67.
    发明专利
    未知

    公开(公告)号:ES2124519T3

    公开(公告)日:1999-02-01

    申请号:ES95902787

    申请日:1994-12-06

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/04057 Sec. 371 Date May 20, 1996 Sec. 102(e) Date May 20, 1996 PCT Filed Dec. 6, 1994 PCT Pub. No. WO95/16020 PCT Pub. Date Jun. 15, 1995The use of polyaspartic acid prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:0.05 to 1:10 at temperatures of at least 120 DEG C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, as additive to detergents and cleaners in amounts of from 0.1 to 10% by weight, and detergents and cleaners which contain polyaspartic acids prepared in the presence of phosphoric acid.

    69.
    发明专利
    未知

    公开(公告)号:AT163439T

    公开(公告)日:1998-03-15

    申请号:AT95929870

    申请日:1995-08-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/03224 Sec. 371 Date Feb. 27, 1997 Sec. 102(e) Date Feb. 27, 1997 PCT Filed Aug. 16, 1995 PCT Pub. No. WO96/06879 PCT Pub. Date Mar. 7, 1996A process for preparing salts of polyaspartic acid by treating polycondensates in aqueous medium with bases, employing at least 0.7 equivalent of an alkali metal and/or alkaline earth metal base per mole of the aspartimide, aspartic acid and/or aspartamide units present in the polycondensates, and the bases being added within from 30 min to 20 hours to an aqueous suspension of polycondensates of aspartic acid which has been heated to 40 DEG -140 DEG C., and the reaction mixture being allowed to react further where appropriate, and the use of alkali metal and/or alkaline earth metal salts of polyaspartic acids obtainable by treating polycondensates of aspartic acid in aqueous medium with more than 1 equivalent of an alkali metal and/or alkaline earth metal base, with the molecular weight of the polycondensates being reduced, as additive to detergents and cleaners.

    70.
    发明专利
    未知

    公开(公告)号:DE59402833D1

    公开(公告)日:1997-06-26

    申请号:DE59402833

    申请日:1994-03-05

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/00660 Sec. 371 Date Sep. 13, 1995 Sec. 102(e) Date Sep. 13, 1995 PCT Filed Mar. 5, 1994 PCT Pub. No. WO94/21695 PCT Pub. Date Sep. 29, 1994Polycocondensates based on aspartic acid which are obtainable by condensing aspartic acid in the presence of polymers containing carboxyl groups, which contain at least 10 mol % of a monoethylenically unsaturated carboxylic acid in copolymerized form and have a molecular weight of at least 300, in the weight ratio from 1,000:1 to 2:1, processes for preparing the polycocondensates and use of the polycocondensates in the form of the free acid groups or in a form neutralized with ammonia, amines, alkali metal or alkaline earth metal bases as an additive to detergents and cleaners, as scale inhibitors or as dispersants for finely divided solids are described.

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