Method of separating oligomeric side-products from an isomerization catalyst

    公开(公告)号:AU7294296A

    公开(公告)日:1997-05-15

    申请号:AU7294296

    申请日:1996-10-17

    Applicant: BASF AG

    Inventor: FISCHER MARTIN

    Abstract: PCT No. PCT/EP96/04504 Sec. 371 Date Apr. 21, 1998 Sec. 102(e) Date Apr. 21, 1998 PCT Filed Oct. 17, 1996 PCT Pub. No. WO97/15392 PCT Pub. Date May 1, 1997An improved process is provided for the recovery of catalyst components from oligomeric impurities which are formed during the industrial preparation of 2,5-dihydrofuran by the catalytic isomerization of vinyl oxirane followed by an essential separation of the oligomeric by-products which otherwise cause deactivation of the catalyst. The catalyst components consist essentially of (a) an onium iodide and (b) a Lewis acid selected from the group consisting of the chloride, bromide or iodide of the metals zinc, tin, cobalt and bismuth, preferably zinc, where the catalyst optionally includes a donor ligand. This separation is carried out by the steps of extracting the initial product mixture containing zinc, cobalt or bismuth halides as Lewis acids with hydrocarbons or chlorinated hydrocarbons containing from 5 to 14 carbon atoms in order to form two separate phases on standing, separating off the extraction solvent phase which contains the dissolved catalyst and then recovering the separated catalyst by distilling off the extraction solvent. The recovery of tin iodide requires the presence of a special onium halide component such as phosphazenium or phosphazanium halides, preferably the iodides, having a high molecular weight and especially those which contain from 16 to 72 carbon atoms while remaining soluble in the extracting agent.

    74.
    发明专利
    未知

    公开(公告)号:DE59305421D1

    公开(公告)日:1997-03-20

    申请号:DE59305421

    申请日:1993-11-30

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP93/03352 Sec. 371 Date Mar. 17, 1995 Sec. 102(e) Date Mar. 17, 1995 PCT Filed Nov. 30, 1993 PCT Pub. No. WO94/13653 PCT Pub. Date Jun. 23, 19943,4-Epoxy-1-butene is prepared by the gas phase epoxidation of 1,3-butadiene by means of oxygen or oxygen-containing gases over silver-containing catalysts and isolation of the 3,4-epoxy-1-butene from the reaction exit mixture by performing the gas phase epoxidation in the presence of from 6 to 80 mol % of water vapor, based on the gas mixture supplied to the reactor.

    77.
    发明专利
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    公开(公告)号:DE50004440D1

    公开(公告)日:2003-12-18

    申请号:DE50004440

    申请日:2000-08-10

    Applicant: BASF AG

    Abstract: The present invention relates to a process for the preparation of phosphonomethylglycine, wherein N-phosphonomethyliminodiacetic acid N-oxide is brought into contact with a catalytically effective amount of thiocyanic acid or a salt thereof.

    78.
    发明专利
    未知

    公开(公告)号:PT1203000E

    公开(公告)日:2003-09-30

    申请号:PT00951493

    申请日:2000-08-10

    Applicant: BASF AG

    Abstract: The present invention relates to a process for the preparation of phosphonomethylglycine in which N-phosphonomethyliminodiacetic acid N-oxide is brought into contact with a catalytically active quantity of at least one catalyst, selected from amongst a thionyl halide, ammonium dithionite or an alkali metal dithionite, a dialkyl sulfite, sulfur dichloride, sulfur dioxide and sulfurous acid, in a reaction chamber by metering the N-phosphonomethyliminodiacetic acid N-oxide into the reaction chamber in such a way that always at least 50% of the N-oxide metered into the reaction chamber are converted.

    Method for the production of phosphonomethylglycin.

    公开(公告)号:ZA200201942B

    公开(公告)日:2003-05-28

    申请号:ZA200201942

    申请日:2002-03-08

    Applicant: BASF AG

    Abstract: The present invention relates to a process for the preparation of phosphonomethylglycine in which N-phosphonomethyliminodiacetic acid N-oxide is brought into contact with a catalytically active quantity of at least one catalyst, selected from amongst a thionyl halide, ammonium dithionite or an alkali metal dithionite, a dialkyl sulfite, sulfur dichloride, sulfur dioxide and sulfurous acid, in a reaction chamber by metering the N-phosphonomethyliminodiacetic acid N-oxide into the reaction chamber in such a way that always at least 50% of the N-oxide metered into the reaction chamber are converted.

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