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公开(公告)号:MX9911269A
公开(公告)日:2000-04-30
申请号:MX9911269
申请日:1999-12-06
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH , MULLER ULRICH , WALCH ANDREAS , RIEBER NORBERT , FISCHER MARTIN , QUAISER STEFAN , HARDER WOLFGANG , ELLER KARSTEN , BASSLER PETER , WENZEL ANNE , KAIBEL GERD , STAMMER ACHIM , HENKELMANN JOCHEM , BOTTCHER ARND , TELES JOAQUIM HENRIQUE , SCHULZ MICHAEL , TREIBER GERT
IPC: B01J29/90 , B01J38/14 , C07B41/00 , C07B61/00 , C07D301/12 , C07D301/19
Abstract: A process for oxidizing an organic compound having at least one C-C double bond or a mixture of two or more thereof comprises the following steps:(I) preparing a hydroperoxide,(II) reacting an organic compound having at least one C-C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst,(III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and(IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).
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公开(公告)号:DE59506908D1
公开(公告)日:1999-10-28
申请号:DE59506908
申请日:1995-07-07
Applicant: BASF AG
Inventor: MUELLER ULRICH , LINGELBACH PETER , BASSLER PETER , HARDER WOLFGANG , ELLER KARSTEN , KOHL VERONIKA , DEMBOWSKI JUERGEN , RIEBER NORBERT , FISCHER MARTIN
IPC: C07D301/06 , B01J23/40 , B01J29/04 , B01J29/74 , B01J29/76 , B01J29/89 , C01B15/029 , C07D301/04 , C07D301/12 , C07D303/04
Abstract: PCT No. PCT/EP95/02651 Sec. 371 Date Jan. 21, 1997 Sec. 102(e) Date Jan. 21, 1997 PCT Filed Jul. 7, 1995 PCT Pub. No. WO96/02323 PCT Pub. Date Feb. 1, 1996In an oxidation catalyst based on a titanium or vanadium silicalite having a zeolite structure and containing from 0.01 to 20% by weight of one or more platinum metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, the platinum metals are each present in at least two different bond energy states and preferably have no metal-metal bonds.
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公开(公告)号:AU7294296A
公开(公告)日:1997-05-15
申请号:AU7294296
申请日:1996-10-17
Applicant: BASF AG
Inventor: FISCHER MARTIN
IPC: B01J31/02 , B01J31/40 , B01J38/00 , C07D307/28
Abstract: PCT No. PCT/EP96/04504 Sec. 371 Date Apr. 21, 1998 Sec. 102(e) Date Apr. 21, 1998 PCT Filed Oct. 17, 1996 PCT Pub. No. WO97/15392 PCT Pub. Date May 1, 1997An improved process is provided for the recovery of catalyst components from oligomeric impurities which are formed during the industrial preparation of 2,5-dihydrofuran by the catalytic isomerization of vinyl oxirane followed by an essential separation of the oligomeric by-products which otherwise cause deactivation of the catalyst. The catalyst components consist essentially of (a) an onium iodide and (b) a Lewis acid selected from the group consisting of the chloride, bromide or iodide of the metals zinc, tin, cobalt and bismuth, preferably zinc, where the catalyst optionally includes a donor ligand. This separation is carried out by the steps of extracting the initial product mixture containing zinc, cobalt or bismuth halides as Lewis acids with hydrocarbons or chlorinated hydrocarbons containing from 5 to 14 carbon atoms in order to form two separate phases on standing, separating off the extraction solvent phase which contains the dissolved catalyst and then recovering the separated catalyst by distilling off the extraction solvent. The recovery of tin iodide requires the presence of a special onium halide component such as phosphazenium or phosphazanium halides, preferably the iodides, having a high molecular weight and especially those which contain from 16 to 72 carbon atoms while remaining soluble in the extracting agent.
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公开(公告)号:DE59305421D1
公开(公告)日:1997-03-20
申请号:DE59305421
申请日:1993-11-30
Applicant: BASF AG
Inventor: BOECK STEFAN , HERZOG KLAUS , FISCHER ROLF , VOGEL HERBERT , FISCHER MARTIN
IPC: C07D301/10 , B01J23/50 , B01J23/96 , B01J38/12 , B01J38/16 , C07D303/04
Abstract: PCT No. PCT/EP93/03352 Sec. 371 Date Mar. 17, 1995 Sec. 102(e) Date Mar. 17, 1995 PCT Filed Nov. 30, 1993 PCT Pub. No. WO94/13653 PCT Pub. Date Jun. 23, 19943,4-Epoxy-1-butene is prepared by the gas phase epoxidation of 1,3-butadiene by means of oxygen or oxygen-containing gases over silver-containing catalysts and isolation of the 3,4-epoxy-1-butene from the reaction exit mixture by performing the gas phase epoxidation in the presence of from 6 to 80 mol % of water vapor, based on the gas mixture supplied to the reactor.
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75.
公开(公告)号:AU2982295A
公开(公告)日:1996-02-16
申请号:AU2982295
申请日:1995-07-07
Applicant: BASF AG
Inventor: MULLER ULRICH , LINGELBACH PETER , BASSLER PETER , HARDER WOLFGANG , ELLER KARSTEN , KOHL VERONIKA , DEMBOWSKI JURGEN , RIEBER NORBERT , FISCHER MARTIN
IPC: C07D301/06 , B01J23/40 , B01J29/04 , B01J29/74 , B01J29/76 , B01J29/89 , C01B15/029 , C07D301/04 , C07D301/12 , C07D303/04
Abstract: PCT No. PCT/EP95/02651 Sec. 371 Date Jan. 21, 1997 Sec. 102(e) Date Jan. 21, 1997 PCT Filed Jul. 7, 1995 PCT Pub. No. WO96/02323 PCT Pub. Date Feb. 1, 1996In an oxidation catalyst based on a titanium or vanadium silicalite having a zeolite structure and containing from 0.01 to 20% by weight of one or more platinum metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, the platinum metals are each present in at least two different bond energy states and preferably have no metal-metal bonds.
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公开(公告)号:CA2036070A1
公开(公告)日:1991-08-17
申请号:CA2036070
申请日:1991-02-11
Applicant: FISCHER MARTIN , BAUR RICHARD , DIESSEL PAUL , BASF AG
Inventor: FISCHER MARTIN , BAUR RICHARD , DIESSEL PAUL
IPC: A61K8/30 , A61K8/00 , A61K8/39 , A61K8/81 , A61K8/86 , A61Q5/02 , A61Q19/00 , A61Q19/10 , C07C43/178 , C07C43/23 , C07C303/20 , C07C303/32 , C07C309/09 , C07C309/10 , C09K23/04 , C09K23/42 , C09K23/52 , C11D1/12 , C11D1/14 , C11D1/16 , C11D1/72 , A61K7/00 , C11D1/29
Abstract: Vinyl polyether alcohols of the disclosure: Vinyl polyether alcohols of formula I I (R = C1-C25-alkyl, C2-C25-alkenyl or alkylaryl having a total of not more than 20 carbon atoms, A = 1,2-alkylene having from 2 to 4 carbon atoms and n = 1 to 20). These compounds serve as intermediates in the preparation of polyether sulfonates of formula III III (M = hydrogen, alkali metal or ammonium). The vinyl polyether alcohols of formula I are useful as surface-active compounds for inclusion in surface-active compositions.
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公开(公告)号:DE50004440D1
公开(公告)日:2003-12-18
申请号:DE50004440
申请日:2000-08-10
Applicant: BASF AG
Inventor: AUST CHRISTIANE , BUTZ THOMAS , FISCHER MARTIN
Abstract: The present invention relates to a process for the preparation of phosphonomethylglycine, wherein N-phosphonomethyliminodiacetic acid N-oxide is brought into contact with a catalytically effective amount of thiocyanic acid or a salt thereof.
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公开(公告)号:PT1203000E
公开(公告)日:2003-09-30
申请号:PT00951493
申请日:2000-08-10
Applicant: BASF AG
Inventor: AUST NICOLA CHRISTIANE , BUTZ THOMAS , FISCHER MARTIN
Abstract: The present invention relates to a process for the preparation of phosphonomethylglycine in which N-phosphonomethyliminodiacetic acid N-oxide is brought into contact with a catalytically active quantity of at least one catalyst, selected from amongst a thionyl halide, ammonium dithionite or an alkali metal dithionite, a dialkyl sulfite, sulfur dichloride, sulfur dioxide and sulfurous acid, in a reaction chamber by metering the N-phosphonomethyliminodiacetic acid N-oxide into the reaction chamber in such a way that always at least 50% of the N-oxide metered into the reaction chamber are converted.
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公开(公告)号:ZA200201942B
公开(公告)日:2003-05-28
申请号:ZA200201942
申请日:2002-03-08
Applicant: BASF AG
Inventor: AUST NICOLA CHRISTIANE , BUTZ THOMAS , FISCHER MARTIN
Abstract: The present invention relates to a process for the preparation of phosphonomethylglycine in which N-phosphonomethyliminodiacetic acid N-oxide is brought into contact with a catalytically active quantity of at least one catalyst, selected from amongst a thionyl halide, ammonium dithionite or an alkali metal dithionite, a dialkyl sulfite, sulfur dichloride, sulfur dioxide and sulfurous acid, in a reaction chamber by metering the N-phosphonomethyliminodiacetic acid N-oxide into the reaction chamber in such a way that always at least 50% of the N-oxide metered into the reaction chamber are converted.
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公开(公告)号:DE59709121D1
公开(公告)日:2003-02-13
申请号:DE59709121
申请日:1997-10-15
Applicant: BASF AG
Inventor: FISCHER MARTIN , KAIBEL GERD , STAMMER ACHIM , FLICK KLEMENS , QUAISER STEFAN , HARDER WOLFGANG , MASSONNE KLEMENS
IPC: B01J8/04 , B01J19/24 , B01J19/26 , C01B15/029
Abstract: A process for preparing a hydrogen peroxide solution having a hydrogen peroxide content of not less than 2.5% by weight, which comprises continuously reacting hydrogen and oxygen in an aqueous, alcoholic or aqueous/alcoholic reaction medium in the presence of a catalyst containing palladium.
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