公开(公告)号：CA2353573A1

公开(公告)日：2000-06-15

申请号：CA2353573

申请日：1999-12-02

Applicant: BASF AG

Inventor： MISSLITZ ULF ,  WESTPHALEN KARL-OTTO ,  GOTZ NORBERT ,  NEIDLEIN ULF ,  BAUMANN ERNST ,  WITSCHEL MATTHIAS ,  OTTEN MARTINA ,  GOTZ ROLAND ,  MAYER GUIDO ,  KUDIS STEFFEN ,  VON DEYN WOLFGANG ,  WALTER HELMUT ,  LANGEMANN KLAUS

IPC: A01N43/50 ,  A01N43/56 ,  A01N43/74 ,  A01N43/80 ,  C07B61/00 ,  C07D231/20 ,  C07D413/10 ,  C07D413/12

Abstract: The invention relates to 3-(heterocyclyl)-benzoylpyrazole derivatives of formula (I), wherein the variables have the following meanings: X is O, NH o r N-alkyl; R1 is nitro, halogen, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkyl-sulfonyl; R2, R3, R4, R5 are hydrogen, alkyl or halogenalkyl; R6 is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R7 is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, (alkylthio)carbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R8, R9 are alkyl; R10 is hydrogen or alkyl; and R11 is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to a method for producing these compounds and to their use or the use of products containing them for combating undesirable plants.

公开(公告)号：AU1380900A

公开(公告)日：2000-06-13

申请号：AU1380900

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOTZ NORBERT ,  GOTZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  BAYETO JUAN JOSE AISCAR

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：AU5970799A

公开(公告)日：2000-03-21

申请号：AU5970799

申请日：1999-08-25

Applicant: BASF AG

Inventor： RENTZEA COSTIN ,  PLATH PETER ,  GOTZ ROLAND ,  OTTEN MARTINA ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

IPC: A01N43/16 ,  C07D309/28 ,  C07D405/12

公开(公告)号：CA2332019A1

公开(公告)日：1999-11-25

申请号：CA2332019

申请日：1999-05-04

Applicant: BASF AG

Inventor： LORENZ GISELA ,  GROTE THOMAS ,  AMMERMANN EBERHARD ,  PTOCK ARNE ,  BAYER HERBERT ,  HARRIES VOLKER ,  KEIL MICHAEL ,  SAUTER HUBERT ,  GOTZ ROLAND ,  CULLMANN OLIVER ,  MULLER BERND ,  STRATHMANN SIEGFRIED ,  GEWEHR MARKUS ,  GYPSER ANDREAS ,  GRAMMENOS WASSILIOS

IPC: C07C251/38 ,  A01N37/40 ,  C07C49/303 ,  C07C251/42 ,  C07C251/50 ,  C07C251/52 ,  C07C251/60 ,  C07C49/35 ,  A01N37/50

Abstract: The invention relates to bisoximether derivatives of formula (I) in which th e variables have the following meanings: R1 represents halogen, C1-C4 alkyl, C 1- C4 alkyl halide, C1-C4 alkoxy or C1-C4 alkoxy halide; n is 1 to 5, whereby t he radicals R1 can be different if n is not equal to 1; R2 represents C1-C4 alkyl, C3-C6 alkenyl or C3-C6 alkynyl, whereby these groups can be partially or completely halogenated; Q represents C(=CHOCH3)-COOCH3, C(=CHCH3)-COOCH3, C(=NOCH3)-COOCH3 or C(=NOCH3)-CONHCH3. The invention also relates to the sal ts of the bisoximether derivatives, to methods and intermediate products for th e production of these compounds and to their use for combating animal pests an d fungicidal pests.

公开(公告)号：AU2718899A

公开(公告)日：1999-08-23

申请号：AU2718899

申请日：1999-01-26

Applicant: BASF AG

Inventor： PTOCK ARNE ,  SAUTER HUBERT ,  KIRSTGEN REINHARD ,  GRAMMENOS WASSILIOS ,  GROTE THOMAS ,  GYPSER ANDREAS ,  BAYER HERBERT ,  GEWEHR MARKUS ,  CULLMANN OLIVER ,  MULLER BERND ,  GOTZ ROLAND ,  ROHL FRANZ ,  AMMERMANN EBERHARD ,  LORENZ GISELA ,  HARRIES VOLKER ,  STRATHMANN SIEGFRIED

IPC: A01N43/48 ,  A01N43/56 ,  C07D401/12 ,  C07D401/14

公开(公告)号：AU5753698A

公开(公告)日：1998-07-15

申请号：AU5753698

申请日：1997-12-04

Applicant: BASF AG

Inventor： VOGELBACHER UWE JOSEF ,  KEIL MICHAEL ,  KLINTZ RALF ,  WAHL JOSEPH ,  WINGERT HORST ,  KONIG HARTMANN ,  RACK MICHAEL ,  GOTZ ROLAND ,  TELES JOAQUIM HENRIQUE

IPC: C07D231/20 ,  C07D231/22

Abstract: PCT No. PCT/EP97/06780 Sec. 371 Date Jun. 14, 1999 Sec. 102(e) Date Jun. 14, 1999 PCT Filed Dec. 4, 1997 PCT Pub. No. WO98/27062 PCT Pub. Date Jun. 25, 1998A process is described for preparing N-substituted 3-hydroxypyrazoles of the formula I where R1 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl or heteroaryl and R2, R3 are hydrogen, cyano, halogen and unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl or heteroaryl, by oxidizing a corresponding pyrazolidin-3-one.

公开(公告)号：NZ564023A

公开(公告)日：2010-11-26

申请号：NZ56402306

申请日：2006-06-19

Applicant: BASF AG

Inventor： ZIEGLER HANS ,  MAYER WINFRIED ,  KROHL THOMAS ,  ERK PETER ,  VOGELBACHER UWE JOSEF ,  NOACK RAINER ,  GOTZ ROLAND ,  COX GERHARD ,  SCHNEIDER KARL-HEINRICH ,  WUCKELT JORG ,  RAULS MATTHIAS

IPC: A01N47/24 ,  A01N43/56 ,  C07D231/22

Abstract: Disclosed is a crystalline modification IV of pyraclostrobin which, in an X-ray powder diffractogram at 25°C, shows at least three of the following reflexes: d = 6.02 ± 0.01 Å, d = 4.78 ± 0.01 Å, d = 4.01 ± 0.01 Å, d = 3.55 ± 0.01 Å and d = 3.01 ± 0.01 Å. Also disclosed is a process for preparing a crystalline modification IV of pyraclostrobin as defined above, which comprises: i) dissolving a pyraclostrobin form different from modification IV in an organic solvent or solvent mixture, where the organic solvent or solvent mixture comprises at least 70% by volume of at least one fully water-miscible organic solvent L1 (such as methanol, ethanol, acetone or butanone) and if appropriate up to 30% by volume of water; and ii) effecting crystallization of pyraclostrobin over a period of at least 10 h and/or in the presence of seed crystals of modification IV.

公开(公告)号：ES2280369T3

公开(公告)日：2007-09-16

申请号：ES01931563

申请日：2001-04-04

Applicant: BASF AG

Inventor： GOTZ ROLAND ,  WOLF BERND ,  RACK MICHAEL

IPC: C07C249/14 ,  C07B61/00 ,  C07C249/12 ,  C07C251/32 ,  C07C251/38

Abstract: Procedimiento para la producción de éteres de oxima de fórmula I, en el que los sustituyentes R1 y R2 pueden ser iguales o diferentes y pueden significar respectivamente ciano, alquilo C1-C4, haloalquilo C1-C4, cicloalquilo C3-C6, fenilo y naftilo y R3 alquilo C1-C4, mediante la alquilación de oximas de fórmula II, en condiciones básicas con un agente de alquilación del grupo de los halogenuros de alquilo, sulfatos de dialquilo y carbonatos de dialquilo, caracterizado porque la reacción se lleva a cabo en una mezcla que se compone de del 5 al 25% en peso de disolventes polares apróticos seleccionados del grupo nitrilo, N-alquilpirrolidina, derivados de urea cíclicos, dimetilformamida y dimetilacetamida, del 55 al 95% en peso de disolventes apolares seleccionados del grupo de los hidrocarburos alifáticos, hidrocarburos aromáticos, éteres y ésteres alquílicos del ácido alquilcarboxílico, y del 0 al 25% en peso de agua, en el que estos porcentajes se complementan para dar hasta el 100%.

公开(公告)号：PE20070090A1

公开(公告)日：2007-02-09

申请号：PE2006000681

申请日：2006-06-16

Applicant: BASF AG

Inventor： ZIEGLER HANS ,  MAYER WINFRIED ,  SCHNEIDER KARL-HEINRICH ,  ERK PETER ,  NOACK RAINER ,  WUCKELT JORG ,  RAULS MATTHIAS ,  GOTZ ROLAND ,  VOGELBACHER UWE JOSEF ,  COX GERHARD ,  KROHL THOMAS

IPC: C07D231/22

Abstract: SE REFIERE A UNA MODIFICACION CRISTALINA IV, LA CUAL EN UN DIFRACTOGRAMA DE POLVO DE RAYOS X A 25°C DEMUESTRA POR LO MENOS TRES DE LOS REFLEJOS SIGUIENTES: d=6,02± 0,01 Å, d=4,78± 0,01 Å, d=4,01± 0,01 Å, d=3,55± 0,01 Å Y d=3,01± 0,01 Å; TENIENDO UN PUNTO DE FUSION ENTRE 62°C Y 72°C, Y UN CONTENIDO DE PIRACLOSTROBINA POR LO MENOS DE 98% EN PESO. UNA MODIFICACION CRISTALINA II, LA CUAL EN UN DIFRACTOGRAMA DE POLVO DE RAYOS X A 25°C DEMUESTRA POR LO MENOS CUATRO DE LOS REFLEJOS SIGUIENTES: d=5,93± 0,01 Å, d=5,82± 0,01 Å, d=4,89± 0,01 Å, d=4,78± 0,01 Å Y d=4,71± 0,01 Å, d=3,97± 0,01 Å, d=3,89± 0,01 Å, d=3,77± 0,01 Å; d=3,75± 0,01 Å, d=3,57± 0,01 Å Y d=3,43± 0,01 Å; TENIENDO UN PUNTO DE FUSION ENTRE 57°C Y 58°C, Y UN CONTENIDO DE PIRACLOSTROBINA POR LO MENOS DE 98% EN PESO. DICHAS MODIFICACIONES SE USAN PARA CONTROLAR HONGOS FITOPATOGENOS. EL PROCEDIMIENTO PARA PREPARALAS INCLUYE: a) PREPARAR UNA SUSPENSION DE O DISOLVER UNA FORMA DE PIRACLOSTROBINA DIFERENTE DE LA MODIFICACION IV, A UNA TEMPERATURA SUPERIOR A 50°C, EN UN SOLVENTE ORGANICO O MEZCLA SOLVENTE QUE COMPRENDE POR LO MENOS 70% EN VOLUMEN DE POR LO MENOS UN SOLVENTE ORGANICO TOTALMENTE MISCIBLE EN AGUA (ALCANOLES C1-C4, ACETONA Y BUTANONA) Y SI FUERA APROPIADO HASTA 30% EN VOLUMEN DE AGUA; Y, b) EFECTUAR LA CRISTALIZACION DE PIRACLOSTROBINA DURANTE POR LO MENOS 10 HORAS, Y/O EN PRESENCIA DE NUCLEOS CRISTALINOS DE MODIFICACION IV, ENFRIANDO LA SOLUCION O AGREGANDO AGUA A LA SOLUCION DE PIRACLOSTROBINA

公开(公告)号：AU766546B2

公开(公告)日：2003-10-16

申请号：AU1380900

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOTZ NORBERT ,  GOTZ ROLAND ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  BAYETO JUAN JOSE AISCAR

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.