ,  C08G2/28 ,  C08G2/30 ,  C08G4/00 ,  C08G12/18 ,  C09K23/00 ,  C09K23/52 ,  C11D3/37

    Abstract: PCT No. PCT/EP93/02176 Sec. 371 Date Feb. 2, 1995 Sec. 102(e) Date Feb. 2, 1995 PCT Filed Aug. 16, 1993 PCT Pub. No. WO94/04585 PCT Pub. Date Mar. 3, 1994.A process for preparing polyacetals by copolymerization of glyoxylic esters with other copolymerizable monomers in the presence of anionic or cationic polymerization initiators, with or without the introduction of stable end groups and with or without hydrolysis of the copolymerized units of glyoxylic ester present in the copolymer comprises using as monomers cyclic formals derived from diols, homopolymers of formaldehyde, trioxepane or mixtures thereof, although up to 50% by weight of this group of monomers may be replaced by other customary copolymerizable monomers, and the poly(acetal-carboxylate)s thus obtainable are useful as additives in reduced-phosphate and phosphate-free detergents and cleaners, as water treatment agents and as dispersants for finely divided substances.

    55.
    发明专利
    未知

    公开(公告)号：ES2092817T3

    公开(公告)日：1996-12-01

    申请号：ES93906587

    申请日：1993-03-23

    Applicant: BASF AG

    Inventor： BURKHART BERND ,  OFTRING ALFRED ,  SCHWENDEMANN VOLKER ,  GLASER KLAUS

    IPC: C07F9/54 ,  C25D3/12 ,  C25D3/14

    Abstract: PCT No. PCT/EP93/00695 Sec. 371 Date Sep. 30, 1994 Sec. 102(e) Date Sep. 30, 1994 PCT Filed Mar. 23, 1993 PCT Pub. No. WO93/20087 PCT Pub. Date Oct. 14, 1993.Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and one or more brighteners by a procedure in which the brighteners used are phosphonium salts I (I) where R1 to R3 are each C1-C18-alkyl, which may be carboxyl-, C1-C4-alkoxycarbonyl- or cyano-substituted, C2-C12-alkenyl, C2-C12-alkynyl, C5-C8-cycloalkyl, C7-C12-phenylalkyl, phenyl, which may be substituted by one or two substituents selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy, halogen, hydroxyl, phenyl and C1-C4-alkoxycarbonyl, or mono- or di(C1-C4-alkyl)amino, R4 and R5 are each hydrogen or C1-C4-alkyl, A is hydrogen or a group of the formula -CO-H, -CO-R6, -CO-OH, -CO-OR6, -CO-CH2-CO-OR6, -O-CO-H, -O-CO-R6, -OR6, -SO2-R6, -SO2-OH, -SO2-OR6, -PO(OH)2, -PO(OH)(OR6), -PO(OR6)2, -OPO(OH)2, -OPO(OH)(OR6) or -OPO(OR6)2, where R6 is C1-C12-alkyl, C2-C12-alkenyl, C2-C12-alkynyl, C5-C8-cycloalkyl, C7-C12-phenylalkyl or phenyl, which may be substituted by one or two substituents selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy, halogen, hydroxyl, phenyl and C1-C4-alkoxycarbonyl, Y is -CH=CH- or -C=C-, m is from 0 to 10, n is from 1 to 4, p is 0 or 1, q is from 0 to 10, and X(-) is an n-valent inorganic or organic anion that promotes solubility in water.

    56.
    发明专利
    未知

    公开(公告)号：ES2080514T3

    公开(公告)日：1996-02-01

    申请号：ES92918765

    申请日：1992-09-04

    Applicant: BASF AG

    Inventor： KRONER MATTHIAS ,  HARTMANN HEINRICH ,  WOLF GERHARD ,  BAUR RICHARD ,  DIESSEL PAUL ,  JAEGER HANS-ULRICH ,  SCHWENDEMANN VOLKER ,  PERNER JOHANNES

    IPC: C08F16/14 ,  C08F216/14 ,  C11D3/37

    Abstract: PCT No. PCT/EP92/02041 Sec. 371 Date Feb. 10, 1994 Sec. 102(e) Date Feb. 10, 1994 PCT Filed Sep. 4, 1992 PCT Pub. No. WO93/06142 PCT Pub. Date Apr. 1, 1993Copolymers of hydroxyalkyl vinyl ethers are obtainable by cationic or free radical copolymerization of (a) from 99 to 1% by weight of a hydroxyalkyl vinyl ether, (b) from 1 to 99% by weight of an adduct of a C2-C4-alkylene oxide with a hydroxyalkyl vinyl ether and (c) from 0 to 98% by weight of other copolymerizable monomers, and the stated copolymer and hydroxyalkyl vinyl ethers polymerized by cationic or free radical polymerization, which contain the monomers (a) or (b) as sole monomers or as a mixture with other copolymerizable monomers in the form of polymerized units, are used as additives for detergents and cleaning agents in amounts of from 0.1 to 50% by weight.

    COPOLYMERS CONTAINING VINYL FORMATE UNITS, METHOD OF PRODUCING THEM AND THEIR USE IN WASHING AND CLEANING AGENTS
    57.
    发明专利
    COPOLYMERS CONTAINING VINYL FORMATE UNITS, METHOD OF PRODUCING THEM AND THEIR USE IN WASHING AND CLEANING AGENTS 未知

    公开(公告)号：CA2193126A1

    公开(公告)日：1995-12-21

    申请号：CA2193126

    申请日：1995-05-31

    Applicant: BASF AG

    Inventor： BOECKH DIETER ,  KISTENMACHER AXEL ,  DENZINGER WALTER ,  RUEHL THOMAS ,  FUNHOFF ANGELIKA ,  BAUR RICHARD ,  KUD ALEXANDER ,  SCHWENDEMANN VOLKER

    IPC: C08F218/06 ,  C08F220/04 ,  C08F222/02 ,  C11D3/37 ,  C08F222/04

    Abstract: Vinyl formate copolymers, preparation thereof, and use thereof in detergents and cleaners Copolymers containing (a) from 5 to 90 mol% of vinyl formate units, (b) from 10 to 95 mol% of units of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol% of units of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol% of units of other monoethylenically unsaturated monomers in copolymerized form and having K values of at least 8 (determined by the method of H. Fikentscher in 1% strength by weight aqueous solution on the sodium salt of the copolymers at pH 7 and 25 C), processes for their preparation by copolymerizing monomer mixtures of (a) from 5 to 90 mol% of vinyl formate, (b) from 10 to 95 mol% of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol% of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol% of other monoethylenically unsaturated monomers in an aqueous medium or in an organic solvent in the presence of free-radical polymerization initiators and use of the vinyl formate copolymers and of the vinyl alcohol copolymers obtainable therefrom by hydrolysis and/or oxidation as detergent and cleaner additives.

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