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    61.
    发明专利
    未知

    公开(公告)号：DE19651300A1

    公开(公告)日：1998-06-18

    申请号：DE19651300

    申请日：1996-12-10

    Applicant: BASF AG

    Inventor： MC KEE GRAHAM EDMUND DR ,  JUENGLING STEPHAN DR ,  WARZELHAN VOLKER DR ,  GAUSEPOHL HERMANN DR

    IPC: C08L51/00 ,  C08F20/00 ,  C08F20/12 ,  C08F265/04 ,  C08F297/04 ,  C08L55/02

    Abstract: The invention concerns a process for preparing rubber-modified moulding compounds, characterized in that: a1) a mixture (A) comprising acrylate or methacrylate derivatives or acrylate and methacrylate derivatives and a solvent, optionally containing olefinically unsaturated compounds which are not acrylate or methacrylate derivatives, is anionically polymerized; or that a2) acrylate or methacrylate derivatives or acrylate and methacrylate derivatives are sequentially anionically polymerized to form block copolymers in the presence of a solvent which optionally contains olefinically unsaturated compounds; and b) the reaction mixture obtained according to a1) or a2) or a1) and a2) is subjected to a radically initiated polymerization process, optionally after the addition of further unsaturated compounds.

    64.
    发明专利
    未知

    公开(公告)号：DE19500757A1

    公开(公告)日：1996-07-18

    申请号：DE19500757

    申请日：1995-01-13

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER DR ,  SCHORNICK GUNNAR DR ,  BAUMANN EDWIN ,  SEELIGER URSULA DR ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD DR

    IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30 ,  C08G69/48 ,  C08G69/42 ,  C08G81/00 ,  C08G18/65 ,  C08G63/685 ,  C08K5/09 ,  C08L67/04 ,  C08L3/02

    Abstract: The invention concerns biologically degradable polyester amides P1 obtainable through reaction of a mixture consisting essentially of the following: (a1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0-5 mol % a compound containing sulphonate groups (the sum of the individual molar percentages is 100); (a2) a mixture consisting essentially of: (a21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (a22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino-C5-C10 cycloalkanol, (a23) 0-50 mol % a diamino C1-C8 alkane; and (a24) 0-50 mol % a 2,2`-bisoxazoline of general formula (I), in which R is a single bond, a (CH2)q-alkylene group in which q = 2, 3 or 4, or a phenylene group (the sum of the individual molar percentages is 100 and the molar ratio of a1 to a2 is in the range 0.4:1 - 1.5:1). The polyester amides P1 will have a molecular weight (Mn) in the range 4000-40,000 g/mol, a viscosity number in the range 30-350 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyester amide P1 at a temperature of 25 DEG C) and a melting point in the range 50-220 DEG C; and a quantity of a compound D equivalent to 0-5 mol % of the molar quantity of components (a1) must also be used for the production of the polyester amides P1, said compound D having at least three groups capable of ester formation. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same, the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles, foams and blends with starch which can be obtained from the polymers or moulding materials according to the invention.

    65.
    发明专利
    未知

    公开(公告)号：DE19500755A1

    公开(公告)日：1996-07-18

    申请号：DE19500755

    申请日：1995-01-13

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER DR ,  SCHORNICK GUNNAR DR ,  BRAUN FRANK DR ,  SEELIGER URSULA DR ,  YAMAMOTO MOTONORI ,  BAUER PETER

    IPC: C08G69/40 ,  C08G18/60 ,  C08G69/44 ,  C08G69/48 ,  C08G73/00 ,  C08G73/04 ,  C08J9/04 ,  C08K5/353 ,  C08L77/12 ,  C08L101/16 ,  C09J177/12 ,  D21H19/30 ,  C08G69/42 ,  C08G81/00 ,  C08G18/65 ,  C08G63/685 ,  C08K5/09 ,  C08L67/04

    Abstract: The invention concerns biologically degradable polyether ester amides P1 obtainable through reaction of a mixture consisting essentially of the following: (a1) a mixture consisting essentially of: 20-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-80 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof; 0.5 mol % of a compound containing sulphonate groups, the sum of the molar percentages being 100; (a2) a mixture of dihydroxy compounds consisting essentially of: (a21) 15-99,3 mol % of a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols; (a22) 0.2-85 mol % of a dihydroxy compound containing ether functions, determined by formula I HO-[(CH2)n-O]m-H, wherein n is 2, 3 or 4 and m is an integer between 2 and 250, or mixtures thereof; (a23) 0.5-80 mol % of an amino-C2-C12 alkanol or an amino C5-C10 cycloalkanol; and (a24) 0-50 mol % of a diamino C1-C8 alkane; (a25) 0-50 mol % of a 2,2'-bisoxazoline. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same, the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles made from the polymers or moulding materials according to the invention.

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