公开(公告)号：TR200101404T2

公开(公告)日：2002-01-21

申请号：TR200101404

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOETZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  BAYETO JUAN JOSE AISCAR

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：DE10031755A1

公开(公告)日：2002-01-10

申请号：DE10031755

申请日：2000-06-29

Applicant: BASF AG

Inventor： HENKELMANN JOCHEM ,  BECKER HEIKE ,  AISCAR BAYETO JUAN JOSE ,  TROFIMOV BORIS ,  GUSAROVA NINA K ,  OPARINA LUDMILLA

IPC: C07C41/08 ,  C07B41/04 ,  C07C41/06 ,  C07C43/15

Abstract: Preparation of enol ethers (I) by reacting alcohols (II) with alkynes (IIIA) and/or alkadienes (IIIB) and is carried out in the presence of an alkali alcoholate and a polar aprotic solvent. Preparation of enol ethers of formula (I) by reacting alcohols of formula (II) with alkynes of formula (IIIA) and/or alkadienes of formula (IIIB) of the given formulae is carried out in the presence of an alkali alcoholate and a polar aprotic solvent. R1-R3 = H or an organic group containing carbon; and R4 = optionally substituted alkyl.

公开(公告)号：AU4648501A

公开(公告)日：2001-09-12

申请号：AU4648501

申请日：2001-02-28

Applicant: BASF AG

Inventor： STAMM ARMIN ,  KNEUPER HEINZ-JOSEF ,  HENKELMANN JOCHEM ,  WEBER THEODOR ,  BUSCH RALPH

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/60 ,  C07C55/40 ,  C07C53/50

Abstract: The invention relates to a method for producing chlorocarboxylic acid chlorides of formula (I), wherein R and R , independently from one another, mean a hydrogen atom, an organic radical containing carbon, a halogen, a nitro or cyano group and Y means an alkylene chain having 1 to 10 carbon atoms in the chain which is unsubstituted or is substituted by organic radicals that contain carbon, by halogen, nitro and/or cyano groups, whereby the alkylene chain can be interrupted by an ether-, thioether-, tertiary amino- or keto group, whereby the organic radicals of Y and/or R and/or R can be connected to one another and thereby form a non-aromatic system, whereby said radicals contain carbon, by converting a lactone of formula (II), wherein R , R and Y have the aforementioned meanings, using a hydrogen chloride and phosgene in the presence of a catalyst. Hydrogen chloride is added before and/or while phosgene is added. The hydrogen chloride is only introduced at a temperature of at least 60 DEG C. A pyridine compound is used as the catalyst.

公开(公告)号：AU1524201A

公开(公告)日：2001-06-18

申请号：AU1524201

申请日：2000-11-27

Applicant: BASF AG

Inventor： GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/60 ,  C07C57/76 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R 1 to R 4 can be the same or different and represent hydrogen C 1 -C 4 alkyl, halogen or trifluoromethyl, by reaction benzo condensed lactones of formula (II), in which R 1 to R 4 have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.

公开(公告)号：CA2393978A1

公开(公告)日：2001-06-14

申请号：CA2393978

申请日：2000-11-27

Applicant: BASF AG

Inventor： GOTZ ROLAND ,  GOTZ NORBERT ,  STAMM ARMIN ,  KNEUPER HEINZ-JOSEF ,  WOLF BERND ,  HENKELMANN JOCHEM

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/09 ,  C07C57/76 ,  C07C51/60 ,  C07C63/04 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzenecarbon yl chlorides of formula (I), wherein R1-R4 can be the same or different and sta nd for hydrogen, C1-C4-alkyl, halogen or trifluoromethyl, by converting benzocondensed lactones of formula (II), wherein R1-R4 have the aforemention ed meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterised in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst.

公开(公告)号：DE19951280A1

公开(公告)日：2001-04-26

申请号：DE19951280

申请日：1999-10-25

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  HILL THOMAS ,  HENKELMANN JOCHEM ,  BOETTCHER ARND ,  ZELLER EDGAR

IPC: C07B61/00 ,  C07C5/11 ,  C07C13/20 ,  C07C29/04 ,  C07C35/08 ,  B01J29/04

Abstract: Preparation of alcohol(s) comprises hydrating an alkene(s) using water and a catalyst(s) comprising a zeolite catalyst(s) of MCM-22, MCM-36, MCM-49, PSH-3 or ITQ-2 structure. An Independent claim is included for an integrated process for preparing alcohols which comprises hydrogenating an educt(s) to give an alkene(s), contacting the reaction mixture with water and a heterogeneous catalyst (comprising the above zeolitic structures) and separating unreacted educt and recycling.

公开(公告)号：DE19943858A1

公开(公告)日：2001-03-15

申请号：DE19943858

申请日：1999-09-13

Applicant: BASF AG

Inventor： BUSCH RALPH ,  KNEUPER HEINZ-JOSEF ,  WEBER THEODOR ,  MUELLER WINFRIED ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07B61/00 ,  C07C51/00 ,  C07C51/64 ,  C07C53/42 ,  C07C57/66

Abstract: The invention relates to a method for purifying acid chlorides which have been produced by converting carboxylic acids with carbon oxychloride or thionyl chloride in the presence of a catalyst adduct. The acid chlorides are treated with a hydro halide of carboxylic acid amides of general formula (I), wherein R stands for hydrogen or C1- to C3-alkyl; R and R , independently from one another, mean C1- to C4-alkyl or R and R together mean a C4- or C5-alkylene chain. The thus purified acid chloride is isolated by separation said acid chloride from the carboxylic acid amide hydro halide-phase.

公开(公告)号：DE19924159A1

公开(公告)日：2000-11-30

申请号：DE19924159

申请日：1999-05-26

Applicant: BASF AG

Inventor： PREISS THOMAS ,  HENKELMANN JOCHEM ,  TROFIMOV BORIS ,  MIKHALEVA ALBINA ,  VASILTCOV ALEXANDER M

IPC: C07C29/44 ,  C07C41/08 ,  C07D317/12 ,  C07D319/06 ,  C07B37/02 ,  C07C33/02 ,  C07C33/18 ,  C07D317/10

Abstract: Preparation of alkene compounds from acetylene and amino, hydroxyl or carboxyl compounds using a mixed CsF/alkali hydroxide catalyst in the absence of DMSO.

公开(公告)号：DE19917051A1

公开(公告)日：2000-10-19

申请号：DE19917051

申请日：1999-04-15

Applicant: BASF AG

Inventor： BOETTCHER ARND ,  HENKELMANN JOCHEM ,  FUNKE FRANK

IPC: B01J23/46 ,  B01J35/10 ,  C07B61/00 ,  C07C5/10 ,  C07C13/18 ,  C07C13/10 ,  C07C13/00

Abstract: In the hydrogenation of mono- or polycyclic aromatics, optionally with alkyl substituent(s), by contact with gas containing hydrogen in the presence of a supported catalyst containing active sub-group VIII metal(s), a support with macropores is used.

公开(公告)号：DE59605800D1

公开(公告)日：2000-09-28

申请号：DE59605800

申请日：1996-09-11

Applicant: BASF AG

Inventor： RUETTNER HEINZ ,  RUEHL THOMAS ,  BREITSCHEIDEL BORIS ,  HENKELMANN JOCHEM ,  HENNE ANDREAS ,  WETTLING THOMAS

IPC: B01J23/46 ,  B01J21/04 ,  B01J23/89 ,  B01J35/10 ,  C07B61/00 ,  C07C209/72 ,  C07C211/35

Abstract: Aromatic compounds in which at least one amino group is bonded to an aromatic nucleus are catalytically hydrogenated in the liquid phase by a process in which the catalyst consists essentially of ruthenium and, optionally at least one metal of subgroup I, VII or VIII in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a carrier which has a mean pore diameter of at least 0.1 mu m and a surface area of not more than 15 m2/g.